Shape memory polymers (SMPs) are polymers which ''remember'' their original shape and can return to it after deformation, if an external stimulus—often an increased temperature – is applied. Some SMPs can be 3D printed, typically by fused deposition modeling (FDM). The most well‐known SMP is poly(lactic acid), which belongs to the most often used materials in FDM 3D printing. There are; however, many more SMPs which can be 3D printed to combine the possibilities to prepare new, sophisticated shapes with the opportunity to restore these shapes after undesirable or intentional deformation. This review gives an overview of several 3D printable SMPs, their mechanical characteristics and their possible applications.
Biosignals often have to be detected in sports or for medical reasons. Typical biosignals are pulse and ECG (electrocardiogram), breathing, blood pressure, skin temperature, oxygen saturation, bioimpedance, etc. Typically, scientists attempt to measure these biosignals noninvasively, i.e., with electrodes or other sensors, detecting electric signals, measuring optical or chemical information. While short-time measurements or monitoring of patients in a hospital can be performed by systems based on common rigid electrodes, usually containing a large amount of wiring, long-term measurements on mobile patients or athletes necessitate other equipment. Here, textile-based sensors and textile-integrated data connections are preferred to avoid skin irritations and other unnecessary limitations of the monitored person. In this review, we give an overview of recent progress in textile-based electrodes for electrical measurements and new developments in textile-based chemical and other sensors for detection and monitoring of biosignals.
Polylactic acid (PLA) belongs to the few thermoplastic polymers that are derived from renewable resources such as corn starch or sugar cane. PLA is often used in 3D printing by fused deposition modeling (FDM) as it is relatively easy to print, does not show warping and can be printed without a closed building chamber. On the other hand, PLA has interesting mechanical properties which are influenced by the printing parameters and geometries. Here we present shape-memory properties of PLA cubes with different infill patterns and percentages, extending the research reported before in a conference paper. We investigate the material response under defined quasi-static load as well as the possibility to restore the original 3D printed shape. The quasi-static flexural properties are linked to the porosity and the infill structure of the samples under investigation as well as to the numbers of closed top layers, examined optically and by simulations. Our results underline the importance of designing the infill patterns carefully to develop samples with desired mechanical properties.
Shielding of instruments and humans from electromagnetic interference (EMI) has become increasingly important during the last decades due to more and more machines and devices radiating electromagnetic waves. While several applications can use rigid shields, more flexibility is enabled by developing bendable, drapable, ideally even stretchable EMI shielding. Textile fabrics can have these properties, combined with potentially good mechanical properties, depending on the textile structure and the chosen material. On the other hand, the necessary physical properties, especially conductivity and magnetic properties, cannot be taken for granted in normal textile fabrics. These properties have to be added by conductive yarn or layer coatings, integration of conductive or magnetic fibers, producing intrinsically conductive or magnetic fibers, etc. The article gives a critical comparison of the properties of materials typically used for this purpose, such as intrinsically conductive polymers, metal-coated fabrics and metal wires, MXene coatings, MXene fibers, carbon coatings, and fibers. The review concentrates on thematically suitable papers found in the Web of Science and Google Scholar from the last five years and shows that especially MXenes are highly investigated recently due to their high conductivity and EMI shielding effectiveness, while other conductive and magnetic coatings and fibers are nevertheless still interesting for the preparation of EMI shielding textile fabrics.
The emerging technology of 3D printing can not only be used for rapid prototyping, but will also play an important role in space exploration. Additive manufactured parts can be used in diverse space applications, such as magnetic shields, heat pipes, thrusters, etc. Three-dimensional printed parts offer reduced mass, high possible complexity, and fast printability of custom-made objects. On the other hand, materials which are not excessively damaged by the harsh conditions in space and are also printable by available technologies are not abundantly available. This review gives an overview of recent metal additive manufacturing technologies and their possible applications in space, with a focus on satellites and rockets, highlighting already applied technologies and materials and gives an outlook on possible future applications and challenges.
Three-dimensional printing enables building objects shaped with a large degree of freedom. Additional functionalities can be included by modifying the printing material, e.g., by embedding nanoparticles in the molten polymer feedstock, the resin, or the solution used for printing, respectively. Such composite materials may be stronger or more flexible, conductive, magnetic, etc. Here, we give an overview of magnetic composites, 3D-printed by different techniques, and their potential applications. The production of the feedstock is described as well as the influence of printing parameters on the magnetic and mechanical properties of such polymer/magnetic composites.