A magnetically separable Co(II)-imprinted polymer based on mesoporous silica (mag@silica-CIP) was synthesized for use as an adsorbent for the selective removal of Co(II). The optimal pH for Co(II) adsorption was found to be 5. Increasing the amount of the Co(II)-imprinted polymer layer on the surface of mag@silica led to an increase in the maximum adsorption capacity for Co(II). The mag@silica-CIP selectively adsorbed Co(II) even in the presence of competing species such as Fe(II), Ni(II), and Mn(II) ions. Thermodynamic experiments revealed that the adsorption of Co(II) by mag@silica-CIP is an endothermic and spontaneous process.

The present study aimed to evaluate the utility of the cement solidification process for stably disposing of waste ion exchange resin generated during the treatment of radioactive wastewater. The cement solidification process using the in-drum mixing system was selected to be used for the solidification process of waste ion exchange resins. The disposal safety of waste forms was evaluated according to the waste acceptance criteria (WAC) applicable to domestic waste disposal sites, and the tests were conducted for six test items provided in the WAC. A total of 15 representative samples were collected from the waste-form drums produced using the optimum operating conditions, and their structural stability for disposal considerations was evaluated. In addition, the leaching index of the samples was 11.05, 10.12, 8.39 for Co, Sr, and Cs, respectively, and it was found to exceed 6, the leaching index standard of WAC. The results confirmed that cement waste forms including waste ion exchange resins produced through this process were considered to be conforming to the requirements for disposal safety.

Nonlinear multiphoton absorption induced by focusing near infrared (NIR) femtosecond (fs) laser pulses into a transparent cornea allows surgery on neovascular structures with minimal collateral damage. In this report, we introduce an fs laser-based microsurgery for selective treatment of rat corneal neovascularizations (in vivo). Contiguous tissue effects are achieved by scanning a focused laser pulse below the corneal surface with a fluence range of 2.2–8.6 J/cm². The minimal visible laser lesion (MVL) threshold determined over the corneal neovascular structures was found to be 4.3 J/cm². Histological and optical coherence tomography examinations of the anterior segment after laser irradiations show localized degeneration of neovascular structures without any unexpected change in adjacent tissues. Furthermore, an approximately 30 % reduction in corneal neovascularizations was observed after 5 days of fs laser exposure. The femtosecond laser is thus a promising tool for minimally invasive intrastromal surgery with the aid of a significantly smaller and more deterministic photodisruptive energy threshold for the interaction between the fs laser pulse and corneal neovascular structures.

A method of chemically bonding copper ferrocynide (CuFC) to the surface of a PVDF hollow-fibre membrane (PVDF-CuFC) was designed and the resulting PVDF-CuFC was applied to the effective removal of aqueous cesium (Cs). In order to chemically immobilize CuFC on the surface of the PVDF hollow-fibre membrane, carboxyl groups were introduced onto the membrane surface (PVDF-COOH) to peptide bond with amine groups from CuFC. The introduction of the carboxyl group onto the surface of the PVDF hollow-fibre membrane was confirmed by Fourier-transform infrared spectroscopy (FT-IR), while the immobilization of CuFC was confirmed by scanning electron microscopy with energy dispersed spectroscopy, FT-IR, and thermogravimetric analysis. The PVDF-CuFC showed higher Cs adsorption kinetics and adsorption capacity than PVDF-COOH. Moreover, as the initial pH increased, the amount of Cs adsorption by PVDF-CuFC also increased. However, the amount of Cs adsorption at pH 10 was slightly less. The applicability of PVDF-CuFC as a filter type adsorbent for the treatment of a Cs-contaminated water source is demonstrated by continuous filtration experiments. GRAPHICAL ABSTRACT