Flexible sensors are the essential foundations of pressure sensing, microcomputer sensing systems, and wearable devices. The flexible tactile sensor can sense stimuli by converting external forces into electrical signals. The electrical signals are transmitted to a computer processing system for analysis, realizing real-time health monitoring and human motion detection. According to the working mechanism, tactile sensors are mainly divided into four types—piezoresistive, capacitive, piezoelectric, and triboelectric tactile sensors. Conventional silicon-based tactile sensors are often inadequate for flexible electronics due to their limited mechanical flexibility. In comparison, polymeric nanocomposites are flexible and stretchable, which makes them excellent candidates for flexible and wearable tactile sensors. Among the promising polymers, conjugated polymers (CPs), due to their unique chemical structures and electronic properties that contribute to their high electrical and mechanical conductivity, show great potential for flexible sensors and wearable devices. In this paper, we first introduce the parameters of pressure sensors. Then, we describe the operating principles of resistive, capacitive, piezoelectric, and triboelectric sensors, and review the pressure sensors based on conjugated polymer nanocomposites that were reported in recent years. After that, we introduce the performance characteristics of flexible sensors, regarding their applications in healthcare, human motion monitoring, electronic skin, wearable devices, and artificial intelligence. In addition, we summarize and compare the performances of conjugated polymer nanocomposite-based pressure sensors that were reported in recent years. Finally, we summarize the challenges and future directions of conjugated polymer nanocomposite-based sensors.

Pressure sensors show significant potential applications in health monitoring, bio-sensing, electronic skin, and tactile perception. Consequently, tremendous research interest has been devoted to the development of high-performance pressure sensors. In this paper, recent progress on the polymer composite-based flexible pressure sensor is reviewed. The parameters of pressure sensors, including sensitivity, linear response range, detection limit, response speed, and reliability, are first introduced. Secondly, representative types of pressure sensors and relevant working principles are introduced and discussed. After that, the applications in human physiology monitoring, health monitoring, artificial skin, and self-powered smart system are listed and discussed in detail. Finally, the remaining challenges and outlook of polymer composite-based flexible sensors are summarized at the end of this review paper. This work should have some impact on the development of high-performance flexible pressure sensors.

Due to the unique two-dimensional structure and features of graphitic carbon nitride (g-C₃N₄), such as high thermal stability and superior catalytic property, it is considered to be a promising flame retardant nano-additive for polymers. Here, we reported a facile strategy to prepare cobalt/phosphorus co-doped graphitic carbon nitride (Co/P-C₃N₄) by a simple and scalable thermal decomposition method. The structure of Co/P-C₃N₄ was confirmed by scanning electron microscopy (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The carbon atoms in g-C₃N₄ were most likely substituted by phosphorous atoms. The thermal stability of polylactide (PLA) composites was increased continuously with increasing the content of Co/P-C₃N₄. In contrast to the g-C₃N₄, the Polylactide (PLA) composites containing Co/P-C₃N₄ exhibited better flame retardant efficiency and smoke suppression. With the addition of 10 wt % Co/P-C₃N₄, the peak heat release rate (PHRR), carbon dioxide (CO₂) production (PCO2P) and carbon oxide (CO) production (PCOP) values of PLA composites decreased by 22.4%, 16.2%, and 38.5%, respectively, compared to those of pure PLA, although the tensile strength of PLA composites had a slightly decrease. The char residues of Co/P-C₃N₄ composites had a more compact and continuous structure with few cracks. These improvements are ascribed to the physical barrier effect, as well as catalytic effects of Co/P-C₃N₄, which inhibit the rapid release of combustible gaseous products and suppression of toxic gases, i.e., CO.