An X-ray diffraction (XRD) analysis was conducted after separating clay particles from three shards, to analyze the production technique of black pottery excavated from a historical site of ancient Baekje in Seoul, South Korea. Through the analysis, clay minerals and iron oxides that were not recognized in the XRD patterns of the bulk powder samples were identified. A pottery type with a blackened portion from the surface to the margin and the core was estimated to have been produced in a reduction firing environment of less than 900 °C, by detecting illite and magnetite. As for the other blackened pottery, a brown soil color remained in the core, and the presence of illite and kaolin was confirmed. In addition, while magnetite was detected on the black surface and margin, hematite was detected in the core. These results confirm that this type of blackened pottery was produced through reduction firing at a temperature below 550 °C. In particular, the results indicate that there is a new category of pottery, produced by firing at lower temperatures in a reduction atmosphere, previously not reported by research on ancient Baekje black pottery, which could be discovered due to its specific clay particles.

The sediment supply to the central Yellow Sea since the last deglaciation was uncovered through clay mineralogy and geochemical analysis of core 11YS-PCL14 in the Central Yellow Sea Mud (CYSM). The core can be divided into four units based on the various proxies, such as grain size, clay mineralogy, geochemistry, and Sr and Nd isotopes: Unit 4 (700–520 cm; 15.5–14.8 ka), Unit 3 (520–310 cm; 14.8–12.8 ka), Unit 2 (310–130 cm; 12.8–8.8 ka), and Unit 1 (130–0 cm; <8.8 ka). Unit 2 is subdivided into two subunits, Unit 2-2 (310–210 cm; 12.8–10.5 ka) and Unit 2-1 (210–130 cm; 10.5–8.8 ka), according to smectite content. Comparison of the clay mineral compositions, rare earth elements, and εNd indicate distinct provenance shifts in core 11YS-PCL14. Moreover, the integration of clay mineralogical and geochemical indices show different origins according to particle size. During the late last deglaciation (Units 3 and 4, 15.5–12.8 ka), Unit 4 sediments originated from all potential provenance rivers, such as the Huanghe, Changjiang, and western Korean rivers, while the source of coarse sediments changed to the Huanghe beginning with Unit 3. Fine-grained sediment was still supplied from all rivers during the deposition of Unit 3. Early Holocene (Unit 2) sediments were characterized by oscillating grain size, clay minerals, and moderate εNd values. In this period, the dominant fine-sediment provenance changed from the Huanghe to the Changjiang, whereas coarse sediments most likely originated from western Korean rivers. The Unit 1 CYSM sediments were sourced primarily from the Changjiang, along with minor contributions from the western Korean rivers. Possible transport mechanisms concerning such changes in the sediment provenance include paleo-river pathways, tidal stress evolution, and the development of the Yellow Sea Warm Current and coastal circulation systems, depending on the sea level fluctuations.