Copper oxide-titanium dioxide (TiO2) p–n junctions are promising materials for photovoltaic devices and may reduce production costs due to their low cost and inexpensive production methods compared with silicon solar cells. The present review compares solar cells made with copper oxides combined with TiO2–TiO2/Cu2O and TiO2/CuO heterojunctions, and “cascade heterojunction systems.” First, we describe the main properties of titanium (iv) dioxide (TiO2), cuprous oxide (Cu2O), and cupric oxide (CuO), and their potential applications. Next, we explain the concept of copper oxide and TiO2 heterojunctions. We summarize and present the photovoltaic characteristics (efficiency, fill factor, circuit current density, and open circuit voltage), thickness, preparation method, and electrode type for solar cells comprising copper oxide and TiO2. The efficiency of the solar cells ranged from 0.0005% to 1.62%. The thickness of the TiO2 and cupric oxide layers ranged from 0.06 to 16 µm, and from 0.18 to 1.5 µm, respectively, depending on the fabrication method. Additionally, we review and discuss the available combinations of copper oxide with other materials (Cu2O with ZnO, CuO with ZnO, and CuO with Si), as well as the effect of the thickness of the copper (i) oxide and copper (ii) oxide on the solar cell performance. Finally, we present aspects to improve the conversion efficiency of heterojunction solar cells with copper oxides combined with TiO2. This review will be useful for the construction and further development of thin-film solar cells.
1 May 2018 in Journal of Physics: Conference Series
Here authors present a numerical study of a thin-film TiO2/Cu2O solar cell using the Solar Cell Capacitance Program. Authors simulated the current density and voltage (J–V) characteristics of an n-TiO2/p-Cu2O solar cell without defects under standard test conditions for a 400-nm thick Cu2O absorber layer and a 200-nm thick TiO2 buffer layer. The simulation confirmed the high potential of the n-TiO2/p-Cu2O structure. The cell efficiency (η) of the n-TiO2/p-Cu2O solar cell was 7.71% with: JSC ≈ JMPP ∼ 9.6 mA/cm2 and VMPP = 0.8 V. Additionally, authors produced a n-TiO2/p-Cu2O thin-film heterojunction solar cell using a direct current magnetron-sputtering technique and analyzed the basic material properties, e.g., composition, optical characteristics, morphologic characteristics, and I–V measurement of TiO2/Cu2O. Our findings revealed the high potential of the TiO2/Cu2O structure as a future-oriented solution for photovoltaic applications.
1 January 2020 in Journal of Ecological Engineering
Nowadays, much attention is paid to the elimination of heat sources poisoning our environment. Air pollution is the most dangerous form of pollution of the environment due to its direct impact on all living organisms, coverage of large areas and easy movement of pollutants. Therefore, air...
1 July 2018 in Journal of Nanoelectronics and Optoelectronics
TiO2 thin films deposited on glass and silicon were obtained using a direct current magnetron sputtering technique and pulsed laser deposition using a modular deposition platform. The sample properties were determined by scanning electron microscopy (SEM) and X-ray diffraction analysis. Basic material properties, such as thickness, layer structure, and optical properties, were also examined. The obtained films had a nanocrystalline structure with a mean grain diameter ranging from 0.2 to 0.4 m. This article presents a detailed discussion of the influence of the manufacturing technique on TiO2 thin film morphology and optical properties for possible photovoltaic applications for polycrystalline heterostructures.
1 September 2016 in Journal of Renewable and Sustainable Energy
Here, we evaluated the efficiency of a solar domestic hot water system in a dormitory in Rzeszow. Radiance exposure was analyzed based on information obtained from an online database (the meteorological station in Rzeszow-Jasionka). The mean seasonal and annual solar irradiation of a flat surface and surfaces inclined at 30°, 45°, and 60° from the horizontal plane in Rzeszow were determined. The mean monthly irradiation was compared with that in selected European cities based on the Photovoltaic Geographical Information System meteorological database. The thermal solar panel area and final consumption of solar energy in Poland from 2005 to 2014 are also presented. The characteristics of the analyzed building, distribution of the inhabitants, and consumption of hot water from 2009 to 2014 are described. The heat demand was determined by hot water consumption per day per person based on hot water consumption metering and heat metering. The solar energy conversion efficiency was determined after the solar thermal collectors were installed in the building. The relation of the heat demand calculated based on the thermal energy utilized to heat water per person and heat metering for heating water was also analyzed. We also present a method of calculating the annual (stratified by month) ratio of solar energy utilization. Energy savings for the building were calculated. Improvements that could further increase the solar energy efficiency and shorten the investment payback period are proposed.