Humic (HA) and fulvic (FA) acids improve the nutrient availability and uptake by plants but some aspects of their agronomic use still need to be clarified. The effects of HA soil application and FA foliar application on the growth, Zn and B uptake by coffee seedlings were evaluated. HA was added to an Oxisol at concentrations 0, 10, 25, 50, 75 and 100 mg kg⁻¹ (C-HA), in both limed (pH 6.2) and overlimed (pH 7.2) conditions. FA (0, 0.2, 0.5 and 1 g L⁻¹ C-FA) was applied to coffee leaves in three different application modes (M): with 0.3% Zn and 0.6% B supplied via foliar (M₁), 0.6% B and 1.2% Zn supplied via foliar (M₂) and 1.2 mg kg⁻¹ B and 6 mg kg⁻¹ Zn supplied via soil (M₃). HA addition in soil significantly (p < 0.05) reduced leaf B and Zn accumulation and coffee growth in both pH conditions. In the M₁ and M₂, FA application significantly (p < 0.05) increased the shoot growth at 0.59 and 0.45 g L⁻¹ and B accumulation at 0.96 and 0.45 g L⁻¹ C-FA. Foliar application of C-FA, instead soil application of C-HA, is a suitable practice to improve coffee seedlings growth and nutrition on Oxisol.

The agronomic efficiency of biochar-based fertilizers (BBFs) relies on the synthesis routes, properties, and interaction with the soil–plant system. In our study, BBFs were produced from coffee husk, low-grade acidulated phosphate rock with and without the addition of magnesium (Mg). BBFs were characterized for infrared analysis and the kinetics of phosphorus (P) release in water or citric acid (CA). The agronomic performance of BBFs was tested by growing maize and, in sequence, brachiaria grass in pots filled with two Oxisols with contrasting soil organic matter (SOM) content. Using the same chemical stoichiometric ratio, nitric acid was more effective than hydrochloric and sulfuric acids, creating BBFs with enhanced agronomic performance. The use of Mg in the BBFs synthesis reduced the P released in water. Phosphorus released in CA leachates positively correlated with the P in the shoot of both plants. BBFs produced using nitric acid had higher residual effect on brachiaria grass grown in the Oxisol with the highest SOM. Our outcomes show that the P rate for maize and brachiaria grass should be considered based on P soluble in neutral ammonium citrate plus water in BBFs. BBFs is an alternative to improve the use efficiency of P in Oxisols.

This study aimed to investigate the role of Se supply in improving osmotic stress tolerance in coffee seedlings while also evaluating the best timing for Se application. Five times of Se foliar application were assessed during induced osmotic stress with PEG-6000 using the day of imposing stress as a default, plus two control treatments: with osmotic stress and without Se, and without osmotic stress and Se. Results demonstrated that osmotic stress (OS) promoted mild stress in the coffee plants (ψw from −1.5MPa to −2.5 MPa). Control plants under stress showed seven and five times lower activity of the enzymes GR and SOD compared with the non-stressed ones, and OS was found to further induce starch degradation, which was potentialized by the Se foliar supply. The seedlings that received foliar Se application 8 days before the stress exhibited higher CAT, APX, and SOD than the absolute control (−OS-Se)—771.1%, 356.3%, and 266.5% higher, respectively. In conclusion, previous Se foliar spray is more effective than the Se supply after OS to overcome the adverse condition. On the other hand, the post-stress application seems to impose extra stress on the plants, leading them to reduce their water potential.