Laboratoire d’Etudes et de Recherche sur le Matériau Bois, Faculté des Sciences et Technologies, Université de Lorraine, EA 4370, Boulevard des Aiguillettes, BP 70239, 54506 Vandœuvre-Lès-Nancy CEDEX, France
Dr. Arnaud Besserer
Laboratoire d’Etudes et de Recherche sur le Matériau Bois, Faculté des Sciences et Technologies, Université de Lorraine, EA 4370, Boulevard des Aiguillettes, BP 70239, 54506 Vandœuvre-Lès-Nancy CEDEX, France
Wood is an increasingly demanded renewable resource and an important raw material for construction and materials. In addition, new consumption habits are leading to the production of ever greater volumes of waste wood, which constitutes a feedstock that can be mobilized for the cascade production of new materials such as particleboard. However, current legislation and wood waste recycling processes need to be improved in order to maximize the volumes that can be reused and to upgrade the properties of the recycled wood. This review describes wood waste flows and volumes available in Europe, the current French and European legislation, and the innovations under development in this field: innovative automated sorting techniques, physical-chemical processes for cleaning residual glue from the surface of wood particles, cleaning of MDF, and bioremediation processes for cleaning hazardous wood contaminated by heavy metals or creosote.
With the production of wood waste constantly on the increase, questions relating to its recycling and reuse are becoming unavoidable. The reuse of wood and its derivatives can be achieved through the production of composite materials, using wood as a reinforcement or even as the main matrix of the material. Additive manufacturing (also known as 3D printing) is an emerging and very promising process, particularly with the use of bio-based and renewable materials such as wood or its industrial derivatives. The aim of this paper is to present an overview of additive manufacturing processes using wood as a raw material and including industrial solutions. After presenting wood and its waste products, all the additive manufacturing processes using wood or its industrial derivatives will be presented. Finally, for each 3D printing process, this review will consider the current state of research, the industrial solutions that may exist, as well as the main challenges and issues that still need to be overcome.
Copper-based formulations of wood preservatives are widely used in industry to protect wood materials from degradation caused by fungi. Wood treated with preservatives generate toxic waste that currently cannot be properly recycled. Despite copper being very efficient as an antifungal agent against most fungi, some species are able to cope with these high metal concentrations. This is the case for the brown-rot fungus Rhodonia placenta and the white-rot fungus Phanerochaete chrysosporium, which are able to grow efficiently in pine wood treated with Tanalith E3474. Here, we aimed to test the abilities of the two fungi to cope with copper in this toxic environment and to decontaminate Tanalith E-treated wood. A microcosm allowing the growth of the fungi on industrially treated pine wood was designed, and the distribution of copper between mycelium and wood was analysed within the embedded hyphae and wood particles using coupled X-ray fluorescence spectroscopy and Scanning Electron Microscopy (SEM)/Electron Dispersive Spectroscopy (EDS). The results demonstrate the copper biosorption capacities of P. chrysosporium and the production of copper-oxalate crystals by R. placenta. These data coupled to genomic analysis suggest the involvement of additional mechanisms for copper tolerance in these rot fungi that are likely related to copper transport (import, export, or vacuolar sequestration).
Palladium (Pd) nanoparticle catalysis has attracted increasing attention due to its efficient catalytic activity and its wide application in environmental protection and chemical synthesis. In this work, Pd nanoparticles (about 71 nm) were synthesized in aqueous solution by microwave-assisted thermal synthesis and immobilized in beech wood blocks as Pd@wood catalysts. The wood blocks were first hydrothermally treated with 10% NaOH solution to improve the internal structure and increase their porosity, thereby providing favorable attachment sites for the formed Pd nanoparticles. The stable deposition of Pd nanoparticle clusters on the internal channels of the wood blocks can be clearly observed. In addition, the catalytic performance of the prepared Pd@wood was investigated through two model reactions: the reduction of 4-nitrophenol and Cr(VI). The Pd@wood catalyst showed 95.4 g−1 s−1 M−1 of normalized rate constant knorm and 2.03 min−1 of the TOF, respectively. Furthermore, Pd nanoparticles are integrated into the internal structure of wood blocks by microwave-assisted thermal synthesis, which is an effective method for wood functionalization. It benefits metal nanoparticle catalysis in the synthesis of fine chemicals as well as in industrial wastewater treatment.