The effect of chemical modification of submicron barium titanate particles by the deposition of MxOy (x = Ti, Co, Ni) oxide layers from aqueous solutions of the corresponding precursors is studied upon the surface properties of modified BaTiO3 particles and dielectric permittivity of organo-inorganic composites obtained by their dispersion in the matrix of cyanoethyl ester of polyvinyl alcohol and useful in electroluminescent light sources. It is shown that a significant increase (by about 25%) of the dielectric permittivity is observed only when adding Nb2O5, in comparison with a similar composite which contains unmodified BaTiO3. A correlation is found between the dielectric permittivity of the organo-inorganic composites and the presence of Brensted neutral and basic centers with pKa = 6−13, localized on the surface of a filler, being capable of interacting with the polymer matrix. It is shown that an increase of the dielectric permittivity upon deposition of niobium oxide on the surface of BaTiO3 is caused by formation of such centers and modification of the surface layer structure of BaTiO3 particles, with transformation of rutile-like Ti-O bonds to anataselike ones.
Low-temperature synthesis methods are used to produce nanoceramic materials for electrodes of the following ionistors: (ZrO2)0.6(In2O3)0.4, praseodymium cobaltite, as well as neodymium, lanthanum, and nickel chromites; they operate in the presence of an ion-conducting phosphorosilicate separator membrane and phosphate impregnation. Film electrodes of ionistors are fabricated that consist of nanocrystalline oxide materials deposited as a thin film on a porous electroconductive metal substrate, i.e., foamed nickel. The MnO2-foamed nickel electrode has a specific capacity of 45.0 F g−1, which is compared with that of industrial supercapacitors.
A synthesis technology for ceramics based on a tetragonal solid solution of zirconia in ZrO2-Y2O3-CeO2 and ZrO2-Y2O3-Al2O3 systems with a high degree of tetragonality (∼1.436) and an average crystal size of 45–70 nm has been developed; it can be recommended for producing bioceramics in restorative dentistry.
30 April 2019 in Journal of Sol-Gel Science and Technology