Biocomposites based on thermoplastic polymers and natural fibers have recently been used in wind turbine blades, to replace non-biodegradable materials. In addition, carbon nanofillers, including carbon nanotubes (CNTs) and graphene nanoplatelets (GNPs), are being implemented to enhance the mechanical performance of composites. In this work, the Mori–Tanaka approach is used for homogenization of a polymer matrix reinforced by CNT and GNP nanofillers for the first homogenization, and then, for the second homogenization, the effective matrix was used with alfa and E-glass isotropic fibers. The objective is to study the influence of the volume fraction and aspect ratio AR of nanofillers on the elastic properties of the composite. The inclusions are considered in a unidirectional and random orientation by using a computational method by Digimat-MF/FE and analytical approaches by Chamis, Hashin–Rosen and Halpin–Tsai. The results show that CNT- and GNP-reinforced nanocomposites have better performance than those without reinforcement. Additionally, by increasing the volume fraction and aspect ratio of nanofillers, Young’s modulus increases and Poisson’s ratio decreases. In addition, the composites have enhanced mechanical characteristics in the longitudinal orientation for CNT- reinforced polymer and in the transversal orientation for GNP-reinforced polymer.
1 September 2017 in Materials Chemistry and Physics
Inorganic halide perovskites, such as Cs₂InSbX₆ (X = F, Cl), have shown potential for next-generation solar cells and photocatalysis due to their light-capturing properties. However, concerns about stability and toxicity in lead-based perovskites drive the need for eco-friendly alternatives like antimony-based compounds. This study employed Density Functional Theory (DFT) calculations to explore how mechanical strain affects the electronic and optical properties of Cs₂InSbX₆. Without strain, Cs₂InSbF₆ and Cs₂InSbCl₆ exhibit bandgaps of 2.06 eV and 1.20 eV, respectively. We investigated how strain ranging from −5% to +5 % influences these materials' performance in optoelectronic and photocatalytic applications. Notably, negative strain enhances absorption and quantum efficiency for both compounds, particularly Cs₂InSbCl₆, which shows superior absorption in the visible spectrum. Our findings suggest that Cs₂InSbCl₆, with a tunable bandgap and favorable optical characteristics under strain, is a promising candidate for environmentally friendly applications, including solar cells and photocatalysis.