Ammonium polyphosphate (APP) as a chelated and controlled-release fertilizer has been widely used in agriculture, and its hydrolysis process is of significance for its storage and application. In this study, the hydrolysis regularity of APP affected by Zn2+ was explored systematically. The hydrolysis rate of APP with different polymerization degrees was calculated in detail, and the hydrolysis route of APP deduced from the proposed hydrolysis model was combined with the conformation analysis of APP to reveal the mechanism of APP hydrolysis. The results show that Zn2+ decreased the stability of the P–O–P bond by causing a conformational change in the polyphosphate due to chelation, which in turn promoted APP hydrolysis. Meanwhile, Zn2+ caused the hydrolysis of polyphosphates with a high polymerization degree in APP to be switched from a terminal chain scission to an intermediate chain scission or various coexisting routes, affecting orthophosphate release. This work provides a theoretical basis and guiding significance for the production, storage, and application of APP.

Water contamination is often reported in agriculturally intensive areas such as the Indo-Gangetic Plain (IGP) in south-eastern Asia. We evaluated the impact of the organic and conventional farming of basmati rice on water quality during the rainy season (July to October) of 2011 and 2016 at Kaithal, Haryana, India. The study area comprised seven organic and seven conventional fields where organic farming has been practiced for more than two decades. Water quality parameters used for drinking (nitrate, NO₃; total dissolved solids (TDS); electrical conductivity (EC) pH) and irrigation (sodium adsorption ratio (SAR) and residual sodium carbonate (RSC)) purposes were below permissible limits for all samples collected from organic fields and those from conventional fields over the long-term (~15 and ~20 years). Importantly, the magnitude of water NO₃ contamination in conventional fields was approximately double that of organic fields, which is quite alarming and needs attention in future for farming practices in the IGP in south-eastern Asia.