Wood polymer composites (WPC) are sensitive to moisture because of the hydrophilic nature of the wood fibers. The main objective of this study was to improve the dimensional stability of WPCs by coating. Polypropylene and polylactic acid were reinforced by three pulp fibers (kraft, thermomechanical (TMP), and chemothermomechanical (CTMP)) at three fiber contents (50, 60, and 70% w/w). The resulting WPCs were coated using two commercial coatings, epoxy and acrylic. Kraft fiber WPCs were less sensitive to moisture than TMP and CTMP WPCs. These differences were explained by the crystallinity of the kraft fibers and their better interfacial adhesion to the polymers. The epoxy coating proved to be more effective than the acrylic coating and significantly reduced the water absorption and the thickness swell for all formulations. Negative relationships between the contact angle and water absorption were obtained. These relationships depend on the fiber content and type, the matrix nature, and the coating.
Demand for high-performance biocomposites is increasing due to their ease of processing, low environmental impact, and in-service performance. This study investigated the effect of boric acid modification of wood flour on polycarbonate (PC) wood composites’ thermal stability, fire retardancy, water absorption, and creep behavior. The composites’ fire retardancy increased with increasing wood flour content, and their char residue increased by 102.3% compared to that of pure PC. However, the water absorption of the resulting composites increased due to the hydroxyl groups of the wood flour. Wood flour also improved the composites’ anti-creep properties. The excellent fire retardancy and anti-creep properties of wood–PC composites expand their use in the construction sector.
The moisture sensitivity of wood–polymer composites (WPCs) is mainly related to their hydrophilic wood components. Coatings are among the alternatives that improve the dimensional stability of these composites. However, the adhesion of most coatings to the WPC surface is generally poor. Thus, chemical and/or mechanical treatments should be applied to the WPC surface to improve the coating adhesion. Therefore, the main objective of this study was to improve the adhesion coating of polypropylene (PP) WPCs through a chromic treatment. PP was reinforced by three different pulp fibers (kraft, thermomechanical (TMP), and chemothermomechanical (CTMP)) at three fiber contents (50, 60, and 70% w/w). A chromic treatment was applied to the PP-based WPCs to activate the surface of the composites and alter their roughness parameters, creating a higher interfacial zone that improved the bonding of the epoxy coating to the surface of the PP composites. The chromic treatment increased the roughness of the surface. An increase in profile and surface parameters was observed after treatment. This treatment modified the chemical composition of the surface by creating polar carbon–oxygen groups and increasing the carbonyl and hydroxyl indexes.
31 March 2018 in Journal of Applied Polymer Science