The colloidal stability of air nanobubbles (NBs) was studied at different temperatures (0–30 °C) and in the presence of sulfates, typically found in mining effluents, in a wide range of Na₂SO₄ concentrations (0.001 to 1 M), along with the effect of surfactants (sodium dodecyl sulfate), chloride salts (NaCl), and acid/base reagents at a pH range from 4 to 9. Using a nanobubble generator based on hydrodynamic cavitation, 1.2 × 10⁸ bubbles/mL with a typical radius of 84.66 ± 7.88 nm were generated in deionized water. Multiple evidence is provided to prove their presence in suspension, including the Tyndall effect, dynamic light scattering, and nanoparticle size analysis. Zeta potential measurements revealed that NBs are negatively charged even after two months (from − 19.48 ± 1.89 to − 10.13 ± 1.71 mV), suggesting that their stability is due to the negative charge on their surface. NBs were found to be more stable in alkaline solutions compared to acidic ones. Further, low amounts of both chloride and sulfate dissolved salts led to a reduction of the size of NBs. However, when high amounts of dissolved salts are present, NBs are more likely to coalesce, and their size to be increased. Finally, the investigation of the stability of air NBs at low temperatures revealed a non-monotonic relationship between temperature and NBs upon considering water self-ionization and ion mobility. This research aims to open a new frontier towards the application of the highly innovative NBs technology on the treatment of mining, mineral, and metal processing effluents, which are challenging aqueous solutions containing chloride and sulfate species.

Water is one of the most essential materials for human survival and preservation of life. The significance of equitable access to safe and clean drinking water and sanitation is established as a human right that is essential for the full enjoyment of life. The scope of this review is to record the different water sources, along with the water’s main characteristics of each source, and to compare the existing regulations and legislations regarding drinking water as have been set by the competent organizations. Furthermore, this review will highlight and provide a general insight into the most applied drinking water treatment methods and introduce some novel treatment methods. Moreover, Hazard Analysis and Critical Control Points (HACCP) requirements and case studies of drinking water treatment plants are presented. Finally, natural mineral water characteristics, treatment methods, and legislation, along with the uses and treatment of water in the food industry, are also discussed.

Hydrate-based desalination (HBD) has emerged as a promising technology among conventional desalination methods due to its low energy consumption, wide operating window with regards to total dissolved solids (TDS), and efficient water recovery. This paper provides an in-depth review of the fundamental properties of hydrates, including thermodynamic and kinetic aspects of their formation. Then, it delves into recent advancements in thermodynamic and kinetic hydrate promoters that aim to address HBD’s main challenge, which is the slow hydrate formation process. Subsequently, the review systematically examines environmental and toxicity concerns associated with chemicals used in HBD, addressing the growing demand for sustainable and biodegradable desalination solutions. Finally, a comparative analysis between HBD and conventional methods highlights its potential as an energy-efficient and selective desalination process poised to enhance sustainability within the water-energy-environment nexus.

This work presents the first validated method to analyze metals dissolved in deep eutectic solvents (DES) on a microwave plasma atomic emission spectrometer (MP-AES), which is key to the success of the upcoming field of solvometallurgical processing. The method was developed and validated for eleven metals: alkali metals: lithium (Li); alkaline earth metals: magnesium (Mg); transition metals: iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), palladium (Pd); and post-transition metals: aluminum (Al), tin (Sn), and lead (Pb) in choline chloride based DES. The proposed method was validated with respect to linearity, limit of detection (LOD), limit of quantification (LOQ), accuracy, precision, and selectivity. Our method's selectivity was evaluated for three DES matrices: (1) choline chloride: ethylene glycol, (2) choline chloride: levulinic acid, and (3) choline chloride: ethylene glycol in the presence of iodine, which is an oxidant often used in solvometallurgy. In all three matrices, the linearity range was plotted with at least 5 levels of standard solutions. All the parameters satisfied the acceptability criteria suggested by international organizations, such as the International Council for Harmonization, AOAC International, and the International Union of Pure and Applied Chemistry. Specifically, the calculated LOD and LOQ are comparable with aqueous matrices on MP-AES and with other analytical methods. The metal with the lowest reported LOD (0.003 ppm) and LOQ (0.008 ppm) was Cu, while the highest LOD and LOQ were obtained for Mg at 0.07 and 0.22 ppm, respectively. The recovery and precision for the three DES matrices were acceptable, i.e., between 95.67–108.40% and less than 10%, respectively. Finally, to compare the proposed method with the standard analytical method used to measure metals dissolved in aqueous solutions, we used 2 ppm standard solutions in DES and found that the accuracy was unacceptable without using the proposed method. Therefore, it is evident that our method will be pivotal in the field of solvometallurgy, as it will allow accurate and precise detection and quantification of metals dissolved in DES and eliminate quantification errors, which were estimated in excess of 140% without using the method developed and proper DES matrix-matched calibrations.

The development of a truly circular economy necessitates the recovery and recycling of resources from secondary streams. In this work, we studied the extraction of metals from printed circuit boards (PCBs) using choline chloride: ethylene glycol deep eutectic solvents: Cu, Ni, Zn, and Sn were selectively extracted from the PCBs, with >75% extraction after 72 h for Cu, Ni, and Sn, and circa. 45% extraction for Zn. This solvometallurgical approach promises to minimize the use of water and acid/base reagents in processing. The results show a considerable ability to compete with current methods of metal extraction and therefore generate a strong potential to attain the goal of a sustainable circular economy via zero-waste green urban mining.

Electronic waste (e-waste) is becoming a serious problem that impacts the environment due to its fast-growing volume. This rise is linked to high electronic and electrical equipment production to meet the increasing demand for high-end electronic devices. Conventional e-waste recycling approaches, including hydrometallurgy and pyrometallurgy, often involve substantial water and energy consumption and the generation of by-products, such as the emission of toxic gases or hazardous effluents. Within this context, solvometallurgy has emerged as a compelling alternative, whereby green non-toxic non-aqueous solvents, namely deep eutectic solvents (DESs), are used to extract and recover the metals with minimal water and harsh acid/base chemical use. The current study presents the solvo-leaching results of critical and strategic metals, i.e., copper (Cu) and nickel (Ni), and precious metals, i.e., gold (Au), from waste printed circuit boards (PCBs). Five different DESs were tested at mild conditions, namely at a temperature of 65 °C, a stirring speed of 300 rpm, a solid/liquid ratio of 10 g/L, and in the presence of iodine (I₂) for 96 h. Among the different solvents tested, the one consisting of choline chloride (ChCl), acetic acid (AA), and I₂ emerged as the optimal solvent, leading to the selective extraction of 99% of Cu, 92% of Ni, and 90% of Au from the PCB powder.