Polydimethylsiloxane (PDMS) is one of the most promising elastomers due its remarkable proprieties such as good thermal stability, biocompatibility, corrosion resistance, flexibility, low cost, ease of use, chemically inertia, hyperplastic characteristics, and gas permeability. Thus, it can be used in areas such as microfluidic systems, biomedical devices, electronic components, membranes for filtering and pervaporation, sensors, and coatings. Although pure PDMS has low mechanical properties, such as low modulus of elasticity and strength, it can be improved by mixing the PDMS with other polymers and by adding particles or reinforcements. Fiber-reinforced PDMS has proved to be a good alternative to manufacturing flexible displays, batteries, wearable devices, tactile sensors, and energy harvesting systems. PDMS and particulates are often used in the separation of liquids from wastewater by means of porosity followed by hydrophobicity. Waxes such as beeswax and paraffin have proved to be materials capable of improving properties such as the hydrophobic, corrosion-resistant, thermal, and optical properties of PDMS. Finally, when blended with polymers such as poly (vinyl chloride-co-vinyl acetate), PDMS becomes a highly efficient alternative for membrane separation applications. However, to the best of our knowledge there are few works dedicated to the review and comparison of different PDMS composites. Hence, this review will be focused on PDMS composites, their respective applications, and properties. Generally, the combination of elastomer with fibers, particles, waxes, polymers, and others it will be discussed, with the aim of producing a review that demonstrates the wide applications of this material and how tailored characteristics can be reached for custom applications.

The examination of hyperelastic materials' behavior, such as polydimethylsiloxane (PDMS), is crucial for applications in areas as biomedicine and electronics. However, the limitations of hyperelastic models for specific stress scenarios, with stress concentration, are not well explored on the literature. To address this, firstly, three constitutive models were evaluated (Neo-Hookean, Mooney-Rivlin, and Ogden) using numerical simulations and Digital Image Correlation (DIC) analysis during a uniaxial tensile test. The samples were made of PDMS with stress concentration geometries (center holes, shoulder fillets, and edge notches). Results of ANOVA analysis showed that any of the three models can be chosen for numerical analysis of PDMS since no significant differences in suitability were found. Finally, the Ogen model was chosen to obtain the stress concentration factors for these geometries, a property which characterize how discontinuities change the maximum stress supported by an element. Our study provides new values for variables needed to analyze and design hyperelastic elements and produce a foundation for understanding PDMS stress-strain behavior.

Flexural and flammability evaluation of a new bio-based polyurethane foam (PUF) with alumina trihydrate (ATH) added as flame retardant were carried out. The PUF was obtained from a blend of vegetable oils. Flexural behavior of the polyurethane with different mass fractions of flame retardant (ATH) was investigated according to ASTM D790-17. Flammability tests were performed according to ASTM D3801-20 and ASTM D635-14 for the vertical and horizontal positions, respectively. The ATH addition influenced the flexural strength of the tested specimens, showing mean values for pure PUF and PUF with 50% of ATH were very close, but the highest value was obtained for PUF with 20% of ATH. Besides, the maximum strain value under flexural load was substantially reduced as the ATH mass increased, which was 11.4% for pure PUF and 3.38% for PUF with 50% of ATH. The flexural modulus increased with ATH incorporation up to 40% mass fraction. The obtained values for pure PUF, PUF with 40% of ATH and PUF with 50% of ATH specimens were 30.63 ± 1.95 MPa, 73.01 ± 2.82 MPa, and 62.16 ± 2.30 MPa, respectively. In addition, flammability test results presented better responses as the amount of ATH increased. PUF with 40% of ATH received V-2 classification, and PUF with 50% of ATH obtained HB classification. Therefore, the results for PUF with the addition of ATH show that the new bio-based material can be designed by using different mass fractions. Thus, this material becomes very useful for many types of applications, such as furniture and automobile industries, as well as sandwich structures and building constructions.

Polydimethylsiloxane (PDMS) is one of the best known elastomers and has been used in several areas of activity, due to its excellent characteristics and properties, such as biocompatibility, flexibility, optical transparency and chemical stability. Furthermore, PDMS modified with other materials promotes the desired changes to broaden its range of applications in various fields of science. However, the heating, mixing and degassing steps of the manufacturing process have not received much attention in recent years when it comes to blending with solid materials. For instance, PDMS has been extensively studied in combination with waxes, which are frequently in a solid state at room temperature and as a result the interaction and manufacturing process are extremely complex and can compromise the desired material. Thus, in this work it is proposed a multifunctional vacuum chamber (MVC) with the aim to improve and accelerate the manufacturing process of PDMS composites combined with additives, blends and different kinds of solid materials. The MVC developed in this work allows to control the mixing speed parameters, temperature control and internal pressure. In addition, it is a low cost equipment and can be used for other possible modifications with different materials and processes with the ability to control those parameters. As a result, samples fabricated by using the MVC can achieve a time improvement over 133% at the heating and mixing step and approximately 200% at the last degassing step. Regarding the complete manufacturing process, it is possible to achieve an improvement over 150%, when compared with the conventional manufacturing process. When compared to maximum tensile strength, specimens manufactured using the MVC have shown a 39% and 65% improvement in maximum strain. The samples have also shown a 9% improvement in transparency at room temperature and 12% at a temperature of about 75 °C. It should be noted that the proposed MVC can be used for other blends and manufacturing processes where it is desirable to control the temperature, agitation speed and pressure.