This study presents a novel approach for biorefining oat husks into furfural, leveraging a unique pilot-scale setup. Unlike conventional furfural manufacturing processes, which often result in substantial cellulose degradation and environmental concerns associated with sulfuric acid usage, our method utilizes phosphoric acid as a catalyst to achieve high furfural yield while minimizing cellulose destruction. Drawing on our research conducted in a distinctive pilot-scale environment, we successfully developed and implemented a tailored biorefining process for oat husks. Through meticulous experimentation, we attained a remarkable furfural yield of 11.84% from oven-dried mass, accompanied by a 2.64% yield of acetic acid. Importantly, our approach significantly mitigated cellulose degradation, preserving 88.31% of the cellulose content in oat husks. Existing catalytic (H₂SO₄) furfural manufacturing processes often lead to substantial cellulose degradation (40–50%) in lignocellulosic leftover during the pretreatment stage. As a result of the research, it was also possible to reduce the destruction of cellulose in the lignocellulose leftover to 11.69% of the output (initial) cellulose of oat husks. This research underscores the feasibility and sustainability of utilizing oat husks as a valuable feedstock for furfural production, highlighting the potential of phosphoric acid as a catalyst in biorefining processes. By showcasing our unique pilot-scale methodology, this study contributes to advancing the field of environmentally friendly biorefining technologies.

From birch wood, it is possible to obtain both acetic acid and 2-furaldehyde as valuable value-added products. The main objective of this study was to develop a new wasteless technology for obtaining 2-furaldehyde, acetic acid, and lignocellulose (LC) residue usable as feedstock in further processing such as thermomechanical (TMP), alkaline peroxide mechanical (APMP), and sulfate pulping processes. To achieve this objective several screening tests were performed, and a further experimental plan was developed using DesignExpert11. Process yields were analyzed both in terms of total yield and at individual time increments. In addition, the obtained LC residue was also characterized. A unique bench-scale reactor system was used to obtain an LC material without pentoses and with maximum preservation of cellulose fiber for further research. Studies on the deacetylation and dehydration of birch wood hemicelluloses of pentose monosaccharides to 2-furaldehyde and acetic acid using orthophosphoric acid as a catalyst were carried out. Results showed that, depending on the used pre-treatment conditions, the 2-furaldehyde yield was from 0.04% to 10.84% oven dry mass (o.d.m.), the acetic acid yield was from 0.51% to 6.50% o.d.m., and the LC residue yield was from 68.13% to 98.07% o.d.m. with minimal content of admixtures. Process optimization using DesignExpert11 revealed that the main pre-treatment process parameters that influenced the yield of 2-furaldehyde in the pre-treatment process were process temperature (53.3%) and process duration (29.8%).

Furfural is a biomass derived-chemical that can be used to replace petrochemicals. In this study, dilute sulphuric acid hydrolysis was used for hemicelluloses secession from birch wood. The reaction was investigated at different biomass treatment times (10-90 min, increasing it by 10 min). We found that the greatest amount of furfural 1.4-2.6%, which is 9.7-17.7% from theoretical possible yield, was formed in the first 30 min of the beginning of birch wood pentoses monosaccharide dehydration, but the greatest yield of furfural 10.3%, which is 70.0% from the theoretical yield, can be obtained after 90 min. Given that furfural yield generally does not exceed 50% from the theoretical amount, the result can be considered as very good.

