Ultrathin, molecular sieving membranes composed of microporous materials offer great potential to realize high permeances and selectivities in separation applications, but strategies for their production have remained a challenge. Here we show a route for the scalable production of nanometre-thick metal–organic framework (MOF) molecular sieving membranes, specifically via gel–vapour deposition, which combines sol–gel coating with vapour deposition for solvent-/modification-free and precursor-/time-saving synthesis. The uniform MOF membranes thus prepared have controllable thicknesses, down to ~17 nm, and show one to three orders of magnitude higher gas permeances than those of conventional membranes, up to 215.4 × 10⁻⁷ mol m⁻² s⁻¹ Pa⁻¹ for H₂, and H₂/C₃H₈, CO₂/C₃H₈ and C₃H₆/C₃H₈ selectivities of as high as 3,400, 1,030 and 70, respectively. We further demonstrate the in situ scale-up processing of a MOF membrane module (30 polymeric hollow fibres with membrane area of 340 cm²) without deterioration in selectivity.

We present here a simple solvothermal method to fabricate metal–organic framework NH₂-MIL-53(Al) crystals with controllable size and morphology just by altering the ratio of water in the DMF–water mixed solvent system without the addition of any surfactants or capping agents. With increasing the volume ratio of water in the mixed solvents, a series of NH₂-MIL-53(Al) crystals with different sizes and morphologies were synthesized. The average size of the smallest crystal is 76 ± 20 nm, which provides us a simple and environmentally friendly way to prepare nanoscale MOFs. The largest BET surface area of these samples is 1882 m² g⁻¹ that is mainly contributed by its micropore surface area, and its corresponding micropore volume is 0.83 cm³ g⁻¹, which have greatly extended its application in the fields of gas adsorption and postsynthetic modification. All these samples were characterized by SEM, XRD, N₂ adsorption/desorption, TGA and FT-IR. Then a mechanism for the impact of the water ratio on the crystal size and morphology is presented and discussed.

High-quality amino-functionalized Ti₃C₂T_x MXene (alk-MXene-NH₂) nanosheets were successfully synthesized by a facile alkalization-grafting modification for lead adsorption.

The development of simple, versatile strategies for the synthesis of metal-organic framework (MOF)-derived membranes are of increasing scientific interest, but challenges exist in understanding suitable fabrication mechanisms. Here we report a route for the complete transformation of a series of MOF membranes and particles, based on multivalent cation substitution. Through our approach, the effective pore size can be reduced through the immobilization of metal salt residues in the cavities, and appropriate MOF crystal facets can be exposed, to achieve competitive molecular sieving capabilities. The method can also be used more generally for the synthesis of a variety of MOF membranes and particles. Importantly, we design and synthesize promising MOF membranes candidates that are hard to achieve through conventional methods. For example, our CuBTC/MIL-100 membrane exhibits 89, 171, 241 and 336 times higher H₂ permeance than that of CO₂, O₂, N₂ and CH₄, respectively.

The adsorption ability of zirconium-based MOF UiO-66 for Congo red can be greatly promoted via the doping of Ti⁴⁺.

A facile controlled interfacial polymerization strategy was proposed for the synthesis of novel thin film nanocomposite (TFN) membranes for enhanced nanofiltration performance. UiO-66 nanoparticles were aminated and pre-immobilized onto a polymer substrate via polydopamine (PDA) coating to achieve a continuous and defect-free polyamide dense layer. The mediation of the PDA coating could not only enhance the structural stability of TFN nanofiltration membranes, but also improve the dispersion and anchorage of UiO-66-NH₂, thus closely fixing the position of UiO-66-NH₂ nanoparticles on the polymer substrate. Moreover, since the amino group (–NH₂) further reacted with PDA via Michael addition or Schiff base reaction, the in situ mutual reaction reduced the nanoparticle losses significantly during the draining off of the monomer solution in the fabrication process, which effectively cut down the actual dosage. The results showed that the PDA interlayer could induce the tight attachment of the PA layer to the support, enhancing the structural stability of TFN membranes. Furthermore, the dosage of UiO-66-NH₂ in the as-prepared TFN membranes could also be decreased to as low as 0.01 w/v%, which was nearly a 10–20-fold reduction in the required amount of UiO-66-NH₂ for the synthesis. The fabricated TFN/UiO-66-NH₂ membranes exhibited very high water permeance and competitive salt rejections in cross-flow nanofiltration, which shows the huge potential for the application of novel TFN membranes with controlled nanoparticle incorporation in industrial separation.