The article discusses the results of examining the impact of aggressive solutions on specimens of mortars with a slag-ash binder. Bar specimens were exposed to unidirectional diffusion of sodium chloride and sodium sulphate for 90 days. Next, the specimens were subjected to flexural and compressive strength tests, ion content tests, XRD phase composition tests, and microstructural SEM-EDS tests. The test results indicated that aggressive solution action resulted in decreased flexural strength, however, it did not impact the compressive strength of mortars. A minor impact of chloride ions on the pH of the pore liquid was recorded, while the tests did not show any influence of sulphate ions. Furthermore, aggressive ion concentration decreased in deeper specimen slices. Specimen phase composition testing after chloride ion action indicated the presence of a small amount of Friedel’s salt, while regular sodium chloride crystals were identified in the microscopic image. The performance properties of mortars exposed to the action of aggressive solutions were maintained.
Hardening slurries (water-bentonite-binder mixtures) constitute a well-established material used broadly, i.a., for cut-off walls in civil and water engineering. Although they usually contain Portland cement, similar to common concrete, their properties differ greatly, mostly due to a much higher water content. This characteristic of hardening slurries creates unique opportunities for the utilization of significant quantities of industrial by-products that are deemed problematic in the concrete industry. This article investigates the effect of the addition of by-products of fluidized-bed combustion of hard, brown coal and municipal sewage sludge, as well as ground granulated blast furnace slag, on the properties of slurries. Unconfined compressive strength tests, as well as mercury porosimetry, scanning electron microscopy, and X-ray diffraction analyses were performed. The results suggest that it is possible to design hardening slurry mixes of desired properties, both in liquid and solid state, containing at least 100–300 kg/m3 of industrial waste. This includes cement-free slurries based entirely on industrial by-products as binders. In addition, the analyzed slurries exhibited good chemical resistance to landfill eluates, at the same time effectively immobilizing heavy metals. It was concluded that hardening slurry technology can ensure the safe deposition of significant amounts of waste that would be otherwise difficult to manage, thus contributing to the circular economy concept.
1 June 2016 in Archives of Hydro-Engineering and Environmental Mechanics
In Poland, in recent years, there has been a rapid accumulation of sewage sludge - a by-product in the treatment of urban wastewater. This has come about as a result of infrastructure renewal, specifically, the construction of modern sewage treatment plants. The more stringent regulations and strategic goals adopted for modern sewage management have necessitated the application of modern engineering methodology for the disposal of sewage sludge. One approach is incineration. As a consequence, the amount of fly ash resulting from the thermal treatment of municipal sewage sludge has grown significantly. Hence, intensive work is in progress for environmentally safe management of this type of waste. The aim of the experiment was to evaluate the possibility of using the fly ash that results from municipal sewage sludge thermal treatment (SSTT) as an additive to hardening slurries. This type of hardening slurry with various types of additives, e.g. coal combustion products, is used in the construction of cut-off walls in hydraulic structures. The article presents the technological and functional parameters of hardening slurries with an addition of fly ash obtained by SSTT. Moreover, the usefulness of these slurries is analysed on the basis of their basic properties, i.e. density, contractual viscosity, water separation, structural strength, volumetric density, hydraulic conductivity, compressive and tensile strength. The mandated requirements for slurries employed in the construction of cut-off walls in flood embankments are listed as a usefulness criteria. The article presents the potential uses of fly ash from SSTT in hardening slurry technology. It also suggests directions for further research to fully identify other potential uses of this by-product in this field.
Strength and permeability properties along with microstructural evolution of hardened slurries composed of fly ash from fluidal bed combustion of brown coal and an addition of OPC/BFSC is assessed in this paper. An increase in the amount of fly ash in slurries influences the development of mechanical strength and a decrease of hydraulic conductivity. SEM, XRD, and porosity analyses confirmed formation of watertight microstructures. The structure of slurries is composed of ettringite, C-S-H phase, AFt, and AFm phases. Ettringite crystallises as relatively short needles forming compact clusters or intermixed with the C-S-H phase. The occurring C-S-H phases are mainly of type I - fibrous and type II - honeycomb.
1 November 2012 in Archives of Environmental Protection
This article presents ways of possible utilization and application of fl uidal combustion wastes as active additives to hardening slurries which are used to seal environment protection structures, i.e. cut-off walls in waste dumps and wastewater treatment plants. Cut-off walls are often exposed to fi ltrating action of eluates - polluted (aggressive) waters. Results of hydraulic conductivity tests of slurries after their long-term (210 days) fi ltration with eluates from a municipal waste dump and with tap water are presented. Porosity tests were also conducted to show the porosity structure of the fi ltered slurries. Additionally, compressive strength of slurries maturing in tap water and waste dump eluates was tested in parallel.
In recent years, there has been a marked increase in the amount of municipal waste generated in Poland. In the context of circular economy assumptions, the key is the availability of technologies that would make it possible to safely process and reuse waste, especially when it is difficult to manage. One such direction is thermal waste treatment. In 2020, 21.6% of all municipal waste was subjected to this process. Consequently, the amount of ash generated is significant (approximately 2,823,000 tons annually). One of the uses of waste materials is the sealing of earth hydrotechnical facilities, such as flood embankments, water dams, and embankments of waste landfills. For this purpose, cut-off screens made of hardening slurries are used. In order to improve the tightness and corrosion resistance of hardening suspensions, combustion by-products are added to their composition. The article presents an assessment of the possibility of using ashes from municipal waste incineration as an additive to hardening slurries. It also discusses the technological and operational parameters of hardening slurries with the addition of the ashes in question. Binding requirements for hardening slurries used for the construction of cut-off walls is also defined. The experiment showed that the tested hardening slurries meet most of the suitability criteria. Further research directions are proposed to fully identify other properties of hardening slurries in terms of their environmental impact.