Modified clay minerals on Mars: Sedimentary rocks exposed in Gale crater on Mars contain extensive clay minerals. Bristow et al. analyzed drill samples collected by the Curiosity rover as it climbed up sedimentary layers in the crater. They found evidence of past reactions with liquid water and sulfate brines, which could have percolated through the clay from an overlying sulfate deposit. Similar sulfate deposits are widespread across the planet and represent some of the last sedimentary rocks to form before the planet lost its surface liquid water, so the results inform our understanding of the geologic processes that occurred as Mars dried out. Science, abg5449, this issue p. 198

Clay processes, mineral reactions, and element budgets in oceans continue to be important topics for scientific investigation, particularly with respect to

X-ray diffraction with a position-sensitive detector (XRD-PSD) was used to make a time-resolved study of the dynamics of deposition and dehydration of Na-montmorillonite crystallites on flat substrates from deionized water suspensions. The static PSD geometry and simultaneous counting procedure allowed the acquisition of high-resolution data on the dynamics of interlayer and interparticle arrangements during dehydration. Three experimental datasets of Na-smectite dehydration are presented, each one representing different initial sample states (suspension, slurry and re-wetted thin film). The computer program NEWMOD was used to simulate one of the three datasets (dehydration of a smectite suspension) and thus obtain the apparent changes in relative proportions of different 00l values as smectite crystallites formed and dehydrated. Two types of diffracting domains formed: water-dispersed ‘packets’ of 1–2 smectite layers gaining long-range order in the c axis direction as water was lost to evaporation, and smectite layers deposited as hydrated crystallites with variable interlayer water contents. The experimental patterns show the rapid step-wise transition of Na-montmorillonite layers from d values of ∼55 to 18.5, 15.4 and 12.5 Å, with variations that depended upon how the hydrated smectite sample was prepared. The simulations show that there was a wide range of d values whose frequency distribution changed as dehydration proceeded and that transient d values occurred between the peaks observed experimentally. The data obtained in this study illustrate that XRD-PSD instruments have great potential in providing detailed data on the rapid kinetics of interlayer reorganization.

McLaughlin crater is a 92‐km diameter complex crater that formed on Mars ~4 billion years ago. The resulting basin was the site of a large (~3,000 km²), deep (~500 m), voluminous (~1,500 km³) Martian lake circa 3.8 Ga. While there is strong evidence that hundreds of lakes have existed on Mars at some point during the same time period, the geology of McLaughlin crater is extraordinary for a number of reasons. Detailed spectral analyses show that the deep‐water sediments include detrital inputs of olivine and pyroxene, but the lake‐floor sediments include lithologies with abundant Fe‐rich, Mg‐bearing smectite, serpentine‐rich deposits, and ferrihydrite. For astrobiologists, this site provides a treasure trove of high‐priority targets. Serpentinization reactions are thought to have played a key role in abiogenesis on Earth, and within McLaughlin crater, deposits of subterranean and probably sublacustrine serpentinites are well preserved. In addition, delta sequences are well exposed throughout the east side of the basin; such deposits are endorsed by some as the highest priority targets for preservation of organics on Mars. Yet deep‐water turbidites, which might have flowed through hydrothermal environments, may be the most intriguing aspect of this geology. Such rapid sedimentation could have sequestered and preserved any potential organic materials for future exploration by a rover.