As water management is still a problem of international concern, scientists and practitioners are collaborating to develop new tools and methods to improve and help in the decision-making process. When addressing the priority pollutant monitoring and impact assessment, the ecotoxicity effects, carcinogenic and non-carcinogenic, should be considered together with the exposure factor and health hazards. The main goals of this study were to assess the ecological and health hazards and to apply integrated impact and risk assessment based on the ecotoxicity and exposure factors of each priority pollutant present in the aquatic ecosystem. This study used as a database the measured concentrations of 5 inorganic and 14 organic priority pollutants from the Siret river basin from NE Romania, from 18 river sections monitored in the period 2015–2020. The USEtox methodology and a new integrated index for environmental impact and risk assessment were developed and applied to evaluate the ecological and health hazards and environmental impacts and risks within the river basin. The total impact scores for heavy metals ranged from 2 × 10³ to 2.25 × 10⁹, and those for organic pollutants ranged from 2.72 × 10⁻¹ to 2.95 × 10⁶. The environmental risk in the case of inorganic priority pollutants ranged between 5.56 and 3136.35, and that in the case of organic pollutants was between 4.69 and 4059.17. The results revealed that there is a major to catastrophic environmental impact in almost all monitored river sections (10 out of 18), and the overall risk exposure was found to be at a significant to a major level. This study proved the harmful effects that the priority pollutants may have, even in very small concentrations, on non-target organisms and suggests that greater control over the pollution sources and mitigation of environmental impacts and risks should be applied.

The Integrated Water Resources Management regulations aim to ensure a good status of surface water quality and its sustainable use. Water quality monitoring of various water users supports the identification of pollution sources and their environmental impacts. The priority pollutants generated by wastewater discharges from municipal, industrial wastewater treatment plants or agricultural areas are of great interest due to their eco-toxicological effects and bio-accumulative properties. The aim of this study was to monitor the priority organic and inorganic pollutants from the Siret River basin, in Romania, with the purpose of assessing the surface water quality status and evaluating it by the Water Quality Index (WAWQI) method. The monitoring of inorganic priority pollutants (e.g., As, Cd, Hg, Ni, Pb) and organic priority pollutants (e.g., Naphthalene, Anthracene, Phenanthrene, Fluoranthene, Benzo(a)anthracene, Benzo(b)fluoranthene, Benzo(k)fluoranthene, Benzo(a)pyrene, Benzo(ghi)perylene, Indeno(1,2,3-cd)pyrene, α, β, and γ-Hexachlorocyclohexane, and Di-2-ethyl-hexyl-phthalate) was conducted within the Siret River basin, during the period 2015–2020. With this purpose, 21 sampling points (18 river sections and 3 lakes) were considered to assess the water quality. The results of this study proved that the water quality within the Siret River basin is generally classified in the 2nd or 3rd class. The spatial distribution of the water quality index values, using ARCGIS, also highlighted the fact that the water quality is mostly unsuitable for drinking water supplies, being influenced by the quality of its main tributaries, as well as by the effluent of wastewater treatment plants.

Pharmaceuticals and heavy metals pose significant risks to human health and aquatic ecosystems, necessitating their removal from water and wastewater. A promising alternative for this purpose involves their removal by adsorption on composite sorbents prepared using a conventional layer-by-layer (LbL) method or an innovative coacervate direct deposition approach. In this study, four novel composite materials based on a silica core (IS) and a polyelectrolyte coacervate shell were used for the investigation of dynamic adsorption of three heavy metals (lead, nickel and cadmium) and an organic drug model (diclofenac sodium salt, DCF-Na). The four types of composite sorbents were tested for the first time in dynamic conditions (columns with continuous flow), and the column conditions were similar to those used in wastewater treatment plants. The influence of the polyanion nature (poly(acrylic acid) (PAA) vs. poly(sodium methacrylate) (PMAA)), maintaining a constant poly(ethyleneimine) (PEI), and the cross-linking degree (r = 0.1 and r = 1.0) of PEI chains on the immobilization of these pollutants (inorganic vs. organic) on the same type of composite was also studied. The experiments involved both single- and multi-component aqueous solutions. The kinetics of the dynamic adsorption process were examined using two non-linear models: the Thomas and Yoon–Nelson models. The tested sorbents demonstrated good adsorption capacities with affinities for the metal ions in the following order: Pb²⁺ > Cd²⁺ > Ni²⁺. An increase in the initial diclofenac sodium concentration led to an enhanced adsorption capacity of the IS/(PEI-PAA)_c-r1 sorbent. The calculated sorption capacities were in good agreement with the adsorption capacity predicted by the Thomas and Yoon–Nelson models. The substantial affinity observed between DCF-Na and a column containing composite microparticles saturated with heavy metal ions was explained.

The current survey aimed to analyse the water quality from wells in a rural area situated in the north-east of Romania, comprising the main water source for human consumption in the area. 80 wells were analysed for total dissolved solids, which was used as the main indicator of water quality and followed by measurements of dissolved oxygen and saturation, salinity, conductivity, redox potential and pH . For comparison, the values of these parameters were also measured in the water from the public network of the cities of Iasi and Botosani, as well as in various brands of bottled water. The results highlighted important water quality issues in rural areas, especially in terms of microbiological contamination and high nitrate levels, urging the need for future measures to improve the local infrastructure and water treatment systems. These findings contribute to a better understanding of the challenges related to ensuring drinking water in rural communities and provide a basis for developing effective public policies in water resources management.