The need to feed 9.9 billion people by 2050 will require the coordination of farming practices and water utilization by nutrient-dense plants and crops. High levels of lead (Pb), a toxic element that can accumulate in plants, can lead to toxicity in humans. With the development of novel treatment technologies, such as atmospheric cold plasma (ACP) and engineered nanoparticles (NPs), the time to germination and levels of heavy metals in food and feed commodities can be reduced. This study provides insight into the impact of plasma-activated water (PAW) on the germination rates and effects of soybean seeds, and the resultant combination effects of zinc oxide uptake in the presence of lead. Soybean seedlings were watered with PAW (treated for 3, 5, and 7 min at 30, 50, and 70 kV), and the germination and growth rate were monitored for 10 days. The germinated seedlings were then grown hydroponically in a nutrient solution, and the biomass of each example was measured. The PAW treatment that resulted in the best growth of soybean seeds was then exposed to Pb and zinc-oxide nanoparticles (ZnONPs) to investigate heavy metal uptake in the presence of nanoparticles. After acid digestion, the rate of heavy metal uptake by the soybean plants was evaluated using inductively coupled plasma-mass spectrometry. The PAW seeds grew and germinated more quickly, demonstrating that the plasma therapy had an effect. The rate of heavy metal uptake by the plants was also shown to be 5x lower in the presence of ZnONP.
In this study, we combined atmospheric pressure cold plasma, a novel treatment technology, with an absorption technique with soybean husk to remove Pb and Cd from milk. Different combinations of treatment duration, voltage, and post treatment retention time were used to determine the effectiveness of cold plasma. Soybean husk was used for metal extraction, and it was observed that when the milk samples were plasma treated with a discharge voltage of 50 kV for 2 min and held for 24 h, the highest mean elimination of about 27.37% for Pb and 14.89% for Cd was obtained. Reactive oxygen and nitrogen species produced from plasma treatment were identified using Optical Emission Spectra analysis. A high voltage of 50 kV plasma for a 2 min duration could produce 500 ± 100 ppm of ozone concentration inside the treated package. The value of ΔE, which indicates overall color difference measurement, was significantly (p < 0.05) higher in all the treated samples than control samples. However, in the frequency range from 0.01 to 100 Hz, there was not much difference between the control and treated sample in the frequency sweep test. The identified functional groups at different wavenumbers (cm−1) in the treated samples were found to be similar compared to the control samples.
Particulate matter (PM) emissions from dairies and feedlot sources require regular emission factor update. Likewise, development of simple measurement technique to accurately measure pollution concentration is warranted to limit the impact of air pollution and take necessary actions. During June of 2020, a dairy facility from central Texas and a feedlot from the Texas Panhandle region, titled as Dairy B and Feedlot C, respectively, were chosen for measurement of PM emissions in the state of Texas to represent dairy facilities and cattle feedlots PM emission rates. Four stations, each assigned with an EPA-approved Federal Reference Method (FRM) sampler, Texas A&M University (TAMU) designed sampler and handheld non-FRM AEROCET (MET One Instruments) sampler for collocation, were selected within each sampling locations. Drones were also utilized mounted with a handheld AEROCET sampler for simultaneously sampling at a certain height. PM2.5 emissions of Dairy B were all below 24-h PM2.5 standard of 35 μg m−3 as specified by National Ambient Air Quality Standards (NAAQS) even at the 98th percentile. The PM ratio between regulated PM10 to PM2.5 was determined to make an estimate of relative percentage of coarser particles to fine particles in both feedlot and the dairy representative animal facilities. The maximum mean emission factor determined using AERMOD for PM2.5 and PM10 was found to be 0.53 and 7.09 kg 1000-hd−1 d−1, respectively, for the dairy facility while 8.93 and 33.42 kg 1000-hd−1 d−1, respectively, for the feedlot. A conversion factor and correlation matrix were developed in this study to relate non-FRM sampler data from the handheld AERCET samplers with FRM samplers. Cheaper handheld samplers (AEROCETs) may play a potential role in quick and relatively instant measurement of PM emissions to initiate necessary preventive actions to control PM emission from dairy facility and feedlot sources.