Nowadays, plant invasion has become a global ecological threat to local biodiversity and ecosystem stability. Spartina alterniflora encroaches on the ecological niches of local species and changes the soil’s nutrient cycle. However, few comprehensive assessments focus on the effects of S. alterniflora invasion. Here, we investigated how soil sulfur changed with spatiotemporal variation and life forms of native species after S. alterniflora invasion and speculated the possible mechanism of the sulfur increase based on the references. The invasion of S. alterniflora increased soil total sulfur by 57.29% and phytotoxic sulfide by 193.29%. In general, the invasion of S. alterniflora enhanced the total plant biomass and soil nutrients, e.g., soil organic carbon, total nitrogen, and soil microbial biomass carbon, further increasing soil sulfur content. The sulfur accumulation caused by S. alterniflora might result in the poisoning of native species. Thus, we hypothesized that the success of S. alterniflora invasion was closely connected with soil sulfur, especially toxic sulfide. Our study suggests that researchers should give more attention to the correlation between S. alterniflora invasion and the soil sulfur increase. More research is needed to investigate the mechanisms of the successful invasion by accumulating phytotoxic sulfide.

The middle reaches of the Yangtze River region (MRYRR) are China’s first trans-regional urban agglomeration, located in the center of the Yangtze River Economic Belt. The MRYRR is an important ecological reserve, and its land cover changes are affected by both socio-economic development and geographical environment. In this paper, Landsat ETM/TM/OLI remote sensing images were used to monitor land use and landscape patterns from 1990 to 2015. Through supervised classification, land use transfer matrix, landscape pattern metrics and correlation analysis, the spatial-temporal patterns of land use change and its relationship with socio-economic in the study area were revealed. The results showed that: (1) the main land use types in the study area were cropland (CL) and forestland (FL), accounting for more than three-quarters of the study area. During the study period, built-up land (BL) increased, CL decreased, FL increased first and then decreased; (2) the BL expanded mainly by occupying CL and FL, and regional landscape pattern was gradually fragmented, with complex patch shape and increasing diversity and heterogeneity. Among them, the BL is gradually gathered, and the FL and CL are gradually fragmented; (3) in the past 25 years, the urbanization process in this region has been obvious, and the Gross Domestic Product (GDP) has increased by 36 times. The socioeconomic variables were positively correlated with BL, orchard (OL) and Shannon diversity index (SHID), and negatively correlated with CL, Wasteland (WL), mean patch size (MPS) and contagion size (CONTAG). The results showed that the urbanization development has a great impact on the region, and the ecological protection task is still challenging. It is necessary to protect high-quality cropland and draw a red line for ecological protection. We should strengthen the construction of ecological corridors and ecological nodes to adapt to regional sustainable development.

Advanced oxidation processes (AOPs) have become a favored approach in wastewater treatment due to the high efficiency and diverse catalyzed ways. Iron-based materials were the commonly used catalyst due to their environmental friendliness and sustainability in the environment. We collected the published papers relative to the application of the modified iron-based materials in AOPs between 1999 and 2020 to comprehensively understand the related mechanism of modified materials to improve the catalytic performance of iron-based materials in AOPs. Related data of iron-based materials, modification types, target pollutants, final removal efficiencies, and rate constants were extracted to reveal the critical process of improving the catalytic efficiency of iron-based materials in AOPs. Our results indicated that the modified materials through various mechanisms to enhance the catalytic performance of iron-based materials. The principal aim of iron-based materials modification in AOPs is to increase the content of available Fe²⁺ and enhance the stability of Fe²⁺ in the system. The available Fe²⁺ is elevated by the following mechanisms: (1) modified materials accelerate the electron transfer to promote the Fe³⁺/Fe²⁺ reaction cycle in the system; (2) modified materials form chelates with iron ions and bond with iron ions to avoid Fe³⁺ precipitation. We further analyzed the effect of different modifying materials in improving these two mechanisms. Combining the advantages of different modified materials to develop iron-based materials with composite modification methods can enhance the catalytic performance of iron-based materials in AOPs for further application in wastewater treatment.