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Mrs. Magdalena Kleybolte
Technical University of Munich (TUM)

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Research Keywords & Expertise

0 ROP
0 Terpenes
0 pinene
0 Polyamides
0 Macromolecular and polymer chemistry

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Short Biography

Bachelor thesis (Technical Chemistry II, Technical University Munich) „Photocatalytic Hydrogen Evolution on g-C3N4” Master Thesis ( WACKER-chair for macromolecular chemistry, Technical University of Munich) „b-Pinene derived Polyesteramides and their Blends: Advances in their Upscaling, Processing and Characterization”

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Journal article
Published: 09 March 2021 in Polymers
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Soluble heterocomplexes consisting of sodium hydride in combination with trialkylaluminum derivatives have been used as anionic initiating systems at 100 °C in toluene for convenient homo-, co- and ter-polymerization of myrcene with styrene and isoprene. In this way it has been possible to obtain elastomeric materials in a wide range of compositions with interesting thermal profiles and different polymeric architectures by simply modulating the alimentation feed and the (monomers)/(initiator systems) ratio. Especially, a complete study of the myrcene-styrene copolymers (PMS) was carried out, highlighting their tapered microstructures with high molecular weights (up to 159.8 KDa) and a single glass transition temperature. For PMS copolymer reactivity ratios, rmyr = 0.12 ± 0.003 and rsty = 3.18 ± 0.65 and rmyr = 0.10 ± 0.004 and rsty = 3.32 ± 0.68 were determined according to the Kelen–Tudos (KT) and extended Kelen–Tudos (exKT) methods, respectively. Finally, this study showed an easy accessible approach for the production of various elastomers by anionic copolymerization of renewable terpenes, such as myrcene, with commodities.

ACS Style

David Lamparelli; Magdalena Kleybolte; Malte Winnacker; Carmine Capacchione. Sustainable Myrcene-Based Elastomers via a Convenient Anionic Polymerization. Polymers 2021, 13, 838 .

AMA Style

David Lamparelli, Magdalena Kleybolte, Malte Winnacker, Carmine Capacchione. Sustainable Myrcene-Based Elastomers via a Convenient Anionic Polymerization. Polymers. 2021; 13 (5):838.

Chicago/Turabian Style

David Lamparelli; Magdalena Kleybolte; Malte Winnacker; Carmine Capacchione. 2021. "Sustainable Myrcene-Based Elastomers via a Convenient Anionic Polymerization." Polymers 13, no. 5: 838.