Interest in perchlorate as environmental pollutant has increased since 1997, when high concentrations have been found in the waters of the Colorado River, USA. Perchlorate is very persistent in nature and it is slowly degraded. Although harmful effects of large doses of perchlorate on thyroid function have been proven, the environmental effects are still unclear. The primary objective of the present review is to collect prevailing data of perchlorate exposure and to discuss its impact on human health. The results show that more than 50% of reviewed works found significant associations of perchlorate exposure and human health. This review consists of the following sections: general information of perchlorate sources, its properties and determination methods, role and sources in human body including food and water intake, overview of the scientific literature on the research on the effect of perchlorate on human health from 2010 to 2020. Finally, conclusions and recommendations on future perchlorate studies concerning human exposure are presented.

The paper presents the results of the studies on the vanadium (V) ions removal from the aqueous solutions in the adsorption process on biochars from different biomass types (cow manure BC1, wet distiller grains BC2, spent mushroom substrates BC3). The adsorbents were characterized by means of the SEM-EDS, FTIR, XRD and XPS techniques. The influence of adsorbent type and basic process parameters, such as pH and metal ion concentration in aqueous phase, adsorbent dose and time of contact of phases on the efficiency of V(V) was determined. Based on the obtained results, the mechanism and kinetics of the adsorption processes occurring on the biochar originating from the wet distiller grains as adsorbents with the greatest affinity for the V(V) ions were characterized, using isotherm models of Langmuir, Freundlich, Temkin and Dubinin-Radushkevich and pseudo-first-order, pseudo-second-order as well as intraparticle diffusion kinetic models. Under the constant process conditions (pH = 3.0; m = 0.5 g; c₀ = 50 mg/L) the order of V(V) ions removal from aqueous solutions was as follows: BC2 > BC1 = BC3. The biochar BC2 exhibited the maximum sorption capacity of 1.61 mg V(V)/g. The experimental kinetic data show the adsorption course according to the pseudo-second order model.

The article reviews the literature on the possibility of application of the calixarene-based compounds for selective separation of toxic heavy metals from aqueous solutions by the solvent extraction and transport across liquid membranes. The specific three-dimensional structure of calixarenes and their derivatives, simple and low-cost synthesis, and ease of chemical transformation qualify these compounds for the role of selective chemical extractants of toxic heavy metal ions present in industrial wastewater. This article analyses the influence of various process factors, with the greatest emphasis on the structure of the extractants/carriers, on efficient separation of heavy metal ions, primarily those most commonly found in galvanic wastewater.

This study investigates heavy metal contamination in soils, irrigation water, and agricultural produce (fruits: Vitis vinifera (grape), Cucumis melo var. saccharimus (melon), and Citrullus vulgaris. Schrade (watermelon); vegetables: Lycopersicum esculentum L. (tomato), Cucurbita pepo (zucchini), Daucus carota (carrot), Lactuca sativa (lettuce), Convolvulus Batatas (potato), and Capsicum annuum L. (green pepper)) in the Boumerdes region of Algeria. The concentrations of seven heavy metals (cadmium (Cd), chromium (Cr), copper (Cu), iron (Fe), nickel (Ni), lead (Pb), and zinc (Zn)) in soil and food samples were analyzed using atomic absorption spectrometry. Health risks associated with these metals were evaluated through the estimated daily intake (EDI), non-carcinogenic risks (using target hazard quotient (THQ), total target hazard quotient (TTHQ), and hazard index (HI)), and carcinogenic risks (cancer risk factor (CR)). Statistical analyses, including cluster analysis (CA) and Pearson correlation, were conducted to interpret the data. The results revealed the highest metal transfer as follows: Cd was most significantly transferred to tomatoes and watermelons; Cr to carrots; Cu to tomatoes; and Fe, Ni, Pb, and Zn to lettuce. Among fruits, the highest EDI values were for Zn (2.54·10⁻³ mg/day) and Cu (1.17·10⁻³ mg/day), with melons showing the highest Zn levels. For vegetables, the highest EDI values were for Fe (1.68·10⁻² mg/day) and Zn (8.37·10⁻³ mg/day), with potatoes showing the highest Fe levels. Although all heavy metal concentrations were within the World Health Organization’s permissible limits, the HI and TTHQ values indicated potential health risks, particularly from vegetable consumption. These findings suggest the need for ongoing monitoring to ensure food safety and mitigate health risks associated with heavy metal contamination.