PrBaFe 1.9 Sn 0.1 O 5+δ shows excellent redox stability, high electrical conductivity, and ASR of a symmetrical cell as low as of 0.095–0.285 Ω cm 2 from 850–750 °C in wet hydrogen, better than or comparable to the best of ceramic anodes in the open literature.
Porous electrode is the critical component of solid-oxide fuel cells (SOFCs) and provides a functional material backbone for multi-physicochemical processes. Model based electrode designs could significantly improve SOFC performance. This task is usually performed via parameter studies for simple case and assumed property distributions for graded electrodes. When nonlinearly coupled multiparameters of electrodes are considered, it could be very difficult for the model based parameter study method to effectively and systematically search the design space. In this research, the optimization approach with a genetic algorithm is demonstrated for this purpose. An anode-supported proton conducting SOFC integrated with a fuel supply system is utilized as a physical base for the model development and the optimization design. The optimization results are presented, which are difficult to obtain for parametric study method.
26 September 2011 in Journal of Fuel Cell Science and Technology
Suitable porous electrode design may play a significant role in the performance enhancement of solid oxide fuel cells (SOFCs). In this paper a genetic algorithm optimization method is employed to design electrodes based on a 2D planar SOFC model development. The objective is to find suitable porosities and particle sizes distributions for both anode and cathode electrodes so that the cell performance can be maximized. The results indicate that the optimized heterogeneous morphology may better improve SOFC performance than the homogeneous counterpart, particularly under relatively high current density conditions. The optimization results are dependent on the operating conditions. The effects of inlet mass flow rates and fuel compositions are investigated. The proposed approach provides a systematical method for electrode microstructure designs of high performance SOFCs.
31 May 2010 in International Journal of Hydrogen Energy