Nowadays, people over the world face severe water scarcity despite the presence of several water sources. Adsorption is considered as the most efficient technique for the treatment of water containing biological, organic, and inorganic contaminants. For this purpose, materials from various origins (clay minerals, modified clays, zeolites, activated carbon, polymeric resins, etc.) have been considered as adsorbent for contaminants. Despite their cheapness and valuable properties, the use of clay minerals as adsorbent for wastewater treatment is limited due to many factors (low surface area, regeneration, and recovery limit, etc.). However, clay mineral can be used to enhance the performance of polymeric materials. The combination of clay minerals and polymers produces clay-polymers nanocomposites (CPNs) with advanced properties useful for pollutants removal. CPNs received a lot of attention for their efficient removal rate of various organic and inorganic contaminants via flocculation and adsorption ability. Three main classes of CPNs were developed (exfoliated nanocomposites (NCs), intercalated nanocomposites, and phase-separated microcomposites). The improved materials can be explored as novel and cost-effective adsorbents for the removal of organic and inorganic pollutants from water/wastewater. The literature reported the ability of CPNs to remove various pollutants such as bacteria, metals, phenol, tannic acid, pesticides, dyes, etc. CPNs showed higher adsorption capacity and efficient water treatment compared to the individual components. Moreover, CPNs offered better regeneration than clay materials. The present paper summarizes the different types of clay-polymers nanocomposites and their effective removal of different contaminants from water. Based on various criteria, CPNs future as promising adsorbent for water treatment is discussed.

Antibiotics can accumulate through food metabolism in the human body which may have a significant effect on human safety and health. It is therefore highly beneficial to establish easy and sensitive approaches for rapid assessment of antibiotic amounts. In the development of next-generation biosensors, nanomaterials (NMs) with outstanding thermal, mechanical, optical, and electrical properties have been identified as one of the most hopeful materials for opening new gates. This study discusses the latest developments in the identification of antibiotics by nanomaterial-constructed biosensors. The construction of biosensors for electrochemical signal-transducing mechanisms has been utilized in various types of nanomaterials, including quantum dots (QDs), metal-organic frameworks (MOFs), magnetic nanoparticles (NPs), metal nanomaterials, and carbon nanomaterials. To provide an outline for future study directions, the existing problems and future opportunities in this area are also included. The current review, therefore, summarizes an in-depth assessment of the nanostructured electrochemical sensing method for residues of antibiotics in different systems.

A magnetic polymer-based nanocomposite was fabricated by the modification of an Fe₃O₄/SiO₂ magnetic composite with polypyrrole (PPy) via co-precipitation polymerization to form PPy/Fe₃O₄/SiO₂ for the removal of Congo red dye (CR) and hexavalent chromium Cr(VI) ions from water. The nanocomposite was characterized using various techniques including X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), vibration sample magnetometer, and thermogravimetric analysis (TGA). The results confirm the successful fabrication of the nanocomposite in the size of nanometers. The effect of different conditions such as the contact time, adsorbent dosage, solution pH, and initial concentration on the adsorption process was investigated. The adsorption isotherm suggested monolayer adsorption of both contaminants over the PPy/Fe₃O₄/SiO₂ nanocomposite following a Langmuir isotherm, with maximum adsorption of 361 and 298 mg.g⁻¹ for CR dye and Cr(VI), respectively. Furthermore, the effect of water type on the adsorption process was examined, indicating the applicability of the PPy/Fe₃O₄/SiO₂ nanocomposite for real sample treatment. Interestingly, the reusability of the nanocomposite for the removal of the studied contaminants was investigated with good results even after six successive cycles. All results make this nanocomposite a promising material for water treatment.

