Ordinary Portland Cement (OPC) production consumes tremendous amounts of fresh water and energy and releases vast quantities of CO2 into the atmosphere. Not only would an alternative to OPC whose production requires no water, releases little CO2, and consumes less energy represent a transformative advance in the pursuit of industrial decarbonization, but the greater availability of safe drinking water would lead to significantly improved public health, particularly among vulnerable populations most at risk from contaminated water supply. For any OPC alternative to be adopted on any meaningful scale, however, its structural capabilities must meet or exceed those of OPC. An inverse vulcanization of brown grease, sunflower oil, and elemental sulfur (5:5:90 weight ratio) was successfully modified to afford the high-sulfur-content material SunBG90 in quantities > 1 kg, as was necessary for standardized ASTM and ISO testing. Water absorption (ASTM C140) and thermal conductivity (ISO 8302) values for SunBG90 (<1 wt% and 0.126 W·m−1·K−1, respectively) were 84% and 94% lower than those for OPC, respectively, suggesting that SunBG90 would be more resistant against freeze-thaw and thermal stress damage than OPC. Consequently, not only does SunBG90 represent a more environmentally friendly material than OPC, but its superior thermomechanical properties suggest that it could be a more environmentally robust material on its own merits, particularly for outdoor structural applications involving significant exposure to water and seasonal or day/night temperature swings.
The thermal performance of economical housing located in hot climates remains a pending subject, especially in emerging economies. A cellular concrete mixture was designed, considering its thermophysical properties, to apply the new material into building envelopes. The proposed materials have low density and thermal conductivity to be used as a nonstructural lightweight construction element. From the design stage, a series of wall systems based on cellular concrete was proposed. Whereas in the second phase, the materials were analyzed to obtain the potential energy savings using dynamic simulations. It is foreseen that the energy consumption in buildings located in these climates will continue to increase critically due to the temperature increase associated with climate change. The temperatures predicted mean vote (PMV), electric energy consumption, and CO2 emissions were calculated for three IPCC scenarios. These results will help to identify the impact of climate change on the energy use of the houses built under these weather conditions. The results show that if the conventional concrete blocks continue to be used, the air conditioning energy requirements will increase to 49% for 2030 and 61% by 2050. The proposed cellular concrete could reduce energy consumption between 15% and 28%, and these saving rates would remain in the future. The results indicate that it is necessary to drive the adoption of lightweight materials, so the impact of energy use on climate change can be reduced.
Se presenta el estudio de transferencia de calor en un muro de bloques de concreto con cavidades, para conocer su resistencia térmica. Se plantea un modelo teórico unidimensional en estado estacionario, considerando conducción, radiación y convección. El problema se resuelve numéricamente utilizando el método iterativo de Gauss-Seidel. La simulación se efectúa en forma horaria para dos días en condiciones extremas de temperatura ambiente. Se obtiene un valor promedio de la resistencia térmica de 0.18 °Cm²/W, con variaciones de 2.3% a 23%. Las aportaciones al flujo total de calor por cada mecanismo son de 25%, 19% y 56%, para conducción, convección y radiación respectivamente. El muro presenta valores de resistencia térmica que tienden a disminuir con el aumento de los diferenciales de temperatura, aspecto que desfavorece su uso para climas cálidos, siendo la radiación el mecanismo que más favorece la transferencia de calor.
The building sector is considered a key area for sustainable development, due to the potential to reduce greenhouse gas emissions in the numerous economic activities that this sector involves. A low-cost lightweight cementitious composite consisting in perlite mortar was fabricated and evaluated. The thermal conductivity and heat capacity of the proposed composite were tested in the laboratory. The lightweight composite was integrated into a prototypical house and its thermal performance was tested for two different arid climates during a typical meteorological year. A techno-economic analysis of this integration was carried out, which showed the lightweight system integration could reduce the energy demand up to 10.3% due to the decreased use of heating and cooling systems. The CO2 emissions associated with electricity and gas use on cooling and heating systems could be reduced up to 10.9%.