Modified clay minerals on Mars: Sedimentary rocks exposed in Gale crater on Mars contain extensive clay minerals. Bristow et al. analyzed drill samples collected by the Curiosity rover as it climbed up sedimentary layers in the crater. They found evidence of past reactions with liquid water and sulfate brines, which could have percolated through the clay from an overlying sulfate deposit. Similar sulfate deposits are widespread across the planet and represent some of the last sedimentary rocks to form before the planet lost its surface liquid water, so the results inform our understanding of the geologic processes that occurred as Mars dried out. Science, abg5449, this issue p. 198

Ancient Mars had surface liquid water and a dense carbon dioxide (CO ₂ )–rich atmosphere. Such an atmosphere would interact with crustal rocks, potentially leaving a mineralogical record of its presence. We analyzed the composition of an 89-meter stratigraphic section of Gale crater, Mars, using data collected by the Curiosity rover. An iron carbonate mineral, siderite, occurs in abundances of 4.8 to 10.5 weight %, colocated with highly water-soluble salts. We infer that the siderite formed in water-limited conditions, driven by water-rock reactions and evaporation. Comparison with orbital data indicates that similar strata (deposited globally) sequestered the equivalent of 2.6 to 36 millibar of atmospheric CO ₂ . The presence of iron oxyhydroxides in these deposits indicates that a partially closed carbon cycle on ancient Mars returned some previously sequestered CO ₂ to the atmosphere.

Curiosity, the Mars Science Laboratory (MSL) rover, landed on Mars in August 2012 to investigate the ~3.5-billion-year-old (Ga) fluvio-lacustrine sedimentary deposits of Aeolis Mons (informally known as Mount Sharp) and the surrounding plains (Aeolis Palus) in Gale crater. After nearly nine years, Curiosity has traversed over 25 km, and the Chemistry and Mineralogy (CheMin) X-ray diffraction instrument on-board Curiosity has analyzed 30 drilled rock and three scooped soil samples to date. The principal strategic goal of the mission is to assess the habitability of Mars in its ancient past. Phyllosilicates are common in ancient Martian terrains dating to ~3.5–4 Ga and were detected from orbit in some of the lower strata of Mount Sharp. Phyllosilicates on Earth are important for harboring and preserving organics. On Mars, phyllosilicates are significant for exploration as they are hypothesized to be a marker for potential habitable environments. CheMin data demonstrate that ancient fluvio-lacustrine rocks in Gale crater contain up to ~35 wt. % phyllosilicates. Phyllosilicates are key indicators of past fluid–rock interactions, and variation in the structure and composition of phyllosilicates in Gale crater suggest changes in past aqueous environments that may have been habitable to microbial life with a variety of possible energy sources.

Gypsum is a common mineral at Gale crater on Mars, currently being explored by the Mars Science Laboratory (MSL) rover, Curiosity. In this paper, we summarize the associations of gypsum with other sulfate minerals (bassanite, anhydrite, jarosite, starkeyite, and kieserite) from the lowest levels of the crater’s northern moat zone (Aeolis Palus) up through ~0.8 km of the stratigraphic section in the lower slopes of the sedimentary mound developed around the central peak, Aeolis Mons (informally, Mount Sharp). The analysis is based on results from the CheMin X-ray diffraction instrument on Curiosity, supplemented with information from the rover’s versatile instrument suite. Gypsum does not occur with the same frequency as less hydrous Ca-sulfates, likely, in most cases, because of its dehydration to bassanite and possibly to anhydrite. All three of these Ca-sulfate phases often occur together and, along with other sulfates, in mixed assemblages that are evidence of limited equilibration on a cold, dry planet. In almost all samples, at least one of the Ca-sulfate minerals is present, except for a very limited interval where jarosite is the major sulfate mineral, with the implication of more acidic groundwater at a much later time in Gale crater’s history. Although observations from orbit reveal a sulfate-rich surface, currently active dark basaltic dunes at Gale crater have only small amounts of a single sulfate mineral, anhydrite. Gale crater has provided the most complete mineralogical analysis of a site on Mars so far, but the data in hand show that Gale crater mineralogy is not a blueprint with planet-wide application. The concurrent study of Jezero crater by the Mars 2020 mission and comparisons to what is believed to be the most extensive deposit of gypsum on Mars, in the dune fields at the north polar ice cap, show significant diversity. Unraveling the stories of gypsum and other sulfates on Mars is just beginning.

