Carbon nanotubes (CNTs) can improve the storage properties of modified asphalt by enhancing the interfacial adhesion of recycled polyethylene (RPE) and base asphalt. In this study, the interaction of CNT/RPE asphalt was investigated using molecular dynamics simulation. The base asphalt was examined using a 12-component molecular model and verified by assessing the following properties: its four-component content, elemental contents, radial distribution function (RDF) and glass transition temperature. Then, the adhesion properties at the interface of the CNT/RPE-modified asphalt molecules were studied by measuring binding energy. The molecular structural stability of CNTs at the interface between RPE and asphalt molecules was analyzed through the relative concentration distribution. The motion of molecules in the modified asphalt was studied in terms of the mean square displacement (MSD) and diffusion coefficient. The results showed that CNTs improved the binding energy between RPE and base asphalt. CNTs not only weakened the repulsion of RPE with asphaltenes and resins, but also promoted the interaction of RPE with light components, which facilitated the compatibility of RPE with the base asphalt. The change in the interaction affected the molecular motion, and the molecular diffusion coefficient in the CNT/RPE-modified asphalt system was significantly smaller than that of RPE-modified asphalt. Moreover, the distribution of the asphaltene component was promoted by CNTs, resulting in the enhancement of the storage stability of RPE-modified asphalt. The property indexes indicated that the storage stability was significantly improved by CNTs, and better viscoelastic properties were also observed. Our research provides a foundation for the application of RPE in pavement engineering.

Interfacing and compatibility are the most challenging issues that affect the performance of polymer modified asphalt. Mechanisms of interfacial enhancemen

The recycling of waste tires is a major environmental problem facing mankind, and the addition of crumbed waste tire rubber (CWTB) to the base asphalt is an extremely promising recycling method. However, the modification mechanism of CWTB to asphalt is not well understood, which restricts the development of CWTB modified asphalt. In this study, the mechanism of CWTB modification of asphalt was explored by dynamic mechanical analysis (DMA), fluorescence microscopy, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and molecular dynamic (MD) simulations. After verifying the asphalt reasonableness using glass transition temperature, CWTB modified asphalt was simulated and experimented. The results showed that CWTB enhanced the high temperature performance of the base asphalt. The microscopic mechanism by which this phenomenon occurs is that CWTB has the largest binding energy with the aromatics (1150–1350 kcal/mol), followed by the saturates (740–830 kcal/mol), followed by the resins (90–330 kcal/mol), and the smallest binding energy with the asphaltenes (100–140 kcal/mol), which causes CWTB to absorb the light components of the asphalt (aromatics and saturates). In addition, the introduction of CWTB reduces the diffusion coefficient of asphalt. In this process, CWTB will gradually swell, which causes CWTB to bind more and more tightly with the base asphalt, and eventually the good high temperature performance of CWTB is transferred to the base asphalt. The macroscopic manifestation of this process is that the rutting factor of CWTB-modified asphalt is significantly higher than that of virgin asphalt. This study can provide basic theoretical support for the application of CWTB-modified asphalt.

In summer, black asphalt pavement can absorb a considerable amount of solar radiation, which causes its temperature to rise. Heated asphalt pavement can aggravate the urban heat island (UHI) effect and transfer heat downward, which may cause the problem of permafrost thawing beneath pavements. The objective of this study was to develop a novel cool coating layer (CCL) with high near-infrared reflectance and heat insulation to make the surface of asphalt pavement cool. A self-developed test device and method was established to evaluate cooling effects. Based on the experimental results, the optimal coating can cool asphalt pavement by 11.21 °C when the radiation striking the sample surface is 650 W/m². This coating, called the composite cool coating layer (CCCL), is composed of the following materials: polyurethane resin, rutile TiO₂ of 18%, hollow glass microspheres of 12%, and copper chromite black spinel of 0.7%. Silicon carbide particles of 1 kg/m² can help the CCCL achieve satisfactory antiskid performance. In conclusion, CCCL can effectively inhibit the absorption of solar radiation and reduce the flow of thermal energy downward without sacrificing skid resistance.