The Bialowieza Primeval Forest (BF) is one of the well-known forests in Central Europe. The most common tree species in BF was Norway spruce (Picea abies (L.) H. Karst), comprising 26%. However, a mass dieback of spruce has occurred during recent years. The spruce dieback in Bialowieza Forest is directly caused by the spruce bark beetle. However, the mass appearance of this pest can be a consequence of global warming and drought. Changes in air temperature were presented and drought indices were calculated as follows: standardized precipitation index, Palmer drought severity index, climatic water balance and soil water storage deficit. The warming of the climate of Bialowieza from 1950 to 2015 is comparable to that observed throughout central Europe. The temperature increased by 1.27 °C. The occurrence of drought from 1950 to 1966 and from 1985 to 2015 had a similar frequency. From 1963 to 1966, the volume of removed deadwood from the managed part of Bialowieza Forest was 27 thousand m³ but from 2012 to 2016, the volume was more than one million m³.

Groundwater is the primary water source for ecosystems, and so changes in groundwater levels, if directional and constant, can cause changes in vegetation and habitat characters. In Białowieża National Park, a significant decline in the water table was observed at the beginning of the 20th century. The question therefore arose as to whether the changes that occurred at that time were permanent. A second question was whether the negative trend would continue so clearly in the following years. The study is based on measurements from 1985 to 2005 and 2022 to 2023 taken in the same monitoring wells. Complete data were collected from 21 monitoring wells. An analysis of groundwater levels between 1985 and 2005 showed an average decline of 0.08 m/10 years in swamp habitats, 0.11 m/10 years in moist habitats, and 0.21 m/10 years in fresh habitats. The measurements in 2022 and 2023 showed that the trend of falling water levels had slowed down in almost the entire study area, with water levels in recent years being similar to those at the beginning of the century. This was also confirmed by comparing years with similar precipitation: 2022 with 1986, and 2002, 2004, and 2023 with 1999. This was due to the higher precipitation after 2005. In the period of 2006–2023, precipitation in the hydrological years was on average 60 mm higher than in the period of 1985–2005. Despite the clear trend toward rising air temperatures, the higher precipitation compensated for the higher evapotranspiration. However, one area showed a systematic decrease in water levels. This occurred at the watershed of the two largest rivers in the Białowieża Forest. The findings indicate that watershed areas are most vulnerable to lowering the groundwater level due to climatic warming.

A Working Ring Test (WRT) was organised in the framework of the EU Regulation (EC) No 2152/2003 (“Forest Focus”) and of the UN/ECE Program “ICP Forests” to evaluate the overall performance of the laboratories monitoring atmospheric deposition and soil solution in European Forests. Seven natural samples of atmospheric deposition and soil solutions and 5 synthetic solutions were distributed to 52 laboratories, which analysed them using their routine methods. Thirteen variables are considered in this paper: pH, conductivity, calcium, magnesium, sodium, potassium, ammonium, sulfate, nitrate, chloride, total alkalinity, total dissolved nitrogen and dissolved organic carbon. For each variable, the relative standard deviation of the results was evaluated, after outlier rejection, to estimate the analytical error of the measurements. The results are evaluated considering the Quality Assurance/Quality Control (QA/QC) procedure included in the ICP Forests monitoring manual: consistency check of the data and use of control charts and internal standards. A Data Quality Objective (DQO) is defined for each of the variables and the number of data meeting the DQOs are discussed in relation to the QA/QC procedures adopted. Although 38% of the results did not meet the DQO, the laboratories adopting QA/QC procedures produced a larger proportion of results meeting the objective and a consistent part of the outliers could be detected a posteriori checking analyses consistence.

Compounds from the group of cationic surfactants are widely applied in household, industrial, cleaning, disinfectant, cosmetic and pharmaceutical products as their specific properties (antimicrobial, emulsifying, anticorrosion, softening). After use, cationic surfactants are disposed to wastewater-treatment plants and finally with effluent water to surface waters due to their incomplete degradation. Moreover, they can freely circulate in different environmental compartments including living organisms. It becomes indispensable to recognize in more detail behavior, fate and biological effects of cationic surfactants. This analytical problem can be solved with use sensitive and reliable analytical techniques at sample preparation step and final determination step. In recent years, during isolation analytes from environmental samples mainly were used liquid-liquid extraction (LLE) - liquid matrices or solid-liquid extraction (SLE) - solid matrices. This technique involves application of toxic solvents (chloroform), is time-consuming and interferences are co-extracted. Nowadays, in scientific centers are carried out research to replace this traditional technique. So far, the following techniques were applied: solid-phase extraction (SPE) or it modification (HF-LPME) - liquid samples; accelerated solvent extraction (ASE) and supercritical fluid extraction (SFE) - solid samples. During the determination of total content of cationic surface active agents in environmental samples were used a traditional spectrophotometry technique and potentiometric titration technique. But those techniques are susceptible of interferences on analysis results (anionic and non-ionic compounds). The chromatographic technique (liquid chromatography) applied at the final determination step gives possibility to determine individual cationic surfactants in solvent extracts of environmental samples. The LC systems coupled with mass spectrometers are most powerful tools during such analysis.

Climate change affects many elements of the natural environment and strongly influences the hydrology of rivers. In this study, we investigated trends in temperature, precipitation, and the water level characteristics in the small lowland river Lebiedzianka in northeastern Poland for the 50 year long period of observations (1970–2019). We recorded significant increase in air temperature and potential evapotranspiration, but the annual sum of precipitation did not change. We found significant downward trends for annual runoff. The results show a steady decrease in the number of days with high water levels. These changes caused by global warming will have a strong impact on forest habitats associated with high water levels and periodic inundations. In Europe, many of these precious habitats are protected under the Natura 2000 network as sites of high heritage value; nevertheless, their sustainability will be at risk due to the ongoing changes in their hydrological regime.

Global warming can lead to changes in groundwater levels in forested areas. Groundwater is the primary water source for ecosystems, so changes in groundwater levels, if directional and constant, can cause changes in vegetation and habitat character. In Białowieża National Park, a significant decline in the water table was observed at the beginning of the 20th century. The question therefore arose as to whether the changes that occurred at that time were permanent and whether the negative trend continued in such a clear direction in the following years. And whether the large water reservoir, which was built near the northern boundary of the Białowieża Forest, had an impact on the groundwater level in the forest areas. The study is based on measurements from 1985-2005 and 2022- 2023, taken in the same monitoring wells. Complete data was collected from 21 monitoring wells, of which seven each represent swamp, moist and fresh habitats. An analysis of groundwater levels between 1985 and 2005 showed an average decline of 0.08 m/10years in swamp habitats, 0.11 m/10years in moist habitats and 0.21 m/10years in fresh habitats. The prediction for the year 2023 showed a significantly greater decreasing groundwater level than the measurements. The measurements in 2022 and 2023 showed that the trend of falling water levels has slowed down in almost the entire study area, with water levels in recent years being similar to those at the beginning of the century. This was also confirmed by comparing years with similar precipitation: 2022 with 1986, 2002, 2004 and 2023 with 1999. This is due to the higher precipitation after 2005. In the period 2006-2023, precipitation in the hydrological years was on average 60 mm higher than in the period 1985-2005. Despite the clear trend towards rising air temperatures, the higher precipitation compensated for the higher evapotranspiration. However, one area showed a systematic decrease in water levels, this occurred at the watershed of the two largest rivers in the Białowieża Forest. It can be indicated that watershed areas are most vulnerable to lowering the groundwater level due to climatic heating.