The proton exchange membrane fuel cell (PEMFC) is the fastest growing fuel cell technology on the market. Due to their sustainable nature, PEMFCs are widely adopted as a renewable energy resource. Fabricating a PEMFC is a costly process; hence, mathematical modeling and simulations are necessary in order to fully optimize its performance. Alongside this, the feasibility of a waste heat recovery system based on the organic Rankine cycle is also studied and power generation for different operating conditions is presented. The fuel cell produces a power output of 1198 W at a current of 24A. It has 50% efficiency and hence produces an equal amount of waste heat. That waste heat is used to drive an organic Rankine cycle (ORC), which in turn produces an additional 428 W of power at 35% efficiency. The total extracted power hence stands at 1626 W. MATLAB/Simulink R2016a is used for modeling both the fuel cell and the organic Rankine cycle.