The article discusses the results of examining the impact of aggressive solutions on specimens of mortars with a slag-ash binder. Bar specimens were exposed to unidirectional diffusion of sodium chloride and sodium sulphate for 90 days. Next, the specimens were subjected to flexural and compressive strength tests, ion content tests, XRD phase composition tests, and microstructural SEM-EDS tests. The test results indicated that aggressive solution action resulted in decreased flexural strength, however, it did not impact the compressive strength of mortars. A minor impact of chloride ions on the pH of the pore liquid was recorded, while the tests did not show any influence of sulphate ions. Furthermore, aggressive ion concentration decreased in deeper specimen slices. Specimen phase composition testing after chloride ion action indicated the presence of a small amount of Friedel’s salt, while regular sodium chloride crystals were identified in the microscopic image. The performance properties of mortars exposed to the action of aggressive solutions were maintained.

In Poland, in recent years, there has been a rapid accumulation of sewage sludge - a by-product in the treatment of urban wastewater. This has come about as a result of infrastructure renewal, specifically, the construction of modern sewage treatment plants. The more stringent regulations and strategic goals adopted for modern sewage management have necessitated the application of modern engineering methodology for the disposal of sewage sludge. One approach is incineration. As a consequence, the amount of fly ash resulting from the thermal treatment of municipal sewage sludge has grown significantly. Hence, intensive work is in progress for environmentally safe management of this type of waste. The aim of the experiment was to evaluate the possibility of using the fly ash that results from municipal sewage sludge thermal treatment (SSTT) as an additive to hardening slurries. This type of hardening slurry with various types of additives, e.g. coal combustion products, is used in the construction of cut-off walls in hydraulic structures. The article presents the technological and functional parameters of hardening slurries with an addition of fly ash obtained by SSTT. Moreover, the usefulness of these slurries is analysed on the basis of their basic properties, i.e. density, contractual viscosity, water separation, structural strength, volumetric density, hydraulic conductivity, compressive and tensile strength. The mandated requirements for slurries employed in the construction of cut-off walls in flood embankments are listed as a usefulness criteria. The article presents the potential uses of fly ash from SSTT in hardening slurry technology. It also suggests directions for further research to fully identify other potential uses of this by-product in this field.

The growing number of municipal sewage treatment plants in Poland raises the problem of managing more and more sludge. The thermal treatment of municipal sewage sludge (TTMSS), which significantly reduces the volume of waste, results in an increase in the concentration of heavy metals in the fly ashes – the final products of the process. The search for methods of utilization of fly ash from TTMSS resulted in attempts to use it in hardening slurries widely used in hydro-engineering. Due to the nature of the application of this material in the cut-off walls (exposure to groundwater flow) one of the key issues is the degree of heavy metal immobilization. The paper attempted to determine the degree of leaching of selected heavy metals from the hardened hardening slurry, composed of fly ash from TTMSS. For this purpose, the eluates were prepared from samples, after various periods of curing, using a dynamic short-term method called “Batch test”. The liquid used for leaching was: distilled water and 0.1 molar EDTA solution – to determine the amount of potentially mobile heavy metal forms. The results show the possibility of the safe usage of fly ash from TTMSS as an additive for hardening slurries.

Hardening slurries (water-bentonite-binder mixtures) constitute a well-established material used broadly, i.a., for cut-off walls in civil and water engineering. Although they usually contain Portland cement, similar to common concrete, their properties differ greatly, mostly due to a much higher water content. This characteristic of hardening slurries creates unique opportunities for the utilization of significant quantities of industrial by-products that are deemed problematic in the concrete industry. This article investigates the effect of the addition of by-products of fluidized-bed combustion of hard, brown coal and municipal sewage sludge, as well as ground granulated blast furnace slag, on the properties of slurries. Unconfined compressive strength tests, as well as mercury porosimetry, scanning electron microscopy, and X-ray diffraction analyses were performed. The results suggest that it is possible to design hardening slurry mixes of desired properties, both in liquid and solid state, containing at least 100–300 kg/m³ of industrial waste. This includes cement-free slurries based entirely on industrial by-products as binders. In addition, the analyzed slurries exhibited good chemical resistance to landfill eluates, at the same time effectively immobilizing heavy metals. It was concluded that hardening slurry technology can ensure the safe deposition of significant amounts of waste that would be otherwise difficult to manage, thus contributing to the circular economy concept.

An increasing number of municipal sewage treatment plants in Poland, desirable from an environmental perspective, raises the problem of managing the growing volume of sewage sludge. The thermal treatment of municipal sewage sludge (TTMSS) method, by greatly reducing the waste volume, increases the heavy metal concentration in fly ash (primary, end product of the treatment process), which may constitute a risk factor when attempting to utilize them economically. The research paper concentrates on determining the TTMSS fly ash heavy metal leaching level. For this purpose, ash samples were subjected to leaching with the batch and percolation tests, and the heavy metal content in eluates was determined by the FAAS method. The obtained results served as a base to determine the level of heavy metal immobilization in the ash, the element release mechanism (percolation test), and the impact of the L/S (liquid to solid) ratio and pH on the heavy metal leaching intensity (percolation test). The conducted research indicated high immobilization of heavy metals in TTMSS fly ash, regardless of the applied study method, which corresponds to the results of other researchers. Lead was the most intensively eluted metal.

In recent years, there has been a marked increase in the amount of municipal waste generated in Poland. In the context of circular economy assumptions, the key is the availability of technologies that would make it possible to safely process and reuse waste, especially when it is difficult to manage. One such direction is thermal waste treatment. In 2020, 21.6% of all municipal waste was subjected to this process. Consequently, the amount of ash generated is significant (approximately 2,823,000 tons annually). One of the uses of waste materials is the sealing of earth hydrotechnical facilities, such as flood embankments, water dams, and embankments of waste landfills. For this purpose, cut-off screens made of hardening slurries are used. In order to improve the tightness and corrosion resistance of hardening suspensions, combustion by-products are added to their composition. The article presents an assessment of the possibility of using ashes from municipal waste incineration as an additive to hardening slurries. It also discusses the technological and operational parameters of hardening slurries with the addition of the ashes in question. Binding requirements for hardening slurries used for the construction of cut-off walls is also defined. The experiment showed that the tested hardening slurries meet most of the suitability criteria. Further research directions are proposed to fully identify other properties of hardening slurries in terms of their environmental impact.