The adsorption of Pb(II) and Cd(II) on three commercial microporous activated carbons was analysed. Adsorption kinetics and statistics were investigated, and the results were described with different models. The highest values of the correlation coefficient R² were obtained for the pseudo-second-order kinetics model for all ions tested and all sorbents used. The adsorption process was found to be determined by both diffusion in the liquid layer and intraparticle diffusion. The adsorption equilibrium is very well described by Langmuir, Temkin, Thoth or Jovanovic isotherm models. Based on the values of n from the Freundlich isotherm and K_L from the Langmuir isotherm, the adsorption of cadmium and lead ions was found to be favourable. The highest monolayer capacities were obtained during the adsorption of lead ions (162.19 mg/g) and for cadmium (126.34 mg/g) for activated carbon WG-12. This carbon is characterised by the highest amount of acid functional groups and the largest specific surface area. The adsorption efficiency of the tested ions from natural water is lower than that from a model solution made from deionised water. The lowest efficiencies are obtained when the process occurs from highly mineralised water.

The aim of the study was to evaluate the possibility of applying commercial activated carbons currently used in water treatment plants and modified carbon at 400 and 800 °C in the atmosphere of air, water vapour and carbon dioxide to remove chloramphenicol. Adsorption kinetics was examined for solutions with pH of 2–10. Adsorption kinetics were determined for the initial concentration of chloramphenicol of 161 mg/dm³ and the adsorption isotherm was determined for the concentrations of 161 to 1615 mg/dm³. Of the analysed activated carbons (F-300, F-100, WG-12, ROW 08 Supra and Picabiol), the highest adsorption capacity was obtained for the use of Picabiol (214 mg/g), characterized by the highest specific surface area and pore volume. The pH value of the solution has little effect on the adsorption of chloramphenicol (the highest adsorption was found for pH = 10, qm = 190 mg/g, whereas the lowest—for pH = 6, qm = 208 mg/g). Modification of activated carbon WG-12 at 800 °C caused an increase in adsorption capacity from 195 mg/g (unmodified carbon) to 343 mg/g. A high correlation coefficient was found between the capacity of activated carbons and the total volume of micropores and mesopores. Among the examined adsorption kinetics equations (pseudo-first order, pseudo-second order, Elovich, intraparticle diffusion), the lowest values of the R² correlation coefficient were obtained for the pseudo-first order equation. Other models with high correlation coefficient values described the adsorption kinetics. The adsorption results were modelled by means of the Freundlich, Langmuir, Temkin and Dubibin–Radushkevich adsorption isotherms. For all activated carbons and process conditions, the best match to the test results was obtained using the Langmuir model, whereas the lowest was found for the Dubibin–Radushkevich model.

The aim of the work was to evaluate the possibility of using commercial and modified activated carbons for the removal of oxytetracycline from aqueous solutions. The kinetics and statics of adsorption as well as the effect of the activated carbon dose and solution pH on the efficiency of the oxytetracycline adsorption were analyzed. Based on the study of oxytetracycline adsorption isotherms, the activated carbons were ranked in the following order: F-300 > WG-12 > Picabiol > ROW08 > WACC 8 × 30 > F-100 > WAZ 0.6–2.4. The most effective activated carbons were characterized by large specific surfaces. The best matching results were obtained for: Redlich–Peterson, Thot and Jovanovic models, and lower for the most frequently used Freundlich and Langmuir models. The adsorption proceeded better from solutions with pH = 6 than with pH = 3 and 10. Two ways of modifying activated carbon were also assessed. A proprietary method of activated carbon modification was proposed. It uses the heating of activated carbon as a result of current flow through its bed. Both carbons modified at 400 °C in the rotary kiln and on the proprietary SEOW (Joule-heat) modification stand enabled to obtain adsorbents with higher and comparable monolayer capacities. The advantage of the proposed modification method is low electricity consumption.