Different types of heating systems have been developed lately, representing a growing interest in both the academic and industrial sectors. Based on the Joule effect, fibrous structures can produce heat once an electrical current is passed, whereby different approaches have been followed. For that purpose, materials with electrical and thermal conductivity have been explored, such as carbon-based nanomaterials, metallic nanostructures, intrinsically conducting polymers, fibers or hybrids. We review the usage of these emerging nanomaterials at the nanoscale and processed up to the macroscale to create heaters. In addition to fibrous systems, the creation of composite systems for electrical and thermal conductivity enhancement has also been highly studied. Different techniques can be used to create thin film heaters or heating textiles, as opposed to the conventional textile technologies. The combination of nanoscale and microscale materials gives the best heating performances, and some applications have already been proven, even though some effort is still needed to reach the industry level.

The rising threats to worldwide security (affecting the military, first responders, and civilians) urge us to develop efficient and versatile technological solutions to protect human beings. Soldiers, medical personnel, firefighters, and law enforcement officers should be adequately protected, so that their exposure to biological warfare agents (BWAs) is minimized, and infectious microorganisms cannot be spread so easily. Current bioprotective military garments include multilayered fabrics integrating activated carbon as a sorptive agent and a separate filtrating layer for passive protection. However, secondary contaminants emerge following their accumulation within the carbon filler. The clothing becomes too heavy and warm to wear, not breathable even, preventing the wearer from working for extended hours. Hence, a strong need exists to select and/or create selectively permeable layered fibrous structures with bioactive agents that offer an efficient filtering capability and biocidal skills, ensuring lightweightness, comfort, and multifunctionality. This review aims to showcase the main possibilities and trends of bioprotective textiles, focusing on metal–organic frameworks (MOFs), inorganic nanoparticles (e.g., ZnO-based), and organic players such as chitosan (CS)-based small-scale particles and plant-derived compounds as bioactive agents. The textile itself should be further evaluated as the foundation for the barrier effect and in terms of comfort. The outputs of a thorough, standardized characterization should dictate the best elements for each approach.

Smart textiles have become a promising area of research for heating applications. Coatings with nanomaterials allow the introduction of different functionalities, enabling doped textiles to be used in sensing and heating applications. These coatings were made on a piece of woven cotton fabric through screen printing, with a different number of layers. To prepare the paste, nanomaterials such as graphene nanoplatelets (GNPs) and multiwall carbon nanotubes (CNTs) were added to a polyurethane-based polymeric resin, in various concentrations. The electrical conductivity of the obtained samples was measured and the heat-dissipating capabilities assessed. The results showed that coatings have induced electrical conductivity and heating capabilities. The highest electrical conductivity of (9.39 ± 1.28 × 10⁻¹ S/m) and (9.02 ± 6.62 × 10⁻² S/m) was observed for 12% (w/v) GNPs and 5% (w/v) (CNTs + GNPs), respectively. The sample with 5% (w/v) (CNTs + GNPs) and 12% (w/v) GNPs exhibited a Joule effect when a voltage of 12 V was applied for 5 min, and a maximum temperature of 42.7 °C and 40.4 °C were achieved, respectively. It can be concluded that higher concentrations of GNPs can be replaced by adding CNTs, still achieving nearly the same performance. These coated textiles can potentially find applications in the area of heating, sensing, and biomedical applications.

We report on-demand formation of emulsions stabilised by interfacial nanoscale networks. These are formed through biocatalytic dephosphorylation and self-assembly of Fmoc(9-fluorenylmethoxycarbonyl)dipeptide amphiphiles in aqueous/organic mixtures. This is achieved by using alkaline phosphatase which transforms surfactant-like phosphorylated precursors into self-assembling aromatic peptide amphiphiles (Fmoc-tyrosine-leucine, Fmoc-YL) that form nanofibrous networks. In biphasic organic/aqueous systems, these networks form preferentially at the interface thus providing a means of emulsion stabilisation. We demonstrate on-demand emulsification by enzyme addition, even after storage of the biphasic mixture for several weeks. Experimental (Fluorescence, FTIR spectroscopy, fluorescence microscopy, electron microscopy, atomic force microscopy) and computational techniques (atomistic molecular dynamics) are used to characterise the interfacial self-assembly process.

In this work, we describe the development of a computational screening approach for tripeptide-dipeptide co-assembly. Studies are carried out both in water and in oil–water mixtures, to evaluate possible candidates that give rise to hydrogels or more stable emulsions, respectively, through nanofibre formation. The results give rise to design rules for the identification of promising systems for numerous types of soft materials. The possibility of achieving innovative functional materials through the co-assembly of tripeptides and dipeptides is studied. In particular, coarse-grained simulations allowed for the extraction of some promising dipeptides that, together with H-aspartyl-phenylalanyl-phenylalanine-OH (DFF), are able to act as hydrogelators or emulsifiers with superior characteristics relative to DFF on its own.