Photonic devices can be developed, and their working principle can be understood only by considering the phenomena taking place at the nanoscale level. Optical properties of plasmonic structures depend on their geometric parameters and are sensitive to them. Recently, many advanced methods for the preparation of nanostructures have been proposed; however still, the geometric parameters are inaccurate. Numerical simulations provide a powerful tool for the analysis of plasmonic nanostructures. To the best of our knowledge, there are not many papers on near-field and far-field properties of single nanoprism and nanoprism dimer, the so-called bowtie, with rounded edges. For this purpose, Finite Integration Technique implemented to the CST Microwave Studio was used. Besides the edge rounding, an additional modification of the resonance modes was investigated, achieved by placement of a spherical nanoparticle in the gap between the prisms. Results of numerical simulations indicate that the radius of the curvature edges strongly affects the plasmon peak localization, and this effect cannot be neglected in plasmonic device design. Increase in the radius of edge curvature causes main extinction cross-section peak blueshift in all cases analyzed. Moreover, our calculations imply that the nanoparticle in the gap between prisms strongly influences the dependence of spectral properties on the radius curvature.

Robust and versatile strategies for the development of functional nanostructured materials often focus on assemblies of metallic nanoparticles. Research interest in such assemblies arises due to their potential applications in the fields of photonics and sensing. Metallic nanoparticles have received considerable recent attention due to their connection to the widely studied phenomenon of localized surface plasmon resonance. For instance, plasmonic hot spots can be observed within their assemblies. A useful form of spectroscopy is based on surface-enhanced Raman scattering (SERS). This phenomenon is a commonly used in sensing techniques, and it works using the principle that scattered inelastic light can be greatly enhanced at a surface. However, further research is required to enable improvements to the SERS techniques. For example, one question that remains open is how to design uniform, highly reproducible, and efficiently enhancing substrates of metallic nanoparticles with high structural precision. In this review, a general overview on nanoparticle functionalization and the impact on nanoparticle assembly is provided, alongside an examination of their applications in surface-enhanced Raman spectroscopy.

Unlocked nucleic acids (UNAs) have been introduced at specific positions in short model DNA hairpins and RNA/DNA triplexes for the first time. UNA residues destabilize the hairpins and decrease triplex thermodynamic stability or suppress triplex formation for most of the evaluated structures. Nevertheless, the incorporation of UNA residues at certain positions of dsDNA was found to be energetically favourable or at least did not affect triplex stability. Notably, the most thermodynamically stable UNA-modified triplexes exhibited improved stability at both acidic and physiological pH. The specificity of the interactions between the triplex-forming oligonucleotide and dsDNA was characterized using EMSA for the most thermodynamically stable structures, and triplex dissociation constants were determined. One of the modified triplexes exhibited an improved Kd in comparison with the unmodified triplex. CD and thermal difference spectra indicated that UNA residues do not alter the overall structure of the most thermodynamically stable triplexes. In addition, incubation of the modified oligonucleotides with human serum indicated that the UNAs demonstrate the potential to improve the biological stability of nucleic acids.

Zinc oxide (ZnO) is a wide-bandgap semiconductor material with applications in a variety of fields such as electronics, optoelectronic and solar cells. However, much of these applications demand a reproducible, reliable and controllable synthesis method that takes special care of their functional properties. In this work ZnO and Cu-doped ZnO nanowires are obtained by an optimized hydrothermal method, following the promising results which ZnO nanostructures have shown in the past few years. The morphology of as-prepared and copper-doped ZnO nanostructures is investigated by means of scanning electron microscopy and high resolution transmission electron microscopy. X-ray diffraction is used to study the impact of doping on the crystalline structure of the wires. Furthermore, the mechanical properties (nanoindentation) and the functional properties (absorption and photoluminescence measurements) of ZnO nanostructures are examined in order to assess their applicability in photovoltaics, piezoelectric and hybrids nanodevices. This work shows a strong correlation between growing conditions, morphology, doping and mechanical as well as optical properties of ZnO nanowires.

This paper examines the influence of aprotic solvents on the spectroscopic properties as well as the energy deactivation of two free-base corrole dyes substituted with C₆F₅ and/or 4-NO₂C₆H₄ groups.