The Sample Analysis at Mars (SAM) instrument on the Curiosity rover has detected evidence of oxychlorine compounds (i.e., perchlorates and chlorates) in Gale crater, which has implications for past habitability, diagenesis, aqueous processes, interpretation of in situ organic analyses, understanding the martian chlorine cycle, and hazards and resources for future human exploration. Pure oxychlorines and mixtures of oxychlorines with Mars-analog phases have been analyzed for their oxygen (O₂) and hydrogen chloride (HCl) releases on SAM laboratory analog instruments in order to constrain which phases are present in Gale crater. These studies demonstrated that oxychlorines evolve O₂ releases with peaks between ~200 and 600 °C, although the thermal decomposition temperatures and the amount of evolved O₂ decrease when iron phases are present in the sample. Mg and Fe oxychlorines decompose into oxides and release HCl between ~200 and 542 °C. Ca, Na, and K oxychlorines thermally decompose into chlorides and do not evolve HCl by themselves. However, the chlorides (original or from oxychlorine decomposition) can react with water-evolving phases (e.g., phyllosilicates) in the sample and evolve HCl within the temperature range of SAM (<~870 °C). These laboratory analog studies support that the SAM detection of oxychlorine phases is consistent with the presence of Mg, Ca, Na, and K perchlorate and/or chlorate along with possible contributions from adsorbed oxychlorines in Gale crater samples.

The MSL Curiosity rover investigated dark, Mn-P-enriched nodules in shallow lacustrine/fluvial sediments at the Groken site in Glen Torridon, Gale Crater, Mars. Applying all relevant information from the rover, the nodules are interpreted as pseudomorphs after original crystals of vivianite, (Fe²⁺,Mn²⁺)₃(PO₄)₂·8H₂O, that cemented the sediment soon after deposition. The nodules appear to have flat faces and linear boundaries and stand above the surrounding siltstone. ChemCam LIBS (laser-induced breakdown spectrometry) shows that the nodules have MnO abundances approximately twenty times those of the surrounding siltstone matrix, contain little CaO, and have SiO₂ and Al₂O₃ abundances similar to those of the siltstone. A deconvolution of APXS analyses of nodule-bearing targets, interpreted here as representing the nodules’ non-silicate components, shows high concentrations of MnO, P₂O₅, and FeO and a molar ratio P/Mn = 2. Visible to near-infrared reflectance of the nodules (by ChemCam passive and Mastcam multispectral) is dark and relatively flat, consistent with a mixture of host siltstone, hematite, and a dark spectrally bland material (like pyrolusite, MnO₂). A drill sample at the site is shown to contain minimal nodule material, implying that analyses by the CheMin and SAM instruments do not constrain the nodules’ mineralogy or composition. The fact that the nodules contain P and Mn in a small molar integer ratio, P/Mn = 2, suggests that the nodules contained a stoichiometric Mn-phosphate mineral, in which Fe did (i.e., could) not substitute for Mn. The most likely such minerals are laueite and strunzite, Mn²⁺Fe³⁺₂(PO₄)₂(OH)₂·8H₂O and –6H₂O, respectively, which occur on Earth as alteration products of other Mn-bearing phosphates including vivianite. Vivianite is a common primary and diagenetic precipitate from low-oxygen, P-enriched waters. Calculated phase equilibria show Mn-bearing vivianite could be replaced by laueite or strunzite and then by hematite plus pyrolusite as the system became more oxidizing and acidic. These data suggest that the nodules originated as vivianite, forming as euhedral crystals in the sediment, enclosing sediment grains as they grew. After formation, the nodules were oxidized—first to laueite/strunzite yielding the diagnostic P/Mn ratio, and then to hematite plus an undefined Mn oxy-hydroxide (like pyrolusite). The limited occurrence of these Mn-Fe-P nodules, both in space and time (i.e., stratigraphic position), suggests a local control on their origin. By terrestrial analogies, it is possible that the nodules precipitated near a spring or seep of Mn-rich water, generated during alteration of olivine in the underlying sediments.