By anodization and thermal oxidation at 600 °C, an oxide layer on Ti with excellent corrosion resistance in strong acid solutions was prepared. The structural properties of TiO₂ films before and after thermal oxidation were investigated with methods of Scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). The electrochemical characterization was recorded via electrochemical impedance spectroscopy, potentiodynamic polarization and Mott–Schottky methods. XRD results show that a duplex rutile/anatase structure formed after oxidation, and the amount of anatase phase increased as the treatment time was prolonged from 3 to 9 h. XPS analysis indicates that as the thermal oxidation time increased, more Ti vacancies were present in the titanium oxide films, with decreased donor concentration. Longer thermal oxidation promoted the formation of hydroxides of titanium on the surface, which is helpful to improve the passive ability of the film. The anodized and thermally oxidized Ti samples showed relatively high corrosion resistance in 4 M HCl and 4 M H₂SO₄ solutions at 100 ± 5 °C. The passive current density values of the thermally oxidized samples were five orders of magnitude under the testing condition compared with that of the anodized sample. With the oxidation time prolonged, the passive current density decreased further to some extent.

Poor wear- and corrosion-resistance of 316L SS implants are critical problems in orthopedic implants. This study aims to improve the wear- and corrosion-resistance of 316L SS through surface coating. In this study, a bilayer composite coating consisting of polyether ether ketone (PEEK) as the first layer, and titania (TiO₂)- and Cu-doped mesoporous bioactive glass nanoparticles (Cu-MBGNs) were deposited as the second layer on a 316L SS via electrophoretic deposition (EPD). Scanning electron microscopy (SEM) images of the bilayer composite coating showed the distribution of TiO₂ and Cu-MBGNs within the PEEK matrix. Energy dispersive spectroscopy (EDS) analysis confirmed the presence of TiO₂ and Cu-MBGNs in the bilayer composite coating. Fourier transform infrared spectroscopy (FTIR) identified the functional groups attributed to the PEEK, TiO₂ and Cu-MBGNs. X-ray diffraction (XRD) analysis confirmed the presence of TiO₂ (anatase) and Cu-MBGNs in the bilayer composite coating. The coating exhibited a strong antibacterial effect against Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli). Incorporating TiO₂/Cu-MBGNs into the bilayer composite coating significantly modified the surface of 316L SS by improving the wear- and corrosion-resistance. Pin on disc test revealed that the specific wear rate of ∼(0.4570 ± 0.009) × 10⁻⁶ mm³ Nm⁻¹ of the PEEK coating decreased to (0.0482 ± 0.007) × 10⁻⁶ mm³ Nm⁻¹ on incorporating TiO₂/Cu-MBGNs in PEEK coating under a normal load of 10 N in Dulbecco's Modified Eagle Medium (DMEM). Furthermore, electrochemical impedance spectroscopy (EIS) results revealed that the impedance value of the bilayer composite coating remained ∼4.56 × 10⁵ Ω cm² compared to 8.81 × 10³ Ω cm² of 316L SS after 24 h immersion in phosphate-buffered saline (PBS). Thus, this study demonstrated that the wear- and corrosion-resistance of 316L SS can be improved by incorporating TiO₂/Cu-MBGNs in PEEK-based composite coatings for orthopedic applications.

The fast leaching and robust barrier property of inhibitors are the basic fundamentals for the formation of active protective coatings to protect aluminum alloys. Herein, an active protective surface was developed based on an epoxy coating and an underlying lithium carbonate (Li₂CO₃)-treated anodized aluminum alloy 2024-T3. The morphology of the Li-LDH layer was studied to know its formation mechanism. The electrochemical studies revealed that the fast and adequate leaching of lithium led to a substantial increment of corrosion resistance of the scratched coating in 3.5 wt% NaCl from 1 to 8 days. Time of flight secondary ion mass spectroscopy (ToF-SIMS) results indicated that Li was distributed in the lateral direction and covered the scratched area. The 3D images indicated that different lithium compounds were formed and 90% of the scratched area was covered with the lithium protective layer over immersion time. A combined approach of morphology observations, electrochemical measurements, and ToF-SIMS showed the lithium protective layer offered good corrosion resistance. On the contrary, lithium provided fast and adequate leaching from the coating, demonstrating good active protection for aluminum and its alloys.