Understanding the deposition history and signal formation in ice cores from polar ice sheets is fundamental for the interpretation of paleoclimate reconstruction based on climate proxies. Polar surface snow responds to environmental changes on a seasonal time scale by snow metamorphism, displayed in the snow microstructure and archived in the snowpack. However, the seasonality of snow metamorphism and accumulation rate is poorly constrained for low-accumulation regions, such as the East Antarctic Plateau. Here, we apply core-scale microfocus X-ray computer tomography to continuously measure snow microstructure of a 3-m deep snow core from Kohnen Station, Antarctica. We compare the derived microstructural properties to discretely measured trace components and stable water isotopes, commonly used as climate proxies. Temperature and snow height data from an automatic weather station are used for further constraints. Dating of the snow profile by combining non-sea-salt sulfate and density crusts reveals a seasonal pattern in the geometrical anisotropy. Considering seasonally varying temperature-gradient metamorphism in the surface snow and the timing of the anisotropy pattern observed in the snow profile, we propose the anisotropy to display the deposition history of the site. An annually varying fraction of deposition during summer months, ranging from no or negative deposition to large deposition events, leads to the observed microstructure and affects trace components as well as stable water isotopes.

Melting polar and alpine ice sheets in response to global warming pose ecological and societal risks but will also hamper our ability to reconstruct past climate and atmospheric composition across the globe. Since polar ice caps are crucial environmental archives but highly sensitive to ongoing climate warming, the Arctic and Antarctic research community is increasingly faced with melt-affected ice cores, which are already common in alpine settings of the lower latitudes. Here, we review the characteristics and effects of near-surface melting on ice-core records, focusing on a polar readership and making recommendations for melt-prone study regions. This review first covers melt layer formation, identification and quantification of melt, and structural characteristics of melt features. Subsequently, it discusses effects of melting on records of chemical impurities, i.e. major ions, trace elements, black carbon, and organic species as well as stable water isotopic signatures, gas records, and applications of melt layers as environmental proxies. Melting occurs during positive surface energy balance events, which are shaped by global to local meteorological forcing, regional orography, glacier surface conditions and subsurface characteristics. Meltwater flow ranges from homogeneous wetting to spatially heterogeneous preferential flow paths and is determined by temperature, thermal conductivity and stratigraphy of the snowpack. Melt layers and lenses are the most common consequent features in ice cores and are usually recorded manually or using line scanning. Chemical ice-core proxy records of water-soluble species are generally less preserved than insoluble particles such as black carbon or mineral dust due to their strong elution behaviour during percolation. However, high solubility in ice as observed for ions like F⁻, Cl⁻, NH${}_{\mathrm{4}}^{+}$ or ultra-trace elements can counteract the high mobility of these species due to burial in the ice interior. Stable water isotope records like δ¹⁸O are often preserved but appear smoothed if significant amounts of meltwater are involved. Melt-affected ice cores are further faced with questions about the permeability of the firn column for gas movement, and gas concentrations can be increased through dissolution and in situ production. Noble gas ratios can be useful tools for identifying melt-affected profile sections in deep ice. Despite challenges for ice-core climate reconstruction based on chemical records, melt layers are a proxy of warm temperatures above freezing, which is most sensitive in the dry snow and percolation zone. Bringing together insights from snow physics, firn hydrology, and ice-core proxy research, we aim to foster a more comprehensive understanding of ice cores as climate and environmental archives, provide a reference on how to approach melt-affected records, and raise awareness of the limitations and potential of melt layers in ice cores.

The sub-Antarctic is one of the most data-sparse regions on earth. A number of glaciated Antarctic and sub-Antarctic islands have the potential to provide unique ice core records of past climate, atmospheric circulation, and sea ice. However, very little is known about the glaciology of these remote islands or their vulnerability to warming atmospheric temperature. Here we present melt histories and density profiles from shallow ice (firn) cores (14 to 24 m) drilled on three sub-Antarctic islands and two Antarctic coastal domes. Additionally, complementary ground-penetrating radar (GPR) data were collected to further characterize each site and assess the spatial distribution of the observed melt layers. This study includes the first ever firn cores from Bouvet Island (54^∘25^′19^′′ S, 03^∘23^′27^′′ E) in the South Atlantic, from Peter I Island (68^∘51^′05^′′ S, 90^∘30^′35^′′ W) in the Bellingshausen Sea, and from Young Island (66^∘31^′44^′′ S, 162^∘33^′21^′′ E) in the Ross Sea sector's Balleny island chain. Despite their sub-Antarctic location, surface melt is low at most sites (melt layers account for ∼ 10 % of total core), with undisturbed ice layers in the upper ∼ 40 m, suggesting minimal impact of meltwater percolation. The exception is Young Island, where melt layers account for 47 % of the firn core. Surface snow densities range from 0.47 to 0.52 kg m⁻³, with close-off depths ranging from 21 to 51 m. Based on the measured density, we estimate that the bottom ages of a 100 m ice core drilled on Peter 1 Island would reach ∼ 1856 CE and ∼ 1874 CE at Young Island.

The climate of the sub-Antarctic is important in understanding the environmental conditions of Antarctica and the Southern Ocean. However, regional climate proxy records from this region are scarce. In this study, we present the stable water isotopes, major ion chemistry, and dust records from the first ice core from the (sub-)Antarctic Young Island. We present and discuss various dating approaches based on commonly used ice core proxies, such as stable water isotopes and seasonally deposited ions, together with site-specific characteristics such as melt layers. The dating approaches are compared with estimated precipitation rates from reanalysis data (ERA5) and volcanic cryptotephra shards likely presenting an absolute tie point from a 2001 CE eruption on neighboring Sturge Island. The resulting ice core age scale spans the period 2016 to 1995, with an uncertainty of ±2 years.

Here we present a case study for using visual stratigraphy to date a shallow firn core from coastal West Antarctica. The Mount Siple ice core has the potential to reconstruct climate in this data-sparse region over recent decades. Line scanned images of the 24 m firn core were used to generate a grey-scale, which displays variability consistent with annual cycles. The resulting Mount Siple age scale spans from 1998 ± 1 to 2017 CE. This study demonstrates that the seasonal changes in the grey-scale record provide an independent method of dating firn cores. However, the presence of melt layers at this site has introduced an error of ±1 year. Visual line stratigraphy has the unique advantage over traditional annual layer counting, based on chemical or isotopic species, of being non-destructive and relatively inexpensive. Visual line stratigraphy has proved to be an effective dating method for this site.