In the present review, we focused on the fundamental concepts of hydrogels—classification, the polymers involved, synthesis methods, types of hydrogels, properties, and applications of the hydrogel. Hydrogels can be synthesized from natural polymers, synthetic polymers, polymerizable synthetic monomers, and a combination of natural and synthetic polymers. Synthesis of hydrogels involves physical, chemical, and hybrid bonding. The bonding is formed via different routes, such as solution casting, solution mixing, bulk polymerization, free radical mechanism, radiation method, and interpenetrating network formation. The synthesized hydrogels have significant properties, such as mechanical strength, biocompatibility, biodegradability, swellability, and stimuli sensitivity. These properties are substantial for electrochemical and biomedical applications. Furthermore, this review emphasizes flexible and self-healable hydrogels as electrolytes for energy storage and energy conversion applications. Insufficient adhesiveness (less interfacial interaction) between electrodes and electrolytes and mechanical strength pose serious challenges, such as delamination of the supercapacitors, batteries, and solar cells. Owing to smart and aqueous hydrogels, robust mechanical strength, adhesiveness, stretchability, strain sensitivity, and self-healability are the critical factors that can identify the reliability and robustness of the energy storage and conversion devices. These devices are highly efficient and convenient for smart, light-weight, foldable electronics and modern pollution-free transportation in the current decade.

Natural gas is an important and fast-growing energy resource in the world and its purification is important in order to reduce environmental hazards and to meet the required quality standards set down by notable pipeline transmission, as well as distribution companies. Therefore, membrane technology has received great attention as it is considered an attractive option for the purification of natural gas in order to remove impurities such as carbon dioxide (CO₂) and hydrogen sulphide (H₂S) to meet the usage and transportation requirements. It is also recognized as an appealing alternative to other natural gas purification technologies such as adsorption and cryogenic processes due to its low cost, low energy requirement, easy membrane fabrication process and less requirement for supervision. During the past few decades, membrane-based gas separation technology employing hollow fibers (HF) has emerged as a leading technology and underwent rapid growth. Moreover, hollow fiber (HF) membranes have many advantages including high specific surface area, fewer requirements for maintenance and pre-treatment. However, applications of hollow fiber membranes are sometimes restricted by problems related to their low tensile strength as they are likely to get damaged in high-pressure applications. In this context, braid reinforced hollow fiber membranes offer a solution to this problem and can enhance the mechanical strength and lifespan of hollow fiber membranes. The present review includes a discussion about different materials used to fabricate gas separation membranes such as inorganic, organic and mixed matrix membranes (MMM). This review also includes a discussion about braid reinforced hollow fiber (BRHF) membranes and their ability to be used in natural gas purification as they can tackle high feed pressure and aggressive feeds without getting damaged or broken. A BRHF membrane possesses high tensile strength as compared to a self-supported membrane and if there is good interfacial bonding between the braid and the separation layer, high tensile strength, i.e., upto 170Mpa can be achieved, and due to these factors, it is expected that BRHF membranes could give promising results when used for the purification of natural gas.

In this study, ternary composites of polyaniline (PANI) with manganese dioxide (MnO₂) nanorods and carbon nanotubes (CNTs) were prepared by employing a hydrothermal methodology and in-situ oxidative polymerization of aniline. The morphological analysis by scanning electron microscopy showed that the MnO₂ possessed nanorod like structures in its pristine form, while in the ternary PANI@CNT/MnO₂ composite, coating of PANI over CNT/MnO₂, rods/tubes were evidently seen. The structural analysis by X-ray diffraction and X-ray photoelectron spectroscopy showed peaks corresponding to MnO₂, PANI and CNT, which suggested efficacy of the synthesis methodology. The electrochemical performance in contrast to individual components revealed the enhanced performance of PANI@CNT/MnO₂ composite due to the synergistic/additional effect of PANI, CNT and MnO₂ compared to pure MnO₂, PANI and PANI@CNT. The PANI@CNT/MnO₂ ternary composite exhibited an excellent specific capacity of 143.26 C g⁻¹ at a scan rate of 3 mV s⁻¹. The cyclic stability of the supercapattery (PANI@CNT/MnO₂/activated carbon)—consisting of a battery type electrode—demonstrated a gradual increase in specific capacity with continuous charge–discharge over ~1000 cycles and showed a cyclic stability of 119% compared to its initial value after 3500 cycles.