These days, environmental pollution, notably water pollution, has increasingly caused severe human health problems. The major water pollutants are heavy metals. MnFe₂O₄/GO nanocomposite was prepared in the current work via in situ method and tested to remove lead ion Pb²⁺ and neutral red (NR) dye from water. The prepared nanocomposite was characterized using different techniques, including X-ray diffraction, transmission electron microscopy, Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, Raman spectra, and vibrating sample magnetometer. The prepared nanocomposite showed high adsorption capacity toward Pb²⁺ and NR dye removal according to Langmuir fitting indicating the monolayer homogeneous adsorption of pollutants over the adsorbent surface and can be separated easily with an external magnet. The effect of different factors, including contact time, pH, initial concentration, and adsorbent dose on the adsorption, were also studied. The increased concentration of pollutants led to increased adsorption capacity from 63 to 625 mg/g for Pb²⁺ ions and from 20 to 90 mg/g for NR dye. The increased adsorbent dose led to increased removal efficiency from 39% to 98.8% and from 63% to 94% for Pb²⁺ and NR dye, respectively. The optimum pH for the adsorption of both pollutants was found to be 6.0. The reusability of MnFe₂O₄/GO nanocomposite was studied for up to five cycles. The nanocomposite can keep its efficiency even after the studied cycles. So, the prepared magnetic nanocomposite is a promising material for water treatment.

The laccase enzyme was successfully immobilized over a magnetic amino-functionalized metal–organic framework Fe₃O₄-NH₂@MIL-101(Cr). Different techniques were used for the characterization of the synthesized materials. The Fe₃O₄-NH₂@MIL-101(Cr) laccase showed excellent resistance to high temperatures and low pH levels with a high immobilization capacity and large activity recovery, due to the combination of covalent binding and adsorption advantages. The long-term storage of immobilized laccase for 28 days indicated a retention of 88% of its initial activity, due to the high stability of the immobilized system. Furthermore, a residual activity of 49% was observed at 85 °C. The immobilized laccase was effectively used for the biodegradation of Reactive Black 5 (RB) and Alizarin Red S (AR) dyes in water. The factors affecting the RB and AR degradation using the immobilized laccase (dye concentration, temperature and pH) were investigated to determine the optimum treatment conditions. The optimum conditions for dye removal were a 5 mg/L dye concentration, temperature of 25 °C, and a pH of 4. At the optimum conditions, the biodegradation and sorption-synergistic mechanism of the Fe₃O₄-NH₂@MIL-101(Cr) laccase system caused the total removal of AR and 81% of the RB. Interestingly, the reusability study of this immobilized enzyme up to five cycles indicated the ability to reuse it several times for water treatment.

Aloe vera plant offers a sustainable solution for the removal of various pollutants from water. Due to its chemical composition, Aloe vera has been explored as coagulant/flocculant and biosorbent for water treatment. Most of the used materials displayed significant pollutants removals depending on the used preparation methods. AV-based materials have been investigated and successfully used as coagulant/flocculant for water treatment at laboratory scale. Selected AV-based materials could reduce the solids (total suspended solids (TSS), suspended solids (SS), total dissolved solids (TDS), and dissolved solids (DS)), turbidity, chemical oxygen demand (COD), biochemical oxygen demand (BOD), heavy metals, and color, with removal percentages varied depending on the coagulant/flocculant materials and on the wastewater characteristics. In the same context, AV materials can be used as biological flocculant for wastewater sludge treatment, allowing good solid–liquid separation and promoting sludge settling. Moreover, using different methods, AV material-based biosorbents were prepared and successfully used for pollutants (heavy metal dyes and phenol) elimination from water. Related results showed significant pollutant removal efficiency associated with an interesting adsorption capacity comparable to other biosorbents derived from natural products. Interestingly, the enzymatic system of Aloe vera (carboxypeptidase, glutathione peroxidase, and superoxide dismutase) has been exploited to degrade textile dyes. The obtained results showed high promise for removal efficiencies of various kinds of pollutants. However, results varied depending on the methodology used to prepare the Aloe vera based materials. Because of its valuable properties (composition, abundance, ecofriendly and biodegradable), Aloe vera may be useful for water treatment.