The International Commission on Radiological Protection (ICRP) issued its Publication 137, Occupational Intakes of Radionuclides: Part 3 in which the radon equilibrium factor is fixed as 0.4 for tourist caves; however, several studies have reported a different value for the factor and its seasonal variation has also been observed. In this study, the radon concentration, equilibrium equivalent radon concentration and meteorological data were measured, and the equilibrium factor was evaluated in a tourist cave, Gyokusen-do Cave located in the southern part of Okinawa Island in southwestern Japan. Radon concentrations were measured with an AlphaGUARD and their corresponding meteorological data were measured with integrated sensors. Equilibrium equivalent radon concentration was measured with a continuous air monitor. The measured radon concentrations tended to be low in winter and high in summer, which is similar to previously obtained results. By contrast, the equilibrium factor tended to be high in winter (0.55 ± 0.09) and low in summer (0.24 ± 0.15), with a particularly large fluctuation in summer. It was concluded that measurements in different seasons are necessary for proper evaluation of radon equilibrium factor.

The aim of this study is to get a better understanding of the variation of tritium concentration for monthly precipitation collected at Okinawa Island, the southwestern part of Japan. Tritium concentrations of monthly precipitation in Okinawa from June 2014 to December 2019 ranged from 0.05 to 0.27 Bq L^–1. Seasonal patterns of tritium concentration are determined with higher in spring and lower in autumn. The results of δD and δ¹⁸O indicate that the tritium concentration in winter is affected by the dilution effect of isotopes over the East China Sea. The stable isotope ratios and major ion components of tritium concentrations in monthly precipitation on Okinawa Island suggest that tritium concentrations are strongly influenced by the surrounding ocean throughout the year due to the dynamics of air masses. This study makes a significant contribution to the understanding of the behavior of tritium concentrations in monthly precipitation under the special environment of subtropical island regions. In order to investigate the source of high tritium concentration in monthly precipitation in the future, it is necessary to understand the supply of tritium from the stratosphere to the troposphere due to vertical convection of the atmosphere.

This study aimed at understanding the background concentration level of tritium in precipitation in southern Japan, where precipitation samples were collected monthly in 2022 in Okinawa and Kagoshima. Tritium concentration in monthly precipitation collected in Okinawa since 2014 ranged from 0.05 to 0.39 Bq per L with the mean value (2015–2022) of 0.15 ± 0.06 Bq per L. That of Kagoshima since 2022 ranged from < 0.11 to 0.58 Bq per L with the mean value of 0.30 ± 0.13 Bq per L. Our observed values were summarized with reported values, from which a clear latitude effect for tritium concentration was found in precipitation of southern Japan.

In this study, to get a better understanding in characterizing groundwater and ensure its effective management, the radon concentrations in water samples were measured through Ryukyu limestone in southern Okinawa Island, Japan. Water samples were collected from a limestone cave (Gyokusendo cave, dropping water) and two springs (Ukinju and Komesu, spring water), and the radon concentrations were measured by liquid scintillation counters. The radon concentrations in the samples from the Gyokusendo cave, and Ukinju and Komesu springs were 10 ± 1.3 Bq L⁻¹, 3.2 ± 1.0 Bq L⁻¹, and 3.1 ± 1.1 Bq L⁻¹, respectively. The radon concentrations showed a gradually increasing trend from summer to autumn and decreased during winter. The variation of radon concentrations in the dripping water sample from the Gyokusendo cave showed a lagged response to precipitation changes by approximately 2–3 months. The estimated radon concentrations in the dripping water sample were calculated with the measured radon concentrations from the dripping water obtained during the study period. Based on our results, groundwater in the Gyokusendo cave system was estimated to percolate through the Ryukyu limestone in 7–10 days, and the residence time of groundwater in the soil above Gyokusendo cave was estimated to be approximately 50–80 days. This work makes a valuable contribution to the understanding of groundwater processes in limestone aquifers, which is essential for ensuring groundwater sustainability.

This paper presents an evaluation of a rapid pretreatment method for tritium analysis, that uses ion exchange resins (the batch method). The standard water samples were prepared with river water collected in Okinawa, Japan. Powdex resin was used in this study, which is an ion exchange resins in the form of powder beads. First, 100 mL of the standard sample was stirred with the cation exchange (PCH) and anion exchange (PAO) resins, as well as with activated carbon. To determine the optimal stirring time, we tested stirring times of 5, 10, 20 and 30 min. Additionally, to determine a suitable amount of ion exchange resin for environmental water samples, variations in the amount of resin and activated carbon were tested. Under the conditions of Experiment-3 (0.3 g, 0.3 g and 0.6 g of PCH, PAO and activated carbon, respectively) and with a stirring time of 5 min, electrical conductivity values of less than 1 mSm⁻¹ were achieved. These results demonstrate the effectiveness of the removal of impurities in the sample water by ion exchange resins and confirm that such an effect can be achieved during a short period of time (i.e., in 5 min).