In this study, silver (Ag) and cobalt oxide (Co₃O₄) decorated polyaniline (PANI) fibers were prepared by the combination of in-situ aniline oxidative polymerization and the hydrothermal methodology. The morphology of the prepared Ag/Co₃O₄@PANI ternary nanocomposite was studied by scanning electron microscopy and transmission electron microscopy, while the structural studies were carried out by X-ray diffraction and X-ray photoelectron spectroscopy. The morphological characterization revealed fibrous shaped PANI, coated with Ag and Co₃O₄ nanograins, while the structural studies revealed high purity, good crystallinity, and slight interactions among the constituents of the Ag/Co₃O₄@PANI ternary nanocomposite. The electrochemical performance studies revealed the enhanced performance of the Ag/Co₃O₄@PANI nanocomposite due to the synergistic/additional effect of Ag, Co₃O₄ and PANI compared to pure PANI and Co₃O₄@PANI. The addition of the Ag and Co₃O₄ provided an extended site for faradaic reactions leading to the high specific capacity. The Ag/Co₃O₄@PANI ternary nanocomposite exhibited an excellent specific capacity of 262.62 C g⁻¹ at a scan rate of 3 mV s⁻¹. The maximum energy and power density were found to be 14.01 Wh kg⁻¹ and 165.00 W kg⁻¹, respectively. The cyclic stability of supercapattery (Ag/Co₃O₄@PANI//activated carbon) consisting of a battery type electrode demonstrated a gradual increase in specific capacity with a continuous charge–discharge cycle until ~1000 cycles, then remained stable until 2500 cycles and later started decreasing, thereby showing the cyclic stability of 121.03% of its initial value after 3500 cycles.

Methanol electrochemical oxidation in a direct methanol fuel cell (DMFC) is considered to be an efficient pathway for generating renewable energy with low pollutant emissions. NiO−CuO and Ni_0.95Cr_0.05O_2+δ thin films were synthesized using a simple dip-coating method and tested for the electro-oxidation of methanol. These synthesized electrocatalysts were characterized by X-ray diffraction spectroscopy (XRD), X-ray photoelectron spectroscopy (XPS), Scanning electron microscopy (SEM), Energy-dispersive X-ray spectroscopy (EDS), and Raman spectroscopy. Different electrochemical techniques were used to investigate the catalytic activity of these prepared electrocatalysts for methanol oxidation, including linear sweep voltammetry (LSV), electrochemical impedance spectroscopy (EIS), and chronoamperometry (CA). In the presence of 0.3 M methanol, the current densities of NiO−CuO and Ni_0.95Cr_0.05O_2+δ thin films were found to be 12.2 mA·cm⁻² and 6.5 mA·cm⁻², respectively. The enhanced catalytic activity of NiO−CuO and Ni_0.95Cr_0.05O_2+δ thin films may be a result of the synergistic effect between different metal oxides. The Chronoamperometry (CA) results of the mixed metal oxide thin films confirmed their stability in basic media. Furthermore, the findings of electrochemical impedance spectroscopy (EIS) of mixed metal oxide thin films demonstrated a lower charge transfer resistance as compared to the pure NiO, CuO, and Cr₂O₃ thin films.

The essential oil extracted from Melissa officinalis (MOEO) exhibits a wide range of therapeutic properties, including antioxidant, antibacterial, and antifungal activities. The current research aimed to analyze the mechanical, barrier, chemical, and antioxidant properties of pectin and collagen-based films. Hydrogel-based films loaded with varying concentrations of MOEO (0.1%, 0.15%, and 0.2%) were prepared by solvent-casting method, and their physicochemical as well as antioxidant properties were examined. GC-MS analysis revealed the presence of major components in MOEO such as 2,6-octadienal, 3,7-dimethyl, citral, caryophyllene, geranyl acetate, caryophyllene oxide, citronellal, and linalool. Fourier transform infrared (FTIR) results revealed the interaction between components of the essential oil and polymer matrix. Scanning electron microscopy (SEM) revealed that films loaded with the highest concentration (0.2%) of MOEO showed more homogeneous structure with fewer particles, cracks, and pores as compared to control film sample. MOEO-incorporated films exhibited higher elongation at break (EAB) (30.24–36.29%) and thickness (0.068–0.073 mm); however, they displayed lower tensile strength (TS) (3.48–1.25 MPa) and transparency (87.30–82.80%). MOEO-loaded films demonstrated superior barrier properties against water vapors. According to the results, the incorporation of MOEO into pectin–collagen composite hydrogel-based films resulted in higher antioxidant properties, indicating that MOEO has the potential to be used in active food packaging material for potential applications.