The electrochemical behaviour and surface changes on AA6061-T6 alloy exposed to Caribbean seawater from the Cozumel Channel for 30 days under laminar flow (0.1 m s⁻¹) were studied, contrasting then with stationary (no flow) conditions. Monitoring of open-circuit potential and current fluctuations, both considered as electrochemical noise (EN), were employed as two nondestructive methods. The calculated corrosion current, based on Rn, was one order higher in laminar flow. The fluctuations of current were transformed in the frequency domain. Their power spectral density (PSD) plots were obtained in order to gain information concerning the dynamic of the spontaneous release of energy during the corrosion process. The value of the exponent β in PSD graphs suggested that the localised corrosion on AA6061-T6 surface occurs as a persistent stationary process, in which dynamic is controlled by oxygen diffusion and its renewal at the metal interface. The changes in the morphology and elemental composition of the formed layers revealed that the localized attacks occurred in the vicinity of intermetallic particles rich in Fe and Cu, which act as cathodes.

The present work compared the initial stages of corrosion process development on the AM60-AlN metal matrix nanocomposite surface and on AM60, during their exposure for 30 days to simulated acid rain solution (SAR). The AlN nanoparticles were observed as “attached” to those of Mn-rich AlMn intermetallic particles, forming clusters. The introduction of 1.0 wt.% AlN (≈ 80 nm) in the AM60 alloy carried a slight grain refinement and favored the formation of a denser and more protective corrosion layer, suggested by the electrochemical impedance spectroscopy (EIS) values of higher charge transfer resistance (R2) and capacitance, characteristic of the double layer in the presence of corrosion products, and also suggested by Rn (EN) values, compared to those of the AM60 alloy. Thus, the concentration of the released Mg-ions from the composite surface was lower. Due to the increase in time of the SAR solution pH, Al de-alloying may occur, as well as Al(OH)₃ formation, as confirmed by XPS analysis. Due to the presence of Cl-ions in SAR solution, localized corrosion was observed, suggested as fractional Gaussian noise of a stationary and persistent process in time, according to the PSD of the corrosion current fluctuations (EN).

A hybrid material of polystyrene (PS)–ZrO₂ was developed by the sol–gel technique and deposited by spin-coating on AM60 and AM60–AlN nanocomposite surfaces to enhance corrosion resistance in marine environments.${\text{PS–ZrO}}_2$ with an average thickness of ≈$305 \pm 20 \mathrm{nm}$ was dispersed homogeneously, presenting isolated micro–nano-structure defects with air trapped inside, which led to an increase in roughness (≈4 times). The wettability of the coated substrates was close to the hydrophobic border (${\mathsf{\theta }}_{\mathrm{CA}}=90°–94°).$ The coated samples were exposed for 30 days to SME solution, simulating the marine–coastal ambience. The initial pH = 7.94 of the SME shifted to more alkaline pH ≈ 8.54, suggesting the corrosion of the Mg matrix through the coating defects. In the meantime, the release of ${\mathrm{Mg}}^{2+}$ from the ${\text{PS–ZrO}}_2$-coated alloy surfaces was reduced by ≈90% compared to that of non-coated. Localized pitting attacks occurred in the vicinity of Al–Mn and β–Mg₁₇Al₁₂ cathodic particles characteristic of the Mg matrix. The depth of penetration (≈23 µm) was reduced by ≈85% compared to that of non-coated substrates. The protective effect against Cl ions, attributed to the hybrid PS–ZrO₂-coated AM60 and AM60–AlN surfaces, was confirmed by the increase in their polarization resistance (Rp) in 37% and 22%, respectively, calculated from EIS data.

The initial stages of AM60-AlN nanocomposite and AM60 corrosion behaviors were compared over 30 days of exposure to solution ($\mathrm{NaCl}$, ${\mathrm{Na}}_2{\mathrm{SO}}_4$ and ${\mathrm{NaHCO}}_3$), simulating the marine-coastal environment (SME). The incorporation of AlN nanoparticles (1.0 wt.%) in the AM60 alloy matrix favored the lower roughness of the AM60-AlN, associated with the grain refinement in the matrix. During the immersion of the alloys, pH of the SME solution shifted to alkaline values >9, and therefore, the solubility of AlN aluminum hydroxide phases were raised, followed by a slightly higher release of Mg-ions and corrosion rate increase. The chloride ions attributed to the unstability of the Al-Mn phase and $\mathrm{Al}{\left(\mathrm{OH}\right)}_3$ corrosion product was formed in a low content. The composite AM60-AlN presented lower value of the electrochemical noise resistance $\left({\mathrm{R}}_{\mathrm{n}}\right)$, suggesting that the corrosion process occurs with less difficulty. The localized corrosion near the Al-Mn cathodes seems to be stronger on the composite surface, in area and depth of penetration. The corrosion current fluctuations suggested that the corrosion is a weakly persistent process, dominated by the fractional Gaussian noise (fGn).

The Green Internet of Things (GIoTs) has emerged as a transformative paradigm for environmental conservation, enabling autonomous, self-sustaining sensor networks that operate without batteries and with minimal ecological footprint. This approach is especially critical for long-term mangrove monitoring in smart coastal cities, where conventional battery-powered systems are impractical due to frequent, costly, and environmentally disruptive replacements that hinder continuous data collection. This paper presents a self-sustaining GIoT sensing system for mangrove monitoring powered by sedimentary microbial fuel cells (SMFCs), enabling perpetual, battery-less, and zero-emission operation. A spatial dynamic energy management (DPM) strategy is implemented for the efficient integration of a microcontroller unit with a LoRa wireless communication transceiver and the SMFC harvested energy, ensuring a balanced self-sustained approach into a GIoT sensing network. Experimental results demonstrate an average power consumption of 190.45 μW per 14-byte data packet transmission, with each packet containing pH, electrical conductivity and ambient temperature measurements from the mangrove environment. Under the spatial DPM strategy, the network of four sensing nodes exhibited an energy consumption of 1.14 mWh. Given a harvested power density of 15.1 mW/m² from the SMFC, and utilizing a 0.1 F supercapacitor as an energy buffer, the system can support at least six consecutive data transmissions. These findings validate the feasibility of sustainable, low-power GIoT architectures for ecological monitoring.

Electroless ZnO (≈900 nm) was deposited on the surface of an Mg-Al alloy (AM60) to reduce its degradation in the marine environment. Uncoated and coated ZnO samples were exposed to an SME simulated marine solution for up to 30 days. The AFM and optical images revealed that the corrosion attack on the ZnO-AM60 surface was reduced due to an increase in the surface hydrophobicity of the ZnO coating (contact angle of ≈91.6°). The change in pH to more alkaline values over time was less pronounced for ZnO-AM60 (by ≈13%), whereas the release of ${\mathrm{Mg}}^{2+}$ ions was reduced by 34 times, attributed to the decrease in active sites on the Mg-matrix provided by the electroless ZnO coating. The OCP (free corrosion potential) of ZnO-AM60 shifted towards less negative values of ≈100 mV, indicating that electroless ZnO may serve as a good barrier for AM60 in a marine environment. The calculated polarization resistance (${\mathrm{R}}_{\mathrm{p}}$), based on EIS data, was ≈3 times greater for ZnO-AM60 than that of the uncoated substrate.