This study seeks to improve the effectiveness of the pretreatment stage when direct furfural production is integrated into the concept of a lignocellulosic biomass biorefinery. First of all, the catalytic effects of different phosphorus-containing salts (AlPO₄, Ca₃(PO₄)₂, FePO₄, H₃PO₄, NaH₂PO₄) were analysed in hydrolysis for their ability to convert birch wood C-5 carbohydrates into furfural. The hydrolysis process was performed with three different amounts of catalyst (2, 3 and 4 wt.%) at a constant temperature (175 °C) and treatment time (90 min). It was found that the highest amount of furfural (63–72%, calculated based on the theoretically possible yield (% t.p.y.)) was obtained when H₃PO₄ was used as a catalyst. The best furfural yield among the used phosphorus-containing salts was obtained with NaH₂PO₄: 40 ± 2%. The greatest impact on cellulose degradation during the hydrolysis process was observed using H₃PO₄ at 12–20% of the initial amount, while the lowest degradation was observed using NaH₂PO₄ as a catalyst. The yield of furfural was 60.5–62.7% t.p.y. when H₃PO₄ and NaH₂PO₄ were combined (1:2, 1:1, or 2:1 at a catalyst amount of 3 wt.%); however, the amount of cellulose that was degraded did not exceed 5.2–0.3% of the starting amount. Enzymatic hydrolysis showed that such pretreated biomass could be directly used as a substrate to produce glucose. The highest conversion ratio of cellulose into glucose (83.1%) was obtained at an enzyme load of 1000 and treatment time of 48 h.

Latvia is a large manufacturer of plywood in Eastern Europe, with an annual production of 250,000 m³. In Latvia’s climatic conditions, birch (Betula pendula) is the main tree species that is mainly used for plywood production. A significant part of the processed wood makes up residues like veneer shorts, cores, and cut-offs (up to 30%), which have a high potential for value-added products. The aim of this research was to comprehensively characterize lignocellulosic (LC) biomass that was obtained after 2-furaldehyde production in terms of further valorization of this resource. The polymeric cellulose-enriched material can be used in the new biorefinery concept for the production of 2-furaldehyde, acetic acid, cellulose pulp, thermomechanical (TMP) and an alkaline peroxide mechanical (APMP) pulping process. In addition, we experimentally developed the best 2-furaldehyde production conditions to optimize the purity and usability of cellulose in the leftovers of the LC material. The best experimental results in terms of both 2-furaldehyde yield and the purity of residual lignocellulose were obtained if the catalyst concentration was 70%, the catalyst amount was 4 wt.%, the reaction temperature was 175 °C,and the treatment time was 60 min. After process optimization with DesignExpert11, we concluded that the best conditions for maximal glucose content (as cellulose fibers) was a catalyst concentration of 85%, a catalyst amount of 5 wt.%, a temperature of 164 °C, and a treatment time of 52 min.

The necessity for the reduction in greenhouse gas emissions, the growing demand for the improvement of biorefinery technologies, and the development of new biorefining concepts oblige us as a society, and particularly us, as scientists, to develop novel biorefinery approaches. The purpose of this study is to thoroughly evaluate the leftover lignocellulosic (LC) biomass obtained after the manufacture of 2-furaldehyde, with the intention of further valorizing this resource. This study demonstrates that by using thermomechanical and alkaline peroxide mechanical pulping techniques, birch wood chips can be used in the new biorefinery processing chain for the production of 2-furaraldehyde, acetic acid, and cellulose pulp. In addition, the obtained lignocellulosic residue is also characterized. To produce a lignocellulosic material without pentoses and with the greatest amount of cellulose fiber preserved for future use, a novel bench-scale reactor technology is used. Studies were conducted utilizing orthophosphoric acid as a catalyst to deacetylate and dehydrate pentose monosaccharides found in birch wood, converting them to 2-furaldehyde and acetic acid. The results showed that, with the least amount of admixtures, the yields of the initial feedstock’s oven-dried mass (o.d.m.) of 2-furaldehyde, acetic acid, and lignocellulose residue ranged from 0.04 to 10.84%, 0.51 to 6.50%, and 68.13 to 98.07%, respectively, depending on the pretreatment conditions utilized. The ideal 2-furaldehyde production conditions with reference to the purity and usability of cellulose in residual lignocellulosic material were also discovered through experimental testing. The experiment that produced the best results in terms of 2-furaldehyde yield and purity of residual lignocellulose used a catalyst concentration of 70%, a catalyst quantity of 4%, a reaction temperature of 175 °C, and a treatment period of 60 min. It was possible to create pulp with a tensile index similar to standard printing paper by mechanically pulping the necessary LC residue with alkaline peroxide, proving that stepwise 2-furaldehyde production may be carried out with subsequent pulping to provide a variety of value-added goods.