This experimental study presents the effect of different surfactants on micro-scale carbon fiber (CFs) distribution into carbon fiber reinforced cement-based composites (CFRC) in terms of flexural and compressive strength, stiffness, flexural toughness, and strain-sensing ability. Conducting a narrative review of the literature focusing on the fibers’ separation, this paper follows a methodology introducing a combination of mechanical and chemical carbon fibers dispersion, as well as the different mixing processes (wet or dry). Three types of surfactants: Carboxymethyl cellulose (CMC), cellulose nanocrystal (CNC), and superplasticizer (SP), were applied to evaluate the CFs distribution in the cement paste matrix. Compressive and flexural strength, modulus of elasticity, and ductility of the cement-based composites (CFRC) reinforced with 0.5 wt.% CFs were investigated by three-point bending and compressive tests; flexure tests were also conducted on notched 20 × 20 × 80 mm specimens using the Linear Elastic Fracture Mechanics (L.E.F.M.) theory. Moreover, the electrical conductivity and the piezoresistive response were determined by conducting electrical resistance measurements and applying compressive loading simultaneously. The results clearly reveal that the CFs/SP solution or the CFs’ dry incorporation led to a significant enhancement of flexural strength by 32% and 23.7%, modulus of elasticity by 30% and 20%, and stress-sensing ability by 20.2% and 18.2%, respectively. Although the wet mixing method exhibits improved mechanical and electrical conductivity performance, constituting an adequate strain and crack sensor, the authors propose dry mixing as the most economical method, in addition to the enhanced mechanical and electrical responses. The authors recommend an effective method for structural health monitoring systems combining an economical CFs insertion in cementitious smart sensors with great mechanical and self-sensing responses.

The current paper presents the results of an experimental study of carbon nano-, micro-, and hybrid-modified cementitious mortar to evaluate mechanical performance, energy absorption, electrical conductivity, and piezoresistive sensibility. Three amounts of single-walled carbon nanotubes (SWCNTs), namely 0.05 wt.%, 0.1 wt.%, 0.2 wt.%, and 0.3 wt.% of the cement mass, were used to prepare nano-modified cement-based specimens. In the microscale modification, 0.05 wt.%, 0.5 wt.%, 1.0 wt.% carbon fibers (CFs) were incorporated in the matrix. The hybrid-modified cementitious specimens were enhanced by adding optimized amounts of CFs and SWCNTs. The smartness of modified mortars, indicated by their piezoresistive behavior, was investigated by measuring the changes in electrical resistivity. The effective parameters that enhance the composites’ mechanical and electrical performance are the different concentrations of reinforcement and the synergistic effect between the types of reinforcement used in the hybrid structure. Results reveal that all the strengthening types improved flexural strength, toughness, and electrical conductivity by about an order of magnitude compared to the reference specimens. Specifically, the hybrid-modified mortars presented a marginal reduction of 1.5% in compressive strength and an increase in flexural strength of 21%. The hybrid-modified mortar absorbed the most energy, 1509%, 921%, and 544% more than the reference mortar, nano-modified mortar, and micro-modified mortar, respectively. The change rate of impedance, capacitance, and resistivity in piezoresistive 28-day hybrid mortars improved the tree ratios by 289%, 324%, and 576%, respectively, for nano-modified mortars and by 64%, 93%, and 234%, respectively, for micro-modified mortars.

