Metal oxide nanoparticles and their composites have garnered significant attention in water treatment and environmental cleanup due to their unique physicochemical properties.

Hazardous chemicals like toxic organic dyes are very harmful to the environment and their removal is quite challenging. Therefore there is a necessity to develop techniques, which are environment friendly, cost-effective and easily available in nature for water purification and remediation. The present research work is focused on the development` and characterization of the ecofriendly semi-interpenetrating polymer network (semi-IPN) nanocomposite hydrogels composed of polyvinyl alcohol (PVA) and alginate (Alg) hydrogel beads incorporating natural bentonite (Bent) clay as a beneficial adsorbent for the removal of toxic methylene blue (MB) from aqueous solution. PVA−Alg/Bent nanocomposite hydrogel beads with different Bent content (0, 10, 20, and 30 wt%) were synthesized via external ionic gelation method. The designed porous and steady structure beads were characterized by the use of Fourier transform infrared spectroscopy (FTIR), energy-dispersive X-ray spectroscopy (EDX), and scanning electron microscopy (SEM). The performance of the beads as MB adsorbents was investigated by treating aqueous solutions in batch mode. The experimental results indicated that the incorporation of Bent (30 wt%) in the nanocomposite formulation sustained the porous structure, preserved water uptake, and increased MB removal efficiency by 230% compared to empty beads. Designed beads possessed higher affinity to MB at high pH 8, 30 °C, and fitted well to pseudo-second-order kinetic model with a high correlation coefficient. Moreover, the designed beads had good stability and reusability as they exhibited excellent removal efficiency (90%) after six consecutive adsorption-desorption cycles. The adsorption process was found be combination of both monolayer adsorption on homogeneous surface and multilayer adsorption on heterogeneous surface. The maximum adsorption capacity of the designed beads system as calculated by Langmuir isotherm was found to be 51.34 mg/g, which is in good agreement with the reported clay-related adsorbents. The designed semi-IPN PVA−Alg/Bent nanocomposite hydrogel beads demonstrated good adsorbent properties and could be potentially used for MB removal from polluted water.

In the field of orthopedics and traumatology, polyether ether ketone (PEEK) serves a significant role as a suitable alternative to traditional metal-based implants like titanium. PEEK is being used more commonly to replace traditional dental products. For bonding with various adhesive agents and preserved teeth, the surface alteration of PEEK was investigated. The aim of this research was to understand how different types and contents of nano-sized silica (SiO₂) fillers influenced the surface and mechanical properties of PEEK nanocomposites used in prosthodontics. In this work, PEEK based nanocomposites containing hydrophilic or hydrophobic nano-silica were prepared by a compression molding technique. The influence of nano-SiO₂ type and content (10, 20 and 30% wt) on surface properties of the resultant nanocomposites was investigated by the use of scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), surface roughness analysis, and contact angle measurement. The crystalline structures of PEEK/SiO₂ nanocomposites were examined by X-ray diffraction (XRD) spectroscopy. Mechanical properties were measured by microhardness, elastic compression modulus, and flexural strength. All nanocomposites showed increased surface roughness compared to pure PEEK. SEM images revealed that nanocomposites filled with low content hydrophobic nano-SiO₂ showed uniform dispersion within the PEEK matrix. The introduction of 10 wt% of hydrophobic nano-SiO₂ to the PEEK matrix improved elastic modulus, flexural strength, and microhardness, according to the findings. The addition of nano-SiO₂ fillers in a higher weight percentage, over 10%, significantly damages the mechanical characteristics of the resultant nanocomposite. On the basis of the obtained results, PEEK/SiO₂ nanocomposites loaded with low content hydrophobic nano-SiO₂ are recommended as promising candidates for orthopedic and prosthodontics materials.

Global warming and climate changes are among the biggest modern-day environmental problems, the main factor causing these problems is the greenhouse gas effect. The increased concentration of carbon dioxide in the atmosphere resulted in capturing increased amounts of reflected sunlight, causing serious acute and chronic environmental problems. The concentration of carbon dioxide in the atmosphere reached 421 ppm in 2022 as compared to 280 in the 1800s, this increase is attributed to the increased carbon dioxide emissions from the industrial revolution. The release of carbon dioxide into the atmosphere can be minimized by practicing carbon capture utilization and storage methods. Carbon capture utilization and storage (CCUS) has four major methods, namely, pre-combustion, post-combustion, oxyfuel combustion, and direct air capture. It has been reported that applying CCUS can capture up to 95% of the produced carbon dioxide in running power plants. However, a reported cost penalty and efficiency decrease hinder the wide applicability of CCUS. Advancements in the CCSU were made in increasing the efficiency and decreasing the cost of the sorbents. In this review, we highlight the recent developments in utilizing both physical and chemical sorbents to capture carbon. This includes amine-based sorbents, blended absorbents, ionic liquids, metal-organic framework (MOF) adsorbents, zeolites, mesoporous silica materials, alkali-metal adsorbents, carbonaceous materials, and metal oxide/metal oxide-based materials. In addition, a comparison between recently proposed kinetic and thermodynamic models was also introduced. It was concluded from the published studies that amine-based sorbents are considered assuperior carbon-capturing materials, which is attributed to their high stability, multifunctionality, rapid capture, and ability to achieve large sorption capacities. However, more work must be done to reduce their cost as it can be regarded as their main drawback.

Globally, water contamination by heavy metals is a serious problem that affects the environment and human health. Adsorption is the most efficient way of water treatment for eliminating heavy metals. Various hydrogels have been prepared and used as adsorbents to remove heavy metals. By taking advantage of poly(vinyl alcohol) (PVA), chitosan (CS), cellulose (CE), and the process for physical crosslinking, we propose a simple method to prepare a PVA-CS/CE composite hydrogel adsorbent for the removal of Pb(II), Cd(II), Zn(II) and Co(II) from water. Structural analyses of the adsorbent were examined by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy-energy dispersive X-ray (SEM-EDX) analysis, and X-ray diffraction (XRD). PVA-CS/CE hydrogel beads had a good spherical shape together with a robust structure and suitable functional groups for the adsorption of heavy metals. The effects of adsorption parameters such as pH, contact time, adsorbent dose, initial concentration of metal ions, and temperature on the adsorption capacity of PVA-CS/CE adsorbent were studied. The adsorption characteristics of PVA-CS/CE for heavy metals may be completely explained by pseudo-second-order adsorption and the Langmuir adsorption model. The removal efficiency of PVA-CS/CE adsorbent for Pb(II), Cd(II), Zn(II), and Co(II) was 99, 95, 92, and 84%, respectively, within 60 min. The heavy metal’s hydrated ionic radius may be crucial in determining the adsorption preference. After five consecutive adsorption–desorption cycles, the removal efficiency remained over 80%. As a result, the outstanding adsorption-desorption properties of PVA-CS/CE can potentially be extended to industrial wastewater for heavy metal ion removal.