Polydimethylsiloxane (PDMS), a silicone-based elastomeric polymer, is generally cured by applying heat to a mixture of a PDMS base and crosslinking agent, and its material properties differ according to the mixing ratio and heating conditions. In this study, we analyzed the effects of different curing processes on the various properties of PDMS thin films prepared by mixing a PDMS solution comprising a PDMS base and a crosslinking agent in a ratio of 10:1. The PDMS thin films were cured using three heat transfer methods: convection heat transfer using an oven, conduction heat transfer using a hotplate, and conduction heat transfer using an ultrasonic device that generates heat internally from ultrasonic vibrations. The physical, chemical, mechanical, and tribological properties of the PDMS thin films were assessed after curing. The polymer chains in the PDMS thin films varied according to the heat transfer method, which resulted in changes in the mechanical and tribological properties. The ultrasonicated PDMS thin film exhibited the highest crystallinity, and hence, the best mechanical, friction, and wear properties.

The purpose of this study is to improve the mechanical durability and surface frictional characteristics of polymer/ceramic-based composite materials. Polydimethylsiloxane (PDMS)/glass bubble (GB) composite specimens are prepared at various weight ratios (PDMS:GB) by varying the amount of micro-sized GBs added to the PDMS. The surface, mechanical, and tribological characteristics of the PDMS/GB composites are evaluated according to the added ratios of GBs. The changes in internal stress according to the indentation depth after contacting with a steel ball tip to the bare PDMS and PDMS/GB composites having different GB densities are compared through finite element analysis simulation. The elastic modulus is proportional to the GB content, while the friction coefficient generally decreases as the GB content increases. A smaller amount of GB in the PDMS/GB composite results in more surface damage than the bare PDMS, but a significant reduction in wear rate is achieved when the ratio of PDMS:GB is greater than 100:5.

Polydimethylsiloxane (PDMS) has many advantages, but the friction coefficient generated by contact with the counter material is high. The purpose of this study is to reduce the friction coefficient by forming hierarchical micro/nanopatterns on the PDMS surface using the imprinting method. In addition, the optimum conditions for reducing the friction coefficient by controlling the sliding speed and normal load were determined. After contacting flat bare PDMS and hierarchical micro/nanostructured PDMS with a counter tip made of polyurethane (PU), the change in friction with sliding speed and vertical load was evaluated. Under normal load conditions, the average friction coefficient of the bare PDMS decreased as the sliding speed increased, and that of the patterned PDMS slightly increased. Regardless of the sliding speed, the friction coefficient decreased as the normal load increased for both specimens. At a sliding speed of 4 mm/s under a load of 10 mN, the friction reduction effect of the pattern structure was the largest at 79%. Overall, the greatest friction reduction effect (84%) was confirmed in patterned PDMS with the lowest friction coefficient under the conditions of 4 mm/s, 50 mN, compared to bare PDMS with the highest friction coefficient under the conditions of 4 mm/s, 10 mN.