Lithium iron phosphate (LFP) batteries have emerged as one of the most promising energy storage solutions due to their high safety, long cycle life, and environmental friendliness. In recent years, significant progress has been made in enhancing the performance and expanding the applications of LFP batteries through innovative materials design, electrode engineering, and manufacturing techniques. This review paper provides a comprehensive overview of the recent advances in LFP battery technology, covering key developments in materials synthesis, electrode architectures, electrolytes, cell design, and system integration. This review paper aims to provide a comprehensive overview of the recent advances in lithium iron phosphate (LFP) battery technology, encompassing materials development, electrode engineering, electrolytes, cell design, and applications. By highlighting the latest research findings and technological innovations, this paper seeks to contribute to the continued advancement and widespread adoption of LFP batteries as sustainable and reliable energy storage solutions for various applications. We also discuss the current challenges and future prospects for LFP batteries, emphasizing their potential role in sustainable energy storage solutions for various applications, including electric vehicles, renewable energy integration, and grid-scale energy storage.
In this work, the morphology of ZnO nanostructures is engineered to demonstrate enhanced supercapacitor characteristics of ZnO nanocones (NCs) compared to ZnO nanowires (NWs). ZnO NCs are obtained by chemically etching ZnO NWs. Electrochemical characteristics of ZnO NCs and NWs are extensively investigated to demonstrate morphology dependent capacitive performance of one dimensional ZnO nanostructures. Cyclic voltammetry measurements on these two kinds of electrodes in a three-electrode cell confirms that ZnO NCs exhibit a high specific capacitance of 378.5 F g −1 at a scan rate of 20 mV s −1 , which is almost twice that of ZnO NWs (191.5 F g −1 ). The charge–discharge and electrochemical impedance spectroscopy measurements also clearly result in enhanced capacitive performance of NCs as evidenced by higher specific capacitances and lower internal resistance. Asymmetric supercapacitors are fabricated using activated carbon (AC) as the negative electrode and ZnO NWs and NCs as positive electrodes. The ZnO NC⫽AC can deliver a maximum specific capacitance of 126 F g −1 at a current density of 1.33 A g −1 with an energy density of 25.2 W h kg −1 at the power density of 896.44 W kg −1 . In contrast, ZnO NW⫽AC displays 63% of the capacitance obtained from the ZnO NC⫽AC supercapacitor. The enhanced performance of NCs is attributed to the higher surface area of ZnO nanostructures after the morphology is altered from NWs to NCs.
The advent of two-dimensional (2D) materials and their capacity to form van der Waals (vdW) heterostructures has revolutionized numerous scientific fields, including electronics, optoelectronics, and energy storage. This paper presents a comprehensive investigation of bandgap engineering and band structure prediction in 2D vdW heterostructures utilizing density functional theory (DFT). By combining various 2D materials, such as graphene, hexagonal boron nitride (h-BN), transition metal dichalcogenides, and blue phosphorus, these heterostructures exhibit tailored properties that surpass those of individual components. Bandgap engineering represents an effective approach to addressing the limitations inherent in material properties, thereby providing enhanced functionalities for a range of applications, including transistors, photodetectors, and solar cells. Furthermore, this study discusses the current limitations and challenges associated with bandgap engineering in 2D heterostructures and highlights future prospects aimed at unlocking their full potential for advanced technological applications.
The challenge of safety problems in lithium batteries caused by conventional electrolytes at high temperatures is addressed in this study. A novel solid electrolyte (HKUST-1@IL-Li) was fabricated by immobilizing ionic liquid ([EMIM][TFSI]) in the nanopores of a HKUST-1 metal–organic framework. 3D angstrom-level ionic channels of the metal–organic framework (MOF) host were used to restrict electrolyte anions and acted as “highways” for fast Li+ transport. In addition, lower interfacial resistance between HKUST-1@IL-Li and electrodes was achieved by a wetted contact through open tunnels at the atomic scale. Excellent high thermal stability up to 300 °C and electrochemical properties are observed, including ionic conductivities and Li+ transference numbers of 0.68 × 10−4 S·cm−1 and 0.46, respectively, at 25 °C, and 6.85 × 10−4 S·cm−1 and 0.68, respectively, at 100 °C. A stable Li metal plating/stripping process was observed at 100 °C, suggesting an effectively suppressed growth of Li dendrites. The as-fabricated LiFePO4/HKUST-1@IL-Li/Li solid-state battery exhibits remarkable performance at high temperature with an initial discharge capacity of 144 mAh·g−1 at 0.5 C and a high capacity retention of 92% after 100 cycles. Thus, the solid electrolyte in this study demonstrates promising applicability in lithium metal batteries with high performance under extreme thermal environmental conditions.
Intumescent fire-retardant coatings, which feature thinner layers and good decorative effects while significantly reducing heat transfer and air dispersion capabilities, are highly attractive for fire safety applications due to their effective prevention of material combustion and protection of materials. Particularly, the worldwide demand for improved environmental protection requirements has given rise to the production of waterborne intumescent fire-retardant polymer composite coatings, which are comparable to or provide more advantages than solvent-based intumescent fire-retardant polymer composite coatings in terms of low cost, reduced odor, and minimal environmental and health hazards. However, there is still a lack of a comprehensive and in-depth overview of waterborne intumescent fire-retardant polymer composite coatings. This review aims to systematically and comprehensively discuss the composition, the flame retardant and heat insulation mechanisms, and the practical applications of waterborne intumescent fire-retardant polymer composite coatings. Finally, some key challenges associated with waterborne intumescent fire-retardant polymer composite coatings are highlighted, following which future perspectives and opportunities are proposed.