The effects of polycarboxylate superplasticizers (PCEs) on the dispersing properties and initial hydration of cement particles with various water-to-cement (w/c) ratios was investigated, including the water film thickness (WFT), rheology, fluidity, adsorption of PCEs, zeta potential, degree of hydration, hydration products. The experimental results demonstrate that the initial rheological and fluidity parameters were more sensitive to the PCE dosage at a lower w/c because the WFT and the zeta potential on cement particles change more significantly. Moreover, the higher adsorption amounts of the PCEs at a lower w/c lead to a stronger inhibition of the initial hydration, whilst, at the same PCE dosage, the cement pastes have a more rapid fluidity loss and quicker hydration reactions at a higher w/c due to a lower adsorption amount of the PCE on cement particles.

Compared with traditional hydrothermal synthesis, microwave-assisted synthesis has the advantages of being faster and more energy efficient. In this work, the MoS₂/BiVO₄ heterojunction photocatalyst was synthesized by the microwave-assisted hydrothermal method within 30 min. The morphology, structure and chemical composition were characterized by X-ray diffraction (XRD), Raman, X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), and high-resolution transmission electron microscopy (HRTEM). The results of characterizations demonstrated that the synthesized MoS₂/BiVO₄ heterojunction was a spherical structure with dimensions in the nanorange. In addition, the photocatalytic activity of the samples was investigated by degrading tetracycline hydrochloride (TC) under visible light irradiation. Results indicated that the MoS₂/BiVO₄ heterojunction significantly improved the photocatalytic performance compared with BiVO₄ and MoS₂, in which the degradation rate of TC (5 mg L⁻¹) by compound where the mass ratio of MoS₂/BiVO₄ was 5 wt% (MB5) was 93.7% in 90 min, which was 2.36 times of BiVO₄. The active species capture experiments indicated that •OH, •O₂⁻ and h⁺ active species play a major role in the degradation of TC. The degradation mechanism and pathway of the photocatalysts were proposed through the analysis of the band structure and element valence state. Therefore, microwave technology provided a quick and efficient way to prepare MoS₂/BiVO₄ heterojunction photocatalytic efficiently.

Previous studies demonstrated that water film thickness (WFT) is a key factor that affects the fluidity of mortar. Changes in the sand-cement (S/C) ratio and polycarboxylate superplasticizer (PCE) dosage will affect the WFT. In this study, several mortar samples with different S/C ratios and different PCE dosages were prepared, and the basic properties of the mortar were measured. The results show that as the S/C ratio increases, the packing density of the mortar will decrease, the WFT will decrease, and the cohesiveness will increase, resulting in a decrease in the flow spread and strength of the mortar. When the PCE dosage is increased, the packing density of the mortar will increase, the WFT will increase, and the cohesiveness will decrease, which increases the flow spread of the mortar. When the water-cement (W/C) ratio is low, the S/C ratio has a significant effect on the strength, and the strength will increase with the increasing of the PCE dosage. When the W/C ratio is high, the strength of the mortar will be reduced once the PCE dosage exceeds the saturation value. In the case of different S/C ratios or different PCE dosages, the WFT can be used as a measure of mortar cohesiveness and flow spread.

Siraitia grosvenorii(LHG) is widely used as a medicinal and edible material around the world. The objective of this study was to develop an effective method for the authentication of the geographical origin of LHG in its main producing area Guangxi, China, which is identified as Chinese Protected Designation of Origin product, against other producing regions in China. The content of 14 elements (K, Na, Ca, P, Mg, Al, B, Ba, Cu, Fe, Mn, Ni, Zn, and Sr) of 114 LHG samples was determined by inductively coupled plasma optical emission spectrometry. Multivariate analysis was then performed to classify the geographical origin of LHG samples. The contents of multielement display an obvious trend of clustering according to the geographical origin of LHG samples based on radar plot and principal component analysis. Finally, three supervised statistical techniques, including linear discriminant analysis (LDA),k-nearest neighbours (k-NN), and support vector machine (SVM), were applied to develop classification models. Finally, 40 unknown LHG samples were used to evaluate the predictive ability of model and discrimination rate of 100%, 97.5% and 100% were obtained for LDA,k-NN, and SVM, respectively. This study indicated that it is feasible to attribute unknown LHG samples to its geographical origin based on its multielement content coupled with chemometric techniques.