There are discrepancies concerning the time frame for biodegradation of different commercially available foils labeled as biodegradable; thus, it is essential to provide information about their biodegradability in the context of their end of life in waste management. Therefore, one-year mesophilic (37 °C) anaerobic degradation tests of two bio-based foils (based on starch (F_S), polylactic acid (F_PLA)) and oxo-degradable material (F_OXO) were conducted in an OxiTop system. Biodegradation was investigated by measuring biogas production (BP) and analyzing structural changes with differential scanning calorimetry, polarizing and digital microscopic analyses, and Fourier transform infrared spectroscopy. After 1 year, F_OXO had not degraded; thus, there were no visible changes on its surface and no BP. The bio-based materials produced small amounts of biogas (25.2, F_PLA, and 30.4 L/kg VS, F_S), constituting 2.1–2.5% of theoretical methane potential. The foil pieces were still visible and only starting to show damage; some pores had appeared in their structure. The structure of F_PLA became more heterogeneous due to water diffusing into the structure. In contrast, the structure of F_S became more homogenous although individual cracks and fissures appeared. The color of F_S had changed, indicating that it was beginning to biodegrade. The fact that F_S and F_PLA showed only minor structural damage after a one-year mesophilic degradation indicates that, in these conditions, these materials would persist for an unknown but long amount of time.

The objective of this study was to compare three methods for determining the Young’s modulus of polylactic acid (PLA) and acrylonitrile-butadiene-styrene (ABS) samples. The samples were manufactured viathe fused filament fabrication/fused deposition modeling (FFF/FDM) 3D printing technique. Samples for analysis were obtained at processing temperatures of 180 °C to 230 °C. Measurements were performed with the use of two nondestructive techniques: the impulse excitation technique (IET) and the ultrasonic (US) method. The results were compared with values obtained in static tensile tests (STT), which ranged from 2.06 ± 0.03 to 2.15 ± 0.05 GPa. Similar changes in Young’s modulus were observed in response to the processing temperatures of the compared methods. The values generated by the US method were closer to the results of the STT, but still diverged considerably, and the error exceeded 10% in all cases. Based on the present findings, it might be concluded that the results of destructive and nondestructive tests differ by approximately 1 GPa.

The exposure parameters in stereolithography with liquid crystal display (SLA-LCD) influence the functional properties of photopolymers, which is particularly important for tribological applications. In this study, the influence of the exposure time of the layers (2–8 s) on the surface topography (ISO 25178), Brinell hardness (HB) and chemical structure (FTIR spectroscopy) of UV-cured resin samples is investigated. Both insufficient and excessive UV irradiation led to undesirable effects ranging from incomplete cross-linking and surface irregularities to excessive curing, micro-cracking and increased surface kurtosis (high Sku values). The most balanced mechanical and topographical performance was observed at a layer exposure time of 6 s, characterised by low Spk values, uniform surface texture and high cohesion between layers. FTIR analysis confirmed the progressive cross-linking with increasing exposure time. The results show that precise control of irradiation parameters enables optimisation of the interrelationships between microstructure, mechanical properties and surface functionality, which is critical for improving the durability and performance of components operating under boundary or mixed lubrication.

Although the manufacturers labelled commercially available bio-based products as biodegradable, there are discrepancies concerning the time frame for their sustainable biodegradation and methane production. Starch-based, polylactic acid-based and oxo-degradable foils were anaerobically treated in thermophilic condition (55 °C, 100 days). The effect of alkaline pretreatment on foils degradation was also investigated. To examine changes in their mechanical and physical properties, static tensile tests and microscopic analyses, FTIR and surface roughness analyses were conducted. Despite the thermophilic condition, and the longer retention time compared to that needed for biowaste, a small amount of methane was produced with bio-based foils, even after pretreatment (ca. 30 vs. 50 L/kg VS) and foils only lost functional and mechanical properties. The pieces of bio-based materials had only disintegrated, which means that digestate may become contaminated with fragments of these materials. Thus, providing guidelines for bio-based foil treatment remains a challenge in waste management.