With the rapid development of urban modernization, traffic congestion, travel delays, and other related inconveniences have become central features in people’s daily lives. The development of subway transit systems has alleviated some of these problems. However, numerous underground subway stations lack adequate fire safety protections, and this can cause rescue difficulties in the event of fire. Once the fire occurs, there will be huge property losses and casualties. In addition, this can have a vicious impact on sustainable development. Therefore, in order to make prevention in advance and implement targeted measures, we should quantify the risk and calculate the fire risk value. In this study, through consulting experts and analysis of data obtained from Changzhou Railway Company and the Emergency Management Bureau, the fire risk index system of subway stations was determined. We calculated the index weight by selecting the combination weighting method of game theory to eliminate the limitations and dependence of subjective and objective evaluation methods. The idea of relative closeness degree in TOPSIS method iwas introduced to calculate the risk value of each subway station. Finally, the subway station risk value model was established, and the risk values for each subway station were calculated and sorted. According to expert advice and the literature review, we divided the risk level into five levels, very high; high; moderate; low and very low. The results shown that 2 subway stations on Line 1 have very high fire risk, 2 subway stations on Line 1 have high fire risk, 2 subway stations on Line 1 have moderate fire risk, 8 subway stations on Line 1 have low fire risk, and 13 subway stations on Line 1 have very low fire risk. We hope that through this evaluation model method and the results to bring some references for local rail companies. Meanwhile, this evaluation model method also promotes resilience and sustainability in social development.
In recent years, the prosperous electric vehicle industry has contributed to the rapid development of lithium-ion batteries. However, the increase in the energy density of lithium-ion batteries has also created more pressing safety concerns. The emergence of a new flame-retardant material with the additive ethoxy (pentafluoro) cyclotriphosphazene can ameliorate the performance of lithium-ion batteries while ensuring their safety. The present study proposes a new polymer composite flame-retardant electrolyte and adopts differential scanning calorimetry (DSC) and accelerating rate calorimetry to investigate its thermal effect. The study found that the heating rate is positively correlated with the onset temperature, peak temperature, and endset temperature of the endothermic peak. The flame-retardant modified polymer electrolyte for new lithium-ion batteries has better thermal stability than traditional lithium-ion battery electrolytes. Three non-isothermal methods (Kissinger; Kissinger–Akahira–Sunose; and Flynn–Wall–Ozawa) were also used to calculate the kinetic parameters based on the DSC experimental data. The apparent activation energy results of the three non-isothermal methods were averaged as 54.16 kJ/mol. The research results can provide valuable references for the selection and preparation of flame-retardant additives in lithium-ion batteries.
11 October 2022 in Journal of Thermal Analysis and Calorimetry
The effects of two different metal oxide catalysts, SnO and Li2O, on the dehydrogenation temperature of Carbazole and N-Ethylcarbazole (NE), respectively, were investigated by the Thermogravimetric analyzer and Differential Scanning Calorimetry. Thermogravimetric experiments were performed with 10wt% SnO and Li2O added to Carbazole and N-Ethylcarbazole, respectively, and compared to pure Carbazole and N-Ethylcarbazole. The results showed that the dehydrogenation temperature of N-Ethylcarbazole was lower than that of Carbazole, and the dehydrogenation temperature of N-Ethylcarbazole +SnO was the lowest, and SnO is an ideal dehydrogenation catalyst for N-Ethylcarbazole. Experiments using Differential Scanning Calorimetry and a Thermogravimetric analyzer showed that with the addition of catalyst, the activation energy of the mixture was more significant and stable, and the thermal hazard was reduced, whereas the relative dehydrogenation temperature was increased. This study provides important information for improving the design of dehydrogenation catalysts for organic liquid hydrogen storage processes.