The capacity fading and thermal safety issues caused by the volume effect of Si-based anodes and unstable solid electrolyte interphase (SEI) films during long-term cycling limit its large-scale application. In this study, silane polymer compound (2-cyanoethyl) triethoxysilane (TCN) was selected as an electrolyte additive to improve the reversibility and thermal safety of Si-based anode lithium-ion batteries (LIBs). TCN prevented the thermal interaction between the vitiated anode and electrolyte, and the onset temperature of the thermal reaction increased from 122.22 to 127.07 °C, as demonstrated by the results of thermogravimetric analysis and differential scanning calorimetry. The thermal stability of lithiated anodes containing various electrolytes was then assessed using a range of thermo-kinetic models. The results revealed that the activation energy of Si-based lithiated anodes increased from 68.46 to 91.32 kJ/mol, while the thermal hazard greatly decreased. Additionally, the electrochemical test and characterization results showed that TCN helped generate a stable SEI coating with more Li₂CO₃ components, which improved the cells’ cycle stability. This study provides a new reference for the growth of LIBs with high security and energy density.

The effects of two different metal oxide catalysts, SnO and Li₂O, on the dehydrogenation temperature of Carbazole and N-Ethylcarbazole (NE), respectively, were investigated by the Thermogravimetric analyzer and Differential Scanning Calorimetry. Thermogravimetric experiments were performed with 10wt% SnO and Li₂O added to Carbazole and N-Ethylcarbazole, respectively, and compared to pure Carbazole and N-Ethylcarbazole. The results showed that the dehydrogenation temperature of N-Ethylcarbazole was lower than that of Carbazole, and the dehydrogenation temperature of N-Ethylcarbazole +SnO was the lowest, and SnO is an ideal dehydrogenation catalyst for N-Ethylcarbazole. Experiments using Differential Scanning Calorimetry and a Thermogravimetric analyzer showed that with the addition of catalyst, the activation energy of the mixture was more significant and stable, and the thermal hazard was reduced, whereas the relative dehydrogenation temperature was increased. This study provides important information for improving the design of dehydrogenation catalysts for organic liquid hydrogen storage processes.