When a seismic load is applied horizontally or laterally on unreinforced masonry walls (URM), the walls behave in two different ways, viz., in-plane (IP) and out-of-plane (OoP). This review beneficially provides a literature overview of the most cited research papers on Scopus, and the database is evaluated with VOSviewer software for scientometric analysis. This review paper delves into the practical applications of various types of reinforcement for masonry walls, specifically focusing on four commonly used systems: externally bonded strengthening techniques using fiber-reinforced polymers (FRP), steel-reinforced grout (SRG), fabric-reinforced cementitious mortar (FRCM), and textile-reinforced mortars (TRM). The main objective of the paper is to explore the efficacy of these reinforcement techniques in strengthening masonry walls, and to provide a comprehensive overview of their respective advantages and limitations. A further detailed study of the extent of the literature is performed about the effect of the different strengthening systems on the mechanical properties of different categories of masonry walls like a cement block, stone, and clay brick are described and categorized. The efficiency of OoP strengthening can depend on various factors, such as the types of masonry units, the rendering mortar, the type of strengthening system, the bond between the different materials interfaces, the geometry of the wall, and the loading conditions. By utilizing the practical method of Dematel (Decision-making trial and evaluation laboratory) analysis, this review can delve deeply into the impact of various factors and precisely identify the crucial components of the cause-and-effect connection. The results indicate that the bond between material interfaces is the critical factor. This meticulous and structured review offers valuable perspectives for researchers and engineers, showcasing current research trends and presenting potential avenues for future exploration.

Computational approaches could provide a viable and cost-effective alternative to expensive experiments for accurately evaluating the nonlinear constitutive behavior of cementitious nanocomposite materials. In the present study, the mechanical properties of cement paste reinforced with multi-wall carbon nanotubes (MWCNTs) are examined experimentally and numerically. A multiscale computational approach is adopted in order to verify the experimental results. For this scope, a random sequential adsorption algorithm was developed to generate non-overlapping matrix-inclusion three-dimensional (3D) representative volume elements (RVEs), considering the inclusions as straight elements. Nonlinear finite element analyses (FEA) were performed, and the homogenized elastic and inelastic mechanical properties were computed. The use of a multiscale computational approach to accurately evaluate the nonlinear constitutive behavior of cementitious materials has rarely been explored before. For this purpose, the RVEs were analyzed both in pure tension and compression. Young’s modulus as well compressive and tensile strength results were compared and eventually matched the experimental values. Moreover, the effect of MWCNTs on the nonlinear stress–strain behavior of reinforced cement paste was noted. Subsequently, three-point bending tests were conducted, and the stress–strain behavior was verified with FEA in the macro scale. The numerical modeling reveals a positive correlation between the concentration of MWCNTs and improved mechanical properties, assuming ideal dispersion. However, it also highlights the impact of practical limitations, such as imperfect dispersion and potential defects, which can deteriorate the mechanical properties that are observed in the experimental results. Among the different cases studied, that with a 0.1 wt% MWCNTs/CP composite demonstrated the closest agreement between the numerical model and the experimental measurements. The numerical model achieved the best accuracy in estimating the Young’s modulus (underestimation of 13%), compressive strength (overestimation of 1%), and tensile strength (underestimation of 6%) compared to other cases. Overall, these numerical findings contribute significantly to understanding the mechanical behavior of the nanocomposite material and offer valuable guidance for optimizing cement-based composites for engineering applications.

Microstructural characteristics and mechanical properties of nano-reinforced cementitious mortar using multi-walled carbon nanotubes (MWCNTs), dispersed in an aqueous solution by applying ultra-solicitation, were studied using X-ray microcomputed tomography (micro-CT), an innovative, non-destructive technique. This useful method was applied for characterizing the cementitious composites’ spatial micro-pore structure. The changes due to the MWCNTs’ integration into the mortar matrix and their effects were studied. The analysis revealed that the density and porosity values processed by micro-CT imaging are crucial parameters. They correlated with the mechanical strength of 2 × 2 × 8 prisms (in cm) in order to evaluate the dispersion effect of the different nanotube concentrations, 0.1 wt.%, 0.2 wt.%, 0.3 wt.%, and 0.5 wt.% by the mass of cement. The results highlight the linear correlation of the density, porosity, and spatial pores’ distribution obtained by the micro-CT 3D in vivo imaging of the microstructure, with the nanotubes’ concentration and flexural and compressive strengths. This investigation was achieved by proving that a deeper understanding of the complex nano- and microstructures can be utilized for the design of advanced cementitious composites at multiple scales.