This article shows the optimization of the reverse osmosis process in seawater desalination plants, taking the example of the Canary Islands, where there are more than 320 units of different sizes, both private and public. The objective is to improve the energy efficiency of the system in order to save on operation costs as well as reduce the carbon and ecological footprints. Reverse osmosis membranes with higher surface area have lower energy consumption, as well as energy recovery systems to recover the brine pressure and introduce it in the system. Accounting for the operation, maintenance and handling of the membranes is also important in energy savings, in order to improve the energy efficiency. The energy consumption depends on the permeate water quality required and the model of the reverse osmosis membrane installed in the seawater desalination plant, as it is shown in this study.

This article shows a climate change mitigation strategy by means of membranes replacement and determination methodology of carbon footprint in reverse osmosis (RO) desalination plants, valid for all the islands, and even isolated territories in the continent. This study takes the case of study of Canary Islands, where there are more than 320 desalination plants with different sizes, private, and public. The objective is to propose a new method which integrates this analysis with the replacement of membranes, from 0% to 20% per year in sea water reverse osmosis desalination plants, to reduce the carbon footprint and ecological footprint. If it is considered a replacement of 20% of the elements per year, the carbon footprint could be reduced to between 5% and 6% and even more if it is introduced low energy consumption membranes instead of high rejection elements. The factor mix in Canary Islands, according to the technological structure of the generation park that uses oil products, is around 0.678 kgCO₂/kWh, much higher than in the Spanish mainland where it is 0.263 kgCO₂/kWh. Therefore, it is estimated in Canary Islands 5,326,963 t CO₂/year can be emitted, which represents 2.4 tCO₂/person/year, 12 times more the admissible admissions per inhabitant in the Canary Islands, only considering the seawater desalination sector. This document shows the different results of the analysis of energy efficiency and the environmental footprints. This study may serve as a tool for the decision-making processes related to how to improve energy efficiency in desalination plants.

Reverse osmosis (RO) is the most widely used technology for seawater desalination purposes. The long-term operating data of full-scale plants is key to analyse their performance under real conditions. The studied seawater reverse osmosis (SWRO) desalination plant had a production capacity of 5000 m³/d for irrigation purposes. The operating data such as conductivities flows, and pressures were collected for around 27,000 h for 4 years. The plant had sand and cartridge filters without chemical dosing in the pre-treatment stage, a RO system with one stage, 56 pressure vessels, seven RO membrane elements per pressure vessel and a Pelton turbine as energy recovery device. The operating data allowed to calculate the average water and salt permeability coefficients (A and B) of the membrane as well as the specific energy consumption (SEC) along the operating period. The calculation of the average A in long-term operation allowed to fit the parameters of three different models used to predict the mentioned parameter. The results showed a 30% decrease of A, parameter B increase around 70%. The SEC was between 3.75 and 4.25 kWh/m³. The three models fitted quite well to the experimental data with standard deviations between 0.0011 and 0.0015.

Desalination is an opportunity to get fresh water for irrigation and for drinking. Reverse Osmosis (RO) for sea water desalination is a solution for the high demand for water in Atlantic islands. The most efficient process to get desalinated water is RO; however, it is necessary to study what to do with the RO membranes used at the end of their life. This paper confirms the possibility to recycle them. The main categories of recycling by thermal processing commonly used in the industry include incineration and pyrolysis to produce energy, gas and fuel. These processes can be applied to mixed plastic waste, such as the combination of materials used in the manufacture of RO membranes. Recycling RO elements from desalination plants is shown to be an opportunity and pioneering initiatives are already underway in Europe. Energy recovery, via incineration, is feasible nowadays and it is a possibility to recycle RO membranes. On the other hand, the recycling of RO elements, via the pyrolytic industry, for fuel production could be centralized in a new industry already planned in the Macaronesia area and all obsolete osmosis membranes could be sent there for recycling. Recycling RO membranes is a very important opportunity for the environment and economy of the zone. This is a new business in water treatments with membranes, very interesting for decreasing the residues and the carbon footprint. The importance of this work is applied to sea water membranes, brackish water ones, and also wastewater tertiaries RO elements at the end of their life.

The penetration of renewable energies in island electricity systems (IESs) poses a series of challenges, which include, among others, grid stability, the response to demand, and the security of the supply. Based on the current characteristics of electricity demand on the islands of the Canary Archipelago (Spain) and their electricity production systems, this study presents a series of alternative scenarios to reduce greenhouse gas (GHG) emissions and increase the penetration of renewable energies. The goal is to optimize combustion-based (nonrenewable) energy production and combine it with renewable-based production that meets the requirements of dynamic response, safety, scaling, and integration with nonrenewable systems in terms of efficiency and power. As verified in the research background, the combination of power producing equipment that is generally employed on the islands is not the best combination to reduce pollution. The aim of this work is to find other possible combinations with better results. A methodology is developed and followed to obtain the lowest GHG production and to determine the measures to be applied based on: (a) changing the fuel type by switching to natural gas in the equipment that allows it; (b) using optimal combinations of the least polluting energy production equipment; (c) integrating, to the extent that it is possible, the Chira-Soria pumped hydroelectric energy storage plant into the Gran Canaria electricity system. A series of alternative scenarios are generated with different operating conditions which show the possibility of increasing the renewable installed capacity in the Canary Islands by up to 36.78% (70% in Gran Canaria), with a 65.13% reduction in GHG emissions and a 71.45% reduction in fuel consumption. The results of this study contribute, through the different measures determined through our research, to the mitigation of GHG emissions.

The cheese whey (95% composed of water) is an effluent produced in the cheese industry, of which more than 1.5 million tons are generated in Spain, constituting a serious environmental problem. The process starts with a new fermentative/enzymatic technology that totally converts whey, mainly composed by lactose, proteins, and salts, into a fermented product with higher added value. This new product is mainly composed by lactic acid bacteria biomass, ammonium lactate, and a protein hydrolysate. To separate valuable fractions, this fermented product is processed by a two-stage membrane system, which is a very innovative process in this type of fermented product. The first stage consists of ultrafiltration to separate all suspended solids. As a result of this stage, a product mainly constituted by lactic acid bacteria that have both agronomic applications, mainly as a biocontrol and biofertilizer/bio-stimulant, and applications in animal feeding as a probiotic, is obtained. The second stage consists of reverse osmosis used to concentrate the ultrafiltered permeate obtained earlier, leading to a microbiologically stable product and reducing transport costs. The concentrate is mainly composed of ammonium lactate and a protein hydrolysate, constituted by peptides and free amino acids, which has application both in agriculture as a bio-stimulant and in animal feeding, and the permeate is water, reusable in other industrial processes. This work demonstrates the technical feasibility of this valorization process to achieve the objective of “Waste 0” from a problematic by-product, while obtaining products with commercial utility.