Biochar application has been reported to improve the physical, chemical, and hydrological properties of soil. However, the information about the size fraction composition of the applied biochar as a factor that may have an impact on the properties of soil-biochar mixtures is often underappreciated. Our research shows how sunflower husk biochar (pyrolyzed at 650 °C) can modify the water retention characteristics of arable sandy soil depending on the biochar dose (up to 9.52 wt.%) and particle size (<50 µm, 50–100 µm, 100–250 µm). For comparison, we used soil samples mixed with biochar passed through 2 mm sieve and an unamended reference. The addition of sieved biochar to the soil caused a 30% increase in the available water content (AWC) in comparing to the soil without biochar. However, the most notable improvement (doubling the reference AWC value from 0.078 m³ m⁻³ to 0.157 m³ m⁻³) was observed at the lowest doses of biochar (0.95 and 2.24 wt.%) and for the finest size fractions (below 100 µm). The water retention effects on sandy soil are explained as the interplay between the dose, the size of biochar particles, and the porous properties of biochar fractions.

Organic matter is an indispensable element of soil. Its quantity and quality affect its properties, e.g., structure, buffering, sorption capacity, air–water relations, and thermal properties. The purpose of the research was to assess greenhouse gas (GHG) emissions in soybean cultivation, fertilized with biochar from various crops. Two experimental factors were included: the dose of biochar and the type of biochar used as per raw material used in its production. The adopted functional unit was 1 ton of soybeans. To reach the adopted goal, a strict field experiment was carried out. The total amount of GHG emitted by the cultivation was calculated according to the ISO 14040 and ISO 14044 standards. The system boundaries included: GHG emissions from fertilizers and seeds used, GHG emissions related to biochar production, emissions related to fossil fuel combustion, and emissions related to the decomposition of crop residues and soil organic matter and the decomposition of biochar. The results of the research indicate a significant potential of biochar to reduce GHG emissions in agricultural production. From the environmental and production perspective, the addition of biochar at 60 Mg ha⁻¹ is the most advantageous. A further increase in the addition of biochar was related to a decrease in plant yield and an increase in GHG emissions per functional unit of the product. The use of biochar in soybean cultivation resulted in a 25% reduction in GHG emissions compared to the object without the biochar addition. The amount of GHG emissions for soybeans ranged from 846.9 to 1260.1 kg of CO₂/Mg. The use of biochar from forest biomass resulted in a higher yield, 12% on average, compared to sunflower husk biochar. The introduction of biochar to soils can be an effective improvement in the economic and environmental efficiency of plant production, as it increases the use of nutrients by the plant and intensifies carbon sequestration in soils.

In recent years, increasing attention has been paid to the possibility of converting waste materials, e.g. manure, bio-waste, green waste, waste from the water and sewage industries (e.g. post-fermentation sludge), and agri-food waste into biochars (BCs) by pyrolysis. The ability of biochar to improve soil health and fertility is driving growing interest in its use as a soil amendment. A high soil stability of BCs and their excellent nutrient sorption properties are the main reasons for the superiority of such materials over other organic soil amendments. In addition, BCs can retain soil-relevant compounds, including humic substances (HSs). Since most of the resources used to produce humic fertilisers are non-renewable, the effluent from anaerobic digestion of sewage sludge (reject water, RW), which contains high levels of HSs, is considered a promising target for their recovery. In this study, the potential of ten BCs derived from pine, oak, straw, sunflower, and digestate at different pyrolysis temperatures for the recovery of HSs from RW was evaluated. The sorption of HSs on the applied BCs was conducted using contact method for 24 h and then determined spectrophotometrically. The most effective sorbents for HSs from RW were BCs obtained from straw in the low and high temperatures with the sorption capacity of 3.10 mg g^-1 and 5.31 mg g^-1, respectively. It was observed that the BCs produced from the same biomass at different pyrolysis temperatures had different sorption capacities for FA, HA, and a mixture of these compounds. The results indicated that BCs obtained from sunflower at different temperatures and oak at high temperature were the most promising sorbents for the recovery of HSs from RW. Such materials have the potential to be applied to soil and were selected for further evaluation due to their ability to enhance soil quality and immobilize pollutants. Further studies will assess their effectiveness in different soil conditions, their stability and persistence, and their impact on plant health and growth.

The paper describes the possibilities of simple and effective modification of calcium sorbents used for flue gas desulfurization with a size between of 125–250 µm. The additives to the sorbents in the amount of 0.5% and 1.0% were inorganic sodium and lithium compounds. The research on the reactivity of sorbents was analyzed in the process of simultaneous calcination and sulfation at the temperature of 850 °C. The type of Na⁺ or Li⁺ cations and the inorganic salt anions have an influence on the modification of calcium sorbents in order to improve the efficiency of the calcination and sulfation process. Modification of calcium sorbents by adding inorganic sodium and lithium compounds, regardless of the amount, changes the reactivity coefficient RI [mol/mol] and the absolute sorption coefficient CI [g S/kg sorbent]. In the case of inorganic sodium salt (Additive 1), regardless of the amount of modifier added, there was a visible improvement in the reactivity of the sorbent: 1.0% of the additive caused an increase in the RI coefficient in relation to the raw sorbent by over 14%, and in the case of the CI coefficient by over 24%. Additional research was the analysis of the limestone behavior mechanism during the simultaneous calcination and sulfation (SCS) process under conditions of elevated temperature and with variable CO₂ and O₂ contents in the flue gas. The behavior of sorbents with a size distribution of 125–250 µm was assessed on the basis of the change in mass of the samples by determining the reactivity coefficient RI, [mol/mol] and the absolute sorption coefficient CI, [g S/kg sorbent]. Using the mercury porosimetry technique, the change in sorbent porosity in the subsequent stages of the simultaneous calcination and sulfation process was investigated. The process was carried out in the temperature range corresponding to the oxy-combustion (i.e., from 850 °C to 1000 °C).

The strength and energy of processed biological materials depend, among others, on their properties. Despite the numerous studies available, the relationship between the internal structure of corn grains and their mechanical properties has not yet been explained. Hence, the aim of the work is to explore the relationship between the internal composition of maize kernels and its mechanical properties by studying the impact of the maize seed coat thickness on its breakage susceptibility. To achieve the assumed goal, selected physical properties (length, width, and thickness) of corn grains were distinguished, and a static compression test was carried out on the Insight 50 kN testing machine (MTS Systems Corporation, Eden Prairie, MN, USA) with a test system for experimental verification of the compression behavior of biological materials. Furthermore, after the compression test, the thickness of the seed coat was measured using a laboratory microscope. It was found that there is a correlation between the thickness of the maize seed coat and force, deformation, and mass-specific energy at the bioyield point. The presented data constitute a foundation for the development of a mechanistic breakage model considering the variable strength properties of the seed coat and endosperm as the structural elements of kernels. Further research should be focused on the determination of the strength properties under dynamic conditions and revealing the relationship between the loading rate, strength properties, and internal structure for several maize varieties, which better reflect the ranges of variability in the real nature of mechanical processing.