Vladimír Holcman

Dr. Vladimír Holcman

orcid

Research Focus & Metrics

Academic Career Length

17Years (2010-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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18 July 2025 in Polymers
Verified
Journal Article
Open access
PDF file
RDRashid Dallaev
Rashid Dallaev
NPNikola Papež
Nikola Papež
MAMohammad M. Allaham
Mohammad M. Allaham
VHVladimír Holcman
Vladimír Holcman
The accelerating global demand for sustainable materials has brought biodegradable polymers to the forefront of scientific and industrial innovation. These polymers, capable of decomposing through biological processes into environmentally benign byproducts, are increasingly seen as viable alternatives to conventional plastics in sectors such as packaging, agriculture, and biomedicine. However, despite significant advancements, the field remains fragmented due to the diversity of raw materials, synthesis methods, degradation mechanisms, and application requirements. This review aims to provide a comprehensive synthesis of the current state of biodegradable polymer development, including their classifications, sources (natural, synthetic, and microbially derived), degradation pathways, material properties, and commercial applications. It highlights critical scientific and technological challenges—such as optimizing degradation rates, ensuring mechanical performance, and scaling up production from renewable feedstocks. By consolidating recent research findings and regulatory considerations, this review serves as a crucial reference point for researchers, material scientists, and policymakers. It strives to bridge knowledge gaps in order to accelerate the deployment of biodegradable polymers as integral components of a circular and low-impact material economy.

15 March 2021 in Materials
Verified
Journal Article
Open access
PDF file
PKPavel Kaspar
Pavel Kaspar
Dinara SobolaDinara Sobola
Dinara Sobola
KČKlára Částková
Klára Částková
RDRashid Dallaev
Rashid Dallaev
EŠEva Šťastná
Eva Šťastná
VHVladimír Holcman
Vladimír Holcman
Modern material science often makes use of polyvinylidene fluoride thin films because of various properties, like a high thermal and chemical stability, or a ferroelectric, pyroelectric and piezoelectric activity. Fibers of this polymer material are, on the other hand, much less explored due to various issues presented by the fibrous form. By introducing carbon nanotubes via electrospinning, it is possible to affect the chemical and electrical properties of the resulting composite. In the case of this paper, the focus was on the further improvement of interesting polyvinylidene fluoride properties by incorporating carbon nanotubes, such as changing the concentration of crystalline phases and the resulting increase of the dielectric constant and conductivity. These changes in properties have been explored by several methods that focused on a structural, chemical and electrical point of view. The resulting obtained data have been documented to create a basis for further research and to increase the overall understanding of the properties and usability of polyvinylidene fluoride fiber composites.

30 September 2023 in Polymers
Verified
Journal Article
Open access
PDF file
RDRashid Dallaev
Rashid Dallaev
TPTatiana Pisarenko
Tatiana Pisarenko
NPNikola Papež
Nikola Papež
PSPetr Sadovský
Petr Sadovský
VHVladimír Holcman
Vladimír Holcman
This paper offers a short overview of epoxy resins, encompassing their diverse characteristics, variants, chemical modifications, curing processes, and intriguing electrical properties. Epoxies, valued for their multifunctional attributes, serve as fundamental materials across industries. In the realm of dielectric strength, epoxy resins play a crucial role in electrical insulation. This paper discusses the mechanisms governing dielectric breakdown, strategies to enhance dielectric strength, and the impact of various fillers and additives on insulation performance. Through an exploration of recent research and advancements, this paper delves into the spectrum of epoxy properties, the array of subspecies and variants, their chemical adaptability, and the intricacies of curing. The examination of electrical resistance and conductivity, with a focus on their frequency-dependent behavior, forms a pivotal aspect of the discussion. By shedding light on these dimensions, this review provides a concise yet holistic understanding of epoxies and their role in shaping modern materials science.

25 August 2023 in Materials
Verified
Journal Article
Open access
PDF file
RDRashid Dallaev
Rashid Dallaev
TPTatiana Pisarenko
Tatiana Pisarenko
NPNikola Papež
Nikola Papež
VHVladimír Holcman
Vladimír Holcman
The rapid growth and evolution of solar panel technology have been driven by continuous advancements in materials science. This review paper provides a comprehensive overview of the diverse range of materials employed in modern solar panels, elucidating their roles, properties, and contributions to overall performance. The discussion encompasses both traditional crystalline silicon-based panels and emerging thin-film technologies. A detailed examination of photovoltaic materials, including monocrystalline and polycrystalline silicon as well as alternative materials such as cadmium telluride (CdTe), copper indium gallium selenide (CIGS), and emerging perovskite solar cells, is presented. Furthermore, the impact of transparent conductive materials, encapsulation polymers, and antireflective coatings on solar panel efficiency and durability is explored. The review delves into the synergistic interplay between material properties, manufacturing processes, and environmental considerations. Through a comprehensive survey of materials utilized in modern solar panels, this paper provides insights into the current state of the field, highlighting avenues for future advancements and sustainable solar energy solutions.

16 August 2022 in Materials
Verified
Journal Article
Open access
PDF file
SDSameh Dabees
Sameh Dabees
SMSaeed Mirzaei
Saeed Mirzaei
PKPavel Kaspar
Pavel Kaspar
VHVladimír Holcman
Vladimír Holcman
Dinara SobolaDinara Sobola
Dinara Sobola
Coatings are now frequently used on cutting tool inserts in the metal production sector due to their better wear resistance and heat barrier effect. Protective hard coatings with a thickness of a few micrometers are created on cutting tools using physical or chemical vapor deposition (PVD, CVD) to increase their application performance. Different coating materials are utilized for a wide range of cutting applications, generally in bi-or multilayer stacks, and typically belong to the material classes of nitrides, carbides, carbonitrides, borides, boronitrides, or oxides. The current study examines typical hard coatings deposited by PVD and CVD in the corresponding material classes. The present state of research is reviewed, and pioneering work on this subject as well as recent results leading to the construction of complete “synthesis–structure–property–application performance” correlations of the different coatings are examined. When compared to uncoated tools, tool coatings prevent direct contact between the workpiece and the tool substrate, altering cutting temperature and machining performance. The purpose of this paper is to examine the effect of cutting-zone temperatures on multilayer coating characteristics during the metal-cutting process. Simplified summary and comparisons of various coating types on cutting tools based on distinct deposition procedures. Furthermore, existing and prospective issues for the hard coating community are discussed.

24 July 2021 in Polymers
Verified
Journal Article
Open access
PDF file
Dinara SobolaDinara Sobola
Dinara Sobola
PKPavel Kaspar
Pavel Kaspar
KČKlára Částková
Klára Částková
RDRashid Dallaev
Rashid Dallaev
NPNikola Papež
Nikola Papež
VHVladimír Holcman
Vladimír Holcman
The method of inclusion of various additives into a polymer depends highly on the material in question and the desired effect. In the case of this paper, nitride salts were introduced into polyvinylidene fluoride fibers prepared by electrospinning. The resulting changes in the structural, chemical and electrical properties of the samples were observed and compared using SEM-EDX, DSC, XPS, FTIR, Raman spectroscopy and electrical measurements. The observed results displayed a grouping of parameters by electronegativity and possibly the molecular mass of the additive salts. We virtually demonstrated elimination of the presence of the γ-phase by addition of Mg(NO3)2, Ca(NO3)2, and Zn(NO3)2 salts. The trend of electrical properties to follow the electronegativity of the nitrate salt cation is demonstrated. The performed measurements of nitrate salt inclusions into PVDF offer a new insight into effects of previously unstudied structures of PVDF composites, opening new potential possibilities of crystalline phase control of the composite and use in further research and component design.