Braids are generally divided into 2D braids and 3D braids. Two-dimensional braids include flat braids and circular braids. Circular braids represent three-dimensional textiles, as they enclose a volume, but consist of a two-dimensional yarn architecture. Three-dimensional braids are defined by a three-dimensional yarn architecture. Historically, 3D braids were produced on row and column braiding machines with Cartesian or radial machine beds, by bobbin movements around inlay yarns. Three-dimensional rotary braiding machines allow a more flexible braiding process, as the bobbins are moved via individually controlled horn gears and switches. Both braiding machines at the Institut für Textiltechnik (ITA) of RWTH Aachen University, Germany, are based on the principal of 3D rotary machines. The fully digitized 3D braiding machine with an Industry 4.0 standard enables the near-net-shape production of three-dimensionally braided textile preforms for lightweight applications. The preforms can be specifically reinforced in all three spatial directions according to the application. Complex 3D structures can be produced in just one process step due to the high degree of design freedom. The 3D hexagonal braiding technology is used in the field of medical textiles. The special shape of the horn gears and their hexagonal arrangement provides the densest packing of the bobbins on the machine bed. In addition, the lace braiding mechanism allows two bobbins to occupy the position between two horn gears, maximizing the number of bobbins. One of the main applications is the near-net-shape production of tubular structures, such as complex stent structures. Three-dimensional braiding offers many advantages compared to 2D braiding, e.g., production of complex three-dimensional geometries in one process step, connection of braided layers, production of cross-section changes and ramifications, and local reinforcement of technical textiles without additional process steps. In the following review, the latest developments in 3D braiding, the machine development of 3D braiding machines, as well as software and simulation developments are presented. In addition, various applications in the fields of lightweight construction and medical textiles are introduced.

In this work, the stress distribution along cylindrical composite pressure vessels with different dome geometries is investigated. The dome contours are generated through an integral method based on shell stresses. Here, the influence of each dome contour on the stress distribution at the interface of the dome-cylinder is evaluated. At first, the integral formulation for dome curve generation is presented and solved for the different dome contours. An analytical approach for the calculation of the secondary stresses in a cylindrical pressure vessel is introduced. For the analysis, three different cases were investigated: (i) a polymer liner; (ii) a single layer of carbon-epoxy composite wrapped on a polymer liner; and (iii) multilayer carbon-epoxy pressure vessel. Accounting for nonlinear geometry is seen to have an effect on the stress distribution on the pressure vessel, also on the isotropic liner. Significant secondary stresses were observed at the dome-cylinder interface and they reach a maximum at a specific distance from the interface. A discussion on the trend in these stresses is presented. The numerical results are compared with the experimental results of the multilayer pressure vessel. It is observed that the secondary stresses present in the vicinity of the dome-cylinder interface has a significant effect on the failure mechanism, especially for thick walled cylindrical composite pressure vessel. It is critical that these secondary stresses are directly accounted for in the initial design phase.

A series of phosphonium salts with pentafluorobenzyl substituents have been synthesized and were investigated in the crystal as well as in solution. The solid state structures of 1a, 1b and 2d reveal the presence of anion-π as well as CH-anion interactions. The two attractive, yet competitive forces seem to act in concert and a directing effect of the CH interaction on the relative position between anion and π-system is observed. The search for anion-π interactions in solution failed. Only CH-anion interactions proved to be important